Abstract
We investigate the optical response of a gold nanocube antenna supported by a high-permittivity dielectric nanocuboid substrate and propose schemes for broadband tailoring of its plasmonic resonances via alteration in image-charge screening. Based on finite-element-method (FEM) simulations—in agreement with filtered-coupled-dipole-approximations (FCDA)—we explore the tunability and spectral evolution of the substrate-supported nanocube’s hybridized plasmon modes as functions of the relative permittivity and dimensions of the dielectric substrate. Besides numerical calculations, we also derive simple analytical expressions using image-charge theory to readily estimate the resonance spectral shift—gauging the intense particle–substrate interaction—for a substrate-supported nanocube. Strong localized electric field, around the nanocube’s vertices and edges near the substrate, is observed due to the image charges induced in the substrate by the coupled bonding mode arising from hybridization of the primitive dipolar and quadrupolar modes of the nanocube. By introducing slots on the dielectric substrate in the areas around the nanocube’s edges where electric field is highly concentrated, we achieve substrate’s surface-mediated wideband tunability of plasmonic resonance as functions of the geometric parameters of the slots while maintaining the overall dimensions and material of the nanocuboid substrate. These slots enable dynamic tunability of plasmon resonance by placing graphene flakes on them, which facilitates electrical tailoring of nanocube’s plasmon resonance over visible and near-infrared regions. Thus, these proposed schemes would allow one to widely tune the optical responses of any plasmonic nanoantennas using a slotted finite high-permittivity-dielectric substrate for numerous applications in nanophotonic integrated circuits and plasmonic devices.
Similar content being viewed by others
References
Bharadwaj P, Deutsch B, Novotny L (2009) Optical antennas. Adv Opt Photon 1(3):438–483
Kreibig U, Vollmer M (1995) Optical Properties of Metal Clusters. Springer, Berlin
Lal S, Link S, Halas NJ (2007) Nano-optics from sensing to waveguiding. Nat Photon 1:641–648
Xiong W, Sikdar D, Yap LW, Premaratne M, Li X, Cheng W (2015) Multilayered core–satellite nanoassemblies with finely-tunable broadband plasmon resonances. Nanoscale 7:3445–3452
Khan AD, Miano G (2013) Higher order tunable fano resonances in multilayer nanocones. Plasmonics 8 (2):1023–1034
Sikdar D, Rukhlenko ID, Cheng W, Premaratne M (2013) Unveiling ultrasharp scattering–switching signatures of layered gold–dielectric–gold nanospheres. J Opt Soc Am B 30(8):2066–2074
Yong KT, Swihart MT, Ding H, Prasad PN (2009) Preparation of gold nanoparticles and their applications in anisotropic nanoparticle synthesis and bioimaging. Plasmonics 4(2):79–93
Sikdar D, Rukhlenko ID, Cheng W, Premaratne M (2014) Tunable broadband optical responses of substrate-supported metal/dielectric/metal nanospheres. Plasmonics 9(3):659–672
Acevedo R, Lombardini R, Halas NJ, Johnson BR (2009) Plasmonic enhancement of Raman optical activity in molecules near metal nanoshells. J Phys Chem A 113(47):13173–13183
Xiong W, Sikdar D, Walsh M, Si KJ, Tang Y, Chen Y, Mazid R, Weyland M, Rukhlenko ID, Etheridge J, et al. (2013) Single-crystal caged gold nanorods with tunable broadband plasmon resonances. Chem Commun 49:9630–9632
Major KJ, De C, Obare SO (2009) Recent advances in the synthesis of plasmonic bimetallic nanoparticles. Plasmonics 4(1):61–78
Sikdar D, Rukhlenko ID, Cheng W, Premaratne M (2013) Effect of number density on optimal design of gold nanoshells for plasmonic photothermal therapy. Biom Opt Express 4(1):15–31
Sikdar D, Rukhlenko ID, Cheng W, Premaratne M (2013) Optimized gold nanoshell ensembles for biomedical applications. Nanoscale Res Lett 8(1):142–146
Zhu W, Sikdar D, Xiao F, Kang M, Premaratne M (2014) Gold nanoparticles with gain-assisted coating for ultra-sensitive biomedical sensing. Plasmonics. doi:10.1007/s11468-014-9875-0
Jain PK, Huang X, El-Sayed IH, El-Sayed MA (2007) Review of some interesting surface plasmon resonance-enhanced properties of noble metal nanoparticles and their applications to biosystems. Plasmonics 2 (3):107–118
Guo P, Sikdar D, Huang X, Si KJ, Xiong W, Gong S, Yap LW, Premaratne M, Cheng W (2015) Plasmonic core–shell nanoparticles for SERS detection of the pesticide Thiram: size- and shape-dependent Raman enhancement. Nanoscale 7: 2862–2868
Lakowicz JR (2006) Plasmonics in biology and plasmon-controlled fluorescence. Plasmonics 1(1):5–33
Massa E, Maier SA, Giannini V (2013) An analytical approach to light scattering from small cubic and rectangular cuboidal nanoantennas. New J Phys 15(6):063013
Hutter T, Elliott SR, Mahajan S (2013) Interaction of metallic nanoparticles with dielectric substrates: effect of optical constants. Nanotechnol 24(3):035201
Zhang S, Bao K, Halas NJ, Xu H, Nordlander P (2011) Substrate-induced fano resonances of a plasmonic nanocube: a route to increased-sensitivity localized surface plasmon resonance sensors revealed. Nano Lett 11(4):1657–1663
Chau YF, Jiang ZH (2011) Plasmonics effects of nanometal embedded in a dielectric substrate. Plasmonics 6(3):581–589
Knight MW, Wu Y, Lassiter JB, Nordlander P, Halas NJ (2009) Substrates matter: influence of an adjacent dielectric on an individual plasmonic nanoparticle. Nano Lett 9(5):2188–2192
Chen F, Johnston RL (2009) Plasmonic properties of silver nanoparticles on two substrates. Plasmonics 4 (2):147–152
Wu Y, Nordlander P (2010) Finite-difference time-domain modeling of the optical properties of nanoparticles near dielectric substrates. J Phys Chem C 114(16):7302–7307
Pinchuk A, Schatz G (2005) Anisotropic polarizability tensor of a dimer of nanospheres in the vicinity of a plane substrate. Nanotechnol 16(10):2209–2217
Pinchuk A, Hilger A, Von Plessen G, Kreibig U (2004) Substrate effect on the optical response of silver nanoparticles. Nanotechnol 15(12):1890–1896
Malinsky MD, Kelly KL, Schatz GC, Van Duyne RP (2001) Nanosphere lithography: effect of substrate on the localized surface plasmon resonance spectrum of silver nanoparticles. J Phys Chem B 105(12):2343–2350
Zhang F, Kang L, Zhao Q, Zhou J, Lippens D (2012) Magnetic and electric coupling effects of dielectric metamaterial. New J Phys 14(3):033031
Sikdar D, Cheng W, Premaratne M (2015) Optically resonant magneto-electric cubic nanoantennas for ultra-directional light scattering. J Appl Phys 117(8):083101
Zhang F, Zhao Q, Lan C, He X, Zhang W, Zhou J, Qiu K (2014) Magnetically coupled electromagnetically induced transparency analogy of dielectric metamaterial. Appl Phys Lett 104(13):131907
Fuchs R (1975) Theory of the optical properties of ionic crystal cubes. Phys Rev B 11(4):1732
Ruppin R (1996) Plasmon frequencies of cube shaped metal clusters. Z Phys D: At Mol Clusters 36(1):69–71
Meier M, Wokaun A (1983) Enhanced fields on large metal particles: dynamic depolarization. Opt Lett 8 (11):581–583
Averitt RD, Westcott SL, Halas NJ (1999) Linear optical properties of gold nanoshells. J Opt Soc Am B 16(10):1824–1832
Johnson PB, Christy RW (1972) Optical constants of the noble metals. Phys Rev B 6(12):4370–4379
Bedeaux D, Vlieger J (2004) Optical properties of surfaces. Imperial College Press, London
Valamanesh M, Borensztein Y, Langlois C, Lacaze E (2011) Substrate effect on the plasmon resonance of supported flat silver nanoparticles. J Phys Chem C 115(7):2914–2922
Zhang S, Bao K, Halas NJ, Xu H, Nordlander P (2011) Substrate-induced Fano resonances of a plasmonic nanocube: a route to increased-sensitivity localized surface plasmon resonance sensors revealed. Nano Lett 11:1657–1663
Bao Q, Loh KP (2012) Graphene photonics, plasmonics, and broadband optoelectronic devices. ACS Nano 6(5):3677–3694
Sikdar D, Premaratne M (2014) Electrically tunable directional spp propagation in gold-nanoparticle-assisted graphene nanoribbons. In: Photonics Conference (IPC), 2014 IEEE, pp 330–331
Zhu J, Liu QH, Lin T (2013) Manipulating light absorption of graphene using plasmonic nanoparticles. Nanoscale 5(17): 7785–7789
Jablan M, Buljan H, Soljacic M (2009) Plasmonics in graphene at infrared frequencies. Phys Rev B 80 (24): 245435
Ooi KJA, Chu HS, Ang LK, Bai P (2013) Mid-infrared active graphene nanoribbon plasmonic waveguide devices. J Opt Soc Am B 30(12):3111–3116
Acknowledgements
The work of DS is supported by Victoria India Doctoral Scholarship. The work of WC, WZ, and MP is supported by the Australian Research Council, through its Discovery Grants DP120100170, DP110100713 and and DP140100883.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sikdar, D., Zhu, W., Cheng, W. et al. Substrate-Mediated Broadband Tunability in Plasmonic Resonances of Metal Nanoantennas on Finite High-Permittivity Dielectric Substrate. Plasmonics 10, 1663–1673 (2015). https://doi.org/10.1007/s11468-015-9968-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11468-015-9968-4