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Enhancement of active anticorrosion via Ce-doped Zn-Al layered double hydroxides embedded in sol-gel coatings on aluminum alloy

  • Metallic Materials
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Abstract

Ce-doped Zn-Al layered double hydroxide (LDH) nanocontainer was synthesized by a co-precipitation method. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) methods were used for the characterization of the LDH nanocontainer. The anticorrosion activity of the LDH powders embedded in a hybrid sol-gel coating on aluminum alloy 2024 was investigated by electrochemical impendence spectroscopy (EIS). The results showed that Ce (III) ions were successfully incorporated into LDHs layers. The sol-gel coating modified with Ce-doped Zn-Al LDHs exhibited higher anticorrosion behavior compared with both unmodified and Ce-undoped LDHs containing coatings, which proved the applicability of Ce-doped LDHs in delaying coating degradation and their potential application as nanocontainers of corrosion inhibitors in self-healing coatings.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Beihang University, Beijing, 100191, China

    You Zhang  (张优), Jianhua Liu  (刘建华), Yingdong Li, Mei Yu, Xiaolin Yin & Songmei Li

Authors
  1. You Zhang  (张优)
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  2. Jianhua Liu  (刘建华)
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  3. Yingdong Li
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  4. Mei Yu
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  5. Xiaolin Yin
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  6. Songmei Li
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Corresponding author

Correspondence to Jianhua Liu  (刘建华).

Additional information

Funded by the National Natural Science Foundation of China (No. 51271012)

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Zhang, Y., Liu, J., Li, Y. et al. Enhancement of active anticorrosion via Ce-doped Zn-Al layered double hydroxides embedded in sol-gel coatings on aluminum alloy. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 32, 1199–1204 (2017). https://doi.org/10.1007/s11595-017-1731-6

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  • DOI: https://doi.org/10.1007/s11595-017-1731-6

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