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An effective strategy to enhance the photocatalytic performance by forming NiS/rGO heterojunction nanocomposites

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Abstract

Exploiting novel, low cost, and efficient photocatalysts for removal of pollutant waste water was significant to resolve the energy crisis and environment remediation. Here, we report the synthesis of nickel sulphide (NiS)/reduced graphene oxide (rGO)-based heterojunction photocatalyst using one step hydrothermal method. The intimate contact between NiS and rGO was suggested to quicken the transfer of photogenerated electrons from NiS to rGO, reducing the recombination of charge transporters and hence increasing the photocatalytic activities. The physico-chemical properties of the NiS/rGO heterojunction photocatalysts were scientifically studied with different characterization methods. The most efficient photocatalytic performances under solar light irradiation have been carefully assessed, and the NiS/rGO heterojunction nanocomposites exhibit photocatalytic degradation on methylene blue (MB). The removal percentage for MB can reach maximum at ~ 87% in ~ 100 min under solar light treatment. Moreover, the NiS/rGO heterojunction nanocomposite revealed highly stable for removing MB even after four successive experiments. Therefore, the experimental results demonstrated that the prepared NiS/rGO nanocomposites showed significant photocatalytic performance, thus supporting probable active heterojunction nanocomposite for energy conversion as well as in environmental remediation.

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Acknowledgments

Dr. Navaneethan Duraisamy acknowledges the DST, New Delhi, India, for the DST Inspire Faculty award (DST/INSPIRE/04/2018/001444).

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Authors and Affiliations

  1. Department of Physics, E.R.K Arts and Science College, Erumiyampatti, Tamil Nadu, India

    Priyadharsan Arumugam

  2. Department of Physics, Periyar University, Salem, Tamil Nadu, India

    Prabhu Sengodan & Ramesh Rajendran

  3. Department of Chemistry, J.K.K.Nataraja College of Arts and Science, Komarapalayam, Namakkal, Tamil Nadu, India

    Navaneethan Duraisamy

  4. Center for New and Renewable Energy, Department of Physics, Periyar University, Salem, Tamil Nadu, India

    Ramesh Rajendran

  5. Department of Chemistry, Periyar University, Salem, Tamil Nadu, India

    Vasanthakumar Vasudevan

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  1. Priyadharsan Arumugam
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Arumugam, P., Sengodan, P., Duraisamy, N. et al. An effective strategy to enhance the photocatalytic performance by forming NiS/rGO heterojunction nanocomposites. Ionics 26, 4201–4212 (2020). https://doi.org/10.1007/s11581-020-03564-y

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