Abstract
W-doped TiO2 supported by hybrid carbon nanomaterials of multi-walled carbon nanotubes and C60 fullerene was synthesized by a simple hydrothermal method. The material displayed high visible light photocatalytic activity. X-ray diffraction, field emission transmission electron microscopy, ultra violet/visible light absorption and photoluminescence spectroscopy were used to characterize the material as photocatalyst. Photocatalytic activity on the degradation of Rhodamine B dye in an aqueous solution under ultraviolet light and visible light irradiation was also studied. The experimental results indicated that the photocatalytic activity of the material was much higher than that of pure TiO2 or Degussa P25 TiO2.
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Yu JG, Xiong JF, Pei C. Low-temperature Hydrothermal Synthesis of TiO2 Photocatalyst with High Activity[J]. Chin. J. Catal., 2005, 26(9): 745–749
Zhang Q, Wang LY, Li XJ, et al. Preparation of TiO2 Film with Visiblelight Activity and Photocatalytic Properties[J]. J. Funct. Mater. Devices., 2002, 8(4): 397–401
Peng SQ, Jiang FY, Li YX. Preparation of N-doped TiO2 Photocatalyst and Degradation of Formaldehyhyde under Visible Light [J]. J. Funct. Mater., 2005, 36(8): 1 207–1 209
Claudio DD, Phani AR, Santuccia S. Enhanced Optical Properties of Sol-gel Derived TiO2 Films Uaing Microwave Irradiation[J]. Opt. Mater., 2007, 30(2): 279–284
Datta A, Priyam A, Bhattacharyya SN, et al. Temperature Tunability of Size in CdS Nanoparticles and Size Dependent Photocatalytic Degradation of Nitroaromatics[J]. J. Colloid Interface Sci., 2008, 322(1): 128–135
Cheng P, Deng CS, Gu MY, et al. Effect of Urea on the Photoactivity of Titania Powder Prepared by Sol-gel Method[J]. Mater. Chem. Phys., 2008, 107(1): 77–81
Becker WG, Truong MM, Ai CC, et al. Interfacial Factors that Affect the Photoefficiency of Semiconductor-sensitized Oxidations in Nonaqueous media [J]. J. Phys. Chem., 1989, 93(12): 4 882–4 886
Kutty TRN, Avudaithai M. Photocatalytic Activity of Tin-substituted TiO2 in Visible Light[J]. Chem. Phys. Lett., 1989, 163(1): 93–97
Vaidyanathan S, Eduardo EW, Prashant VK. Influence of Metal/Metal Ion Concentration on the Photocatalytic Activity of TiO2-Au Composite Nanoparticles [J]. Langmuir, 2003, 19(2): 469–474
Ryu JH, Park DS, Hahn BD, et al. Photocatalytic TiO2 Thin Films by Aerosol-deposition: From Micron-sized Particles to Nano-grained Thin Film at Room Temperature. Appl. Catal. B, 2008, 83(1–2): 1–7
Gopidas KR, Bohorquez M, Kamat PV. Photophysical and Photochemical Aspects of Coupled Semiconductors: Charge-transfer Processes in Colloidal Cadmium Sulfide-titania and Cadmium Sulfide-silver (I) Iodide Systems [J]. J. Phys. Chem., 1990, 94(16): 6 435–6 440
Tian H, Ma JF, Li K, et al. Photocatalytic Degradation of Methyl Orange with W-doped TiO2 Synthesized by a Hydrothermal Method [J]. Mater. Chem. Phys., 2008, 112(1): 47–51
Baskaran D, Mays JW, Bratcher MS. Noncovalent and Nonspecific Molecular Interactions of Polymers with Multiwalled Carbon Nanotubes [J]. Chem. Mater., 2005, 17(13): 3 389–3 397
Ge JJ, Zhang D, Li Q, et al. Multiwalled Carbon Nanotubes with Chemically Grafted Polyetherimides [J]. J. Am. Chem. Soc., 2005, 127(28): 9 984–9 985
Fugetsu B, Satoh S, Shiba T, et al. Caged Multiwalled Carbon Nanotubes as the Adsorbents for Affinity-Based Elimination of Ionic Dyes [J]. Environ. Sci. Technol., 2004, 38(24): 6 890–6 896
Chu DB, Zhang LY, Zhang JH, et al. Heterogeneous Electrocatalytic Reduction of Furfural on Nanocrystalline TiO2-CNT Complex Film Electrode in DMF Solution[J]. Acta Phys. Chim. Sin., 2006, 22(3): 373–377
Li WZ, Liang CH, Qiu JS, et al. Multi-walled Carbon Nanotubes Supported Pt-Fe Cathodic Catalyst for Direct Methanol Fuel Cell [J]. React. Kinet. Catal. Lett., 2004, 82(2): 235–240
Salveat-Delmontte JP, Rubio A. Mechanical Properties of Carbon Nanotubes: A Fiber Digest for Beginners[J]. Carbon, 2000, 40(10):1 729–1 734
Saito T, Matsushige K, Tanaka K. Chemical Treatment and Modification of Multi-walled Carbon Nanotubes[J]. Physica B, 2002, 323(1–4): 280–283
Wang F, Wang Q, Hu, YC et al. Study on Fabrication, Characterization and Photocatalytic Properties of Loaded Nanometer TiO2[J]. Rare Metal Mat. Eng., 2005, 34(3): 641–643
Wu YC, Song LY, Liu XL, et al. Preparation and Characterization of Carbon Nanotubes-TiO2 Nanocomposites [J]. J. Funct. Mater., 2008, 39(3): 497–498
Bie WW, Cong Y, Dong ZJ, et al. Synthesis and Characterization of TiO2-MWCNT Composites [J]. J. Wuhan. Univ. Sci. Technol. Mater. Sci. Ed., 2010, 33(4): 398–401
Schuster DI, MacMahon S, Guldi DM, et al. Synthesis and Photophysics of Porphyrin-fullerene Donor-acceptor Dyads with Conformationally Flexible Linkers[J]. Tetrahedron, 2006, 62(9): 1 928–1 936
Guldi DM, Maggini M, Martin N, et al. Charge Separation in Fullerene Containing Donor-bridge-acceptor Molecules[J]. Carbon, 2000, 38(11–12): 1 615–1 623
Krishna V, Noguchi N, Koopman B, et al. Enhancement of Titanium Dioxide Photocatalysis by Water-soluble Fullerenes [J]. J. Colloid Interf. Sci., 2006, 304(1): 166–171
Delgado JL, Cruz PDL, Urbina A, et al. The First Synthesis of A Conjugated Hybrid of C60-fullerene and a Single-wall Carbon Nanotube[J]. Carbon, 2007, 45(11): 2 250–2 252
Wei W, Zhang C, Du ZJ, et al. Synthesis and Characterization of MWCNTs/fullerene Hybrid [J]. J. Mater. Sci. Engin., 2009, 27(2): 216–218
Lin J, Zong RL, Zhou M, et al. Photoelectric Catalytic Degradation of Methylene Blue by C60-modified TiO2 Nanotube Array[J]. Appl. Catal. B, 2009, 89(3–4): 425–431
Shi XL, Wang S, Dong XB, et al. Enhanced Photocatalytic Activity of Titanium Dioxide by Nut Shell Carbon[J]. J. Hazard. Mater., 2009, 167(1–3): 692–695
Guan LH, Suenaga K, Okazaki T, et al. Coalescence of C60 Molecules Assisted by Doped Iodine Inside Carbon Nanotubes [J]. J. Am. Chem. Soc., 2007, 129(29): 8 954–8 955
Yang Y, Wang HY, Li X, et al. Electrospun Mesoporous W6+-doped TiO2 Thin Films for Efficient Visible-light Photocatalysis[J]. Mater. Lett., 2009, 63(2): 331–333
Luo YS, Liu JP, Xia XH, et al. Fabrication and Characterization of TiO2/Short MWCNTs with Enhanced Photocatalytic Activity [J]. Mater. Lett., 2007, 61(11–12): 2 467–2 472
Okada S, Saito S, Oshiyama A. Energetics and Electronic Structures of Encapsulated C60 in a Carbon Nanotube[J]. Phys. Rev. Lett., 2001, 86(17): 3 835–3 838
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Funded by the Project for the Academic Leader Program of Wuhan City (No. 201150530146) and the Natural Science Foundation of Hubei Province (No. 20101j0018)
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Shi, X., Zhu, Z. Synthesis and characterization of W-doped TiO2 supported by hybrid carbon nanomaterials of multi-walled carbon nanotubes and C60 fullerene by a hydrothermal method. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 28, 207–214 (2013). https://doi.org/10.1007/s11595-013-0666-9
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DOI: https://doi.org/10.1007/s11595-013-0666-9