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Structural and electronic properties of the LiNiPO4 orthophosphate

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Abstract

Microcrystalline LiNiPO4 powders have been prepared by solid-state reaction using various precursors. Characterization of the structure and morphology of powders was performed using XRD, SEM, HRTEM, Raman, and FTIR. The electronic properties of materials were investigated by SQUID and ESR. The LiNiPO4 material adopts the olivine-like structure (Pnma S.G.). Analysis of the Raman and FTIR spectra figures out, with the aid of a molecular vibration model, the bonding between NiO6 octahedral and (PO4)3− tetrahedral groups. The electronic configuration and the local cationic arrangement are confirmed by magnetic susceptibility and electron spin resonance spectroscopy.

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Acknowledgments

We would like to thank M. Selmane for his assistance in XRD measurements.

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Authors and Affiliations

  1. Physicochimie des Electrolytes, Colloïdes et Systèmes Analytiques (PECSA), UMR 7195, Université Pierre et Marie Curie, 4 place Jussieu, 75005, Paris, France

    C. M. Julien & H. Groult

  2. Institut de Minéralogie et Physique de la Matière Condensée (IMPMC), UMR 7590, Université Pierre et Marie Curie, 4 place Jussieu, 75005, Paris, France

    A. Mauger

  3. Institut de Recherche d’Hydro-Québec (IREQ), 1800 boul. Lionel-Boulet, Varennes, Québec, Canada, J3X 1S1

    K. Zaghib & R. Veillette

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  1. C. M. Julien
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  2. A. Mauger
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  3. K. Zaghib
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  4. R. Veillette
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  5. H. Groult
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Correspondence to C. M. Julien.

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Julien, C.M., Mauger, A., Zaghib, K. et al. Structural and electronic properties of the LiNiPO4 orthophosphate. Ionics 18, 625–633 (2012). https://doi.org/10.1007/s11581-012-0671-6

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  • DOI: https://doi.org/10.1007/s11581-012-0671-6

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