Abstract
Hydrogen storage is a real challenge for realizing “hydrogen economy” that will solve the critical issues of humanity such as energy depletion, air pollution, greenhouse emission and climate change. Recently, tremendous efforts have been devoted to this internationally focused area. Magnesium (Mg) is among the most promising candidates for this purpose and attracts numerous research interests. This paper is aiming at reviewing recent literatures on approaches and progress, the necessity of further research, and future direction to the research of Mg for hydrogen storage.
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IPHE Report of USA, European Commission, Japan, Australia and China. www.iphe.net
Kruger R. Hydrogen & Fuel Cell Activities at Ford. Hydrogen Vehicles-Onboard Storage Systems, Cologne, 2002
Schlapbach L, Zuttel A. Hydrogen-storage materials for mobile applications. Nature, 2001, 414: 353–358
FY 2003 Progress Report. Hydrogen, Fuel Cells and Infrastructure Technologies Program, 2003
Amankwah K A G, Noh J S, Schwarz J A. Hydrogen storage on superactivated carbon at refrigeration temperatures. Int J Hydrogen Energy, 1989, 14: 437–447
Hynek S, Fuller W, Bentley J. Hydrogen storage by carbon sorption. Int J Hydrogen Energy, 1997, 22(6): 601–610
Ajayan P M, Ebbesen T W. Nanometre-size tubes of carbon. Rep Prog Phys, 1997, 60: 1025–1062
Tibbetts G G, Meisner G P, Olk C H. Hydrogen storage capacity of carbon nanotubes, filaments, and vapor-grown fibers. Carbon, 2001, 39: 2291–2301
Liu C, Fan Y Y, Liu M, et al. Hydrogen storage in single-walled carbon nanotubes at room temperature. Science, 1999, 286: 1127–1129
Yang Z X, Xia Y D, Mokaya R. Enhanced hydrogen storage capacity of high surface area zeolite-like carbon materials. J Am Chem Soc, 2007, 129: 1673–1679
Rosi N L, Eckert J, Eddaoudi M, et al. Hydrogen storage in microporous metal-organic frameworks. Science, 2003, 300: 1127–1129
Panella B, Hirscher M. Hydrogen physisorption in metal-organic porous crystals. Adv Mater, 2005, 17: 538
Rowsell J L C, Yaghi O M. Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal-organic frameworks. J Am Chem Soc, 2006, 128: 1304–1315
Han S S, Deng W Q, Goddard W A. Improved designs of metal-organic frameworks for hydrogen storage. Angew Chem Int Edit, 2007, 46: 6289–6292
Zaluski L, Zaluska A, Strom-Olsen J O. Nanocrystalline metal hydrides. J Alloys Comp, 1997, 253: 70–79
Huot J, Liang G, Schulz R. Mechanically alloyed metal hydride systems. Appl Phys A, 2001, 72: 187–195
Schuth F, Bogdanovic B, Felderhoff M. Light metal hydrides and complex hydrides for hydrogen storage. Chem Comm, 2004, 20: 2249–2258
Schimmel H G, Huot J, Chapon L C, et al. Hydrogen cycling of niobium and vanadium catalyzed nanostructured magnesium. J Am Chem Soc, 2005, 127: 14348–14354
Yartys V A, Riabov A B, Denys R V, et al. Novel intermetallic hydrides. J Alloys Comp, 2006, 408: 273–279
Sakintuna B, Lamari-Darkrim F, Hirscher M. Metal hydride materials for solid hydrogen storage: A review. Int J Hydrogen Energy, 2007, 32: 1121–1140
Bogdanovic B, Felderhoff M, Kaskel S, et al. Improved hydrogen storage properties of Ti-doped sodium alanate using titanium nanoparticles as doping agents. Adv Mater, 2003, 15: 1012
Chen J, Kuriyama N, Xu Q, et al. Reversible hydrogen storage via titanium-catalyzed LiAlH4 and Li3AlH6. Phys Chem B, 2001, 105: 11214–11220
Gross K J, Majzoub E H, Spangler S W. The effects of titanium precursors on hydriding properties of alanates. J Alloys Comp, 2003, 356: 423–428
van Setten M J, de Wijs G A, Brocks G. Model for the formation energies of alanates and boranates. J Phys Chem C, 2007, 111: 9592–9594
Xiong Z T, Wu G T, Hu H J, et al. Ternary imides for hydrogen storage. Adv Mater, 2004, 16: 1522
Chen P, Xiong Z T, Luo J Z, et al. Interaction of hydrogen with metal nitrides and imides. Nature, 2002, 420: 302–304
Gutowska A, Li L Y, Shin Y S, et al. Nanoscaffold mediates hydrogen release and the reactivity of ammonia borane. Angew Chem Int Edit, 2005, 44: 3578–3582
Bluhm M E, Bradley M G, Butterick R, et al. Amineborane-based chemical hydrogen storage: Enhanced ammonia borane dehydrogenation in ionic liquids. J Am Chem Soc, 2006, 128: 7748–7749
Paul A, Musgrave C B. Catalyzed dehydrogenation of ammonia-borane by iridium dihydrogen pincer complex differs from ethane dehydrogenation. Angew Chem Int Edit, 2006, 46: 8153–8156
Keaton R J, Blacquiere J M, Baker R T. Base metal catalyzed dehydrogenation of ammonia-borane for chemical hydrogen storage. J Am Chem Soc, 2007, 129: 1844
Selvam P, Viswanathan B, Swamy C S, et al. Magnesium and magnesium alloy hydrides. Int J Hydrogen Energy, 1986, 11: 169–192
Gerard N, Ono S. Hydrogen in Intermetallic Compounds II. New York: Springer-Verlag, 1992. 178–182
Grochala W, Edwards P P. Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen. Chem Rev, 2004, 104: 1283–1315
Zaluska A, Zaluski L, Strom-Olsen J O. Structure, catalysis and atomic reactions on the nano-scale: A systematic approach to metal hydrides for hydrogen storage. Appl Phys A, 2001, 72: 157–165
Zaluska A, Zaluski L, Strom-Olsen J O. Nanocrystalline magnesium for hydrogen storage. J Alloys Comp, 1999, 288: 217–225
Krozer A, Kasemo B. Equilibrium hydrogen uptake and association kinetics for the Mg-H2 system at low pressures. J Phys Cond Matt, 1989, 1: 1533–1538
Zaluski L, Zaluska A, Strom-Olsen J O. Hydrogen absorption in nanocrystalline Mg2Ni formed by mechanical alloying. J Alloys Comp, 1995, 217: 245–249
Nohara S, Fujita N, Zhang S G, et al. Electrochemical characteristics of a homogeneous amorphous alloy prepared by ball-milling Mg2Ni with Ni. J Alloys Comp, 1998, 267: 76–78
Zhang Y S, Yang H B, Yuan H T, et al. Dehydriding properties of ternary Mg2Ni1−x Zrx hydrides synthesized by ball milling and annealing. J Alloys Comp, 1998, 269: 278–283
Liang G, Huot J, Boily S, et al. Catalytic effect of transition metals on hydrogen sorption in nanocrystalline ball milled MgH2-Tm (Tm=Ti, V, Mn, Fe and Ni) systems. J Alloys Comp, 1999, 292: 247–252
Shang C X, Bououdina M, Song Y, et al. Mechanical alloying and electronic simulations of (MgH2 + M) systems (M-Al, Ti, Fe, Ni, Cu and Nb) for hydrogen storage. Int J Hydrogen Energy, 2004, 29: 73–80
Yavari A R, LeMoulec A, de Castro F R, et al. Improvement in H-sorption kinetics of MgH2 powders by using Fe nanoparticles generated by reactive FeF3 addition. Scr Mater, 2005, 52: 719–724
Hanada N, Ichikawa T, Fujii H. Catalytic effect of nanoparticle 3d-transition metals on hydrogen storage properties in magnesium hydride MgH2 prepared by mechanical milling. J Phys Chem B, 2005, 109: 7188–7194
Yermakov A Y, Mushnikov N V, Uimin M A, et al. Hydrogen reaction kinetics of Mg-based alloys synthesized by mechanical milling. J Alloys Comp, 2006, 425: 367–372
Dufour J, Huot J. Rapid activation, enhanced hydrogen sorption kinetics and air resistance in laminated Mg-Pd 2.5 at%. J Alloys Comp, 2007, 439: L5–L7
Oelerich W, Klassen T, Bormann R. Metal oxides as catalysts for improved hydrogen sorption in nanocrystalline Mg-based materials. J Alloys Comp, 2001, 315: 237–242
Song M Y, Bobet J L, Darriet B. Improvement in hydrogen sorption properties of Mg by reactive mechanical grinding with Cr2O3, Al2O3 and CeO2. J Alloys Comp, 2002, 340: 256–262
Barkhordarian G, Klassen T, Bormann R. Fast hydrogen sorption kinetics of nanocrystalline Mg using Nb2O5 as catalyst. Scr Mater, 2003, 49: 213–217
Friedrichs O, Aguey-Zinsou F, Fernandez J R A, et al. MgH2 with Nb2O5 as additive, for hydrogen storage: Chemical, structural and kinetic behavior with heating. Acta Mater, 2006, 54: 105–110
Aguey-Zinsou K F, Fernandez J R A, Klassen T, et al. Effect of Nb2O5 on MgH2 properties during mechanical milling. Int J Hydrogen Energy, 2007, 32: 2400–2407
Gross K J, Spatz P, Zuttel A, et al. Mechanically milled Mg composites for hydrogen storage—The transition to a steady state composition. J Alloys Comp, 1996, 240: 206–213
Wang P, Wang A M, Ding B Z, et al. Mg-FeTi1.2 (amorphous) composite for hydrogen storage. J Alloys Comp, 2002, 334: 243–248
Wang H, Ouyang L Z, Peng C H, et al. MmM(5)/Mg multi-layer hydrogen storage thin films prepared by dc magnetron sputtering. J Alloys Comp, 2004, 370: L4–L6
Kondo T, Shindo K, Sakurai Y. Dependence of hydrogen storage characteristics of Mg-TiFe0.92Mn0.08 composite on amount of TiFe0.92Mn0.08. J Alloys Comp, 2005, 404: 511–514
Barkhordarian G, Klassen T, Bormann R. Catalytic mechanism of transition-metal compounds on Mg hydrogen sorption reaction. J Phys Chem B, 2006, 110: 11020–11024
Yu Z X, Liu Z Y, Wang E D. Hydrogen storage properties of nanocomposite Mg-Ni-Cu-CrCl3 prepared by mechanical alloying. Mater Sci Eng A, 2003, 335: 43–48
Yu Z X, Liu Z Y, Wang E D. Hydrogen storage properties of the Mg-Ni-CrCl3 nanocomposite. J Alloys Comp, 2002, 333: 207–214
Xie L, Liu Y, Wang Y T, et al. Superior hydrogen storage kinetics of MgH2 nanoparticles doped with TiF3. Acta Mater, 2007, 55: 4585–4591
Jin S A, Shim J H, Cho Y W, et al. Dehydrogenation and hydrogenation characteristics of MgH2 with transition metal fluorides. J Power Sources, 2007, 172: 859–862
Imamura H, Kusuhara M, Minami S, et al. Carbon nanocomposites synthesized by high-energy mechanical milling of graphite and magnesium for hydrogen storage. Acta Mater, 2003, 51: 6407–6414
Fujii H, Orimo S. Hydrogen storage properties in nano-structured magnesium-and carbon-related materials. Physica B, 2003, 328: 77–80
Shang C X, Guo Z X. Effect of carbon on hydrogen desorption and absorption of mechanically milled MgH2. J Powder Sources, 2004, 129: 73–80
Takasaki A, Furuya Y, Katayama M. Mechanical alloying of graphite and magnesium powders, and their hydrogenation. J Alloys Comp, 2007, 446: 110–113
Narayanan D L, Lueking A D. Mechanically milled coal and magnesium composites for hydrogen storage. Carbon, 2007, 45: 805–820
Vegge T. Locating the rate-limiting step for the interaction of hydrogen with Mg(0001) using density-functional theory calculations and rate theory. Phys Rev B, 2004, 70: 035412
Du A J, Smith S C, Yao X D, et al. The role of Ti as a catalyst for the dissociation of hydrogen on a Mg(0001) surface. J Phys Chem B, 2005, 109: 18037–18041
Du A J, Smith S C, Yao X D, et al. Catalytic effects of subsurface carbon in the chemisorption of hydrogen on a Mg(0001) surface: An ab-initio study. J Phys Chem B, 2006, 110: 1814–1819
Du A J, Smith S C, Yao X D, et al. Ab initio studies of hydrogen desorption from low index magnesium hydride surface. Surf Sci, 2006, 600: 1854–1859
Du A J, Smith S C, Yao X D, et al. First-principle study of adsorption of hydrogen on Ti-doped Mg(0001) surface. J Phys Chem B, 2006, 110: 21747–21750
Du A J, Smith S C, Yao X D, et al. Hydrogen spillover mechanism on a Pd-doped Mg surface as revealed by ab initio density functional calculation. J Am Chem Soc, 2007, 129: 10201–10204
Yao X D, Wu C Z, Du A J, et al. Metallic and carbon nanotube-catalyzed coupling of hydrogenation in magnesium. J Am Chem Soc, 2007, 129: 15650–15654
Du A J, Smith S C, Yao X D, et al. Catatytic effect of V2O5 on the dissociation of hydrogen on a Mg(0001) surface. Appl Phys Lett, 2008, 92: 163106–163108
Du A J, Smith S C, Yao X D, et al. Atomic hydrogen diffusion in novel magnesium nanostructures: The impact of incorporated subsurface carbon atoms. J Phys: Conf Ser, 2006, 29: 167–172
Joo S H, Choi S J, Oh I, et al. Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles. Nature, 2001, 412: 169–172
Dillon A C, Jones K M, Bekkedahl T A, et al. Storage of hydrogen in single-walled carbon nanotubes. Nature, 1997, 386: 377–379
Lin J Y. Hydrogen storage in nanotubes. Science, 2000, 287: 1929–1929
Wu C Z, Wang P, Yao X, et al. Effect of carbon/noncarbon addition on hydrogen storage behaviors of magnesium hydride. J Alloys Comp, 2006, 414: 259–264
Wu C Z, Wang P, Yao X, et al. Hydrogen storage properties of MgH2/SWNT composite prepared by ball milling. J Alloys Comp, 2006, 420: 278–282
Yao X D, Wu C Z, Du A J, et al. Mg-based nanocomposites with high capacity and fast kinetics for hydrogen storage. J Phys Chem B, 2006, 110: 11697–11703
Yao X, Wu C Z, Wang H, et al. Effects of carbon nanotubes and metal catalysts on hydrogen storage in magnesium nanocomposites. J Nanosci Nanotech, 2006, 6: 494–498
Yao X, Wu C Z, Zhu Z H, et al. Effect of Mn and Zr on hydrogen absorption in Mg-based nanocomposites. Int J Hydrogen Energy, 2008, in press
Sholl D S. Using density functional theory to study hydrogen diffusion in metals: A brief overview. J Alloys Comp, 2007, 446: 462–468
San-Martin A, Manchester F D. In: Nayer-Hashemi A A, Clark J B, eds. Phase Diagrams of Binary Magnesium Alloys. ASM International, 1988
Berlouis L E A, Cabrera E, Hall-Barientos E, et al. Thermal analysis investigation of hydriding properties of nanocrystalline Mg-Ni-and Mg-Fe-based alloys prepared by high-energy ball milling. Mater Res, 2001, 16: 45–57
Yao X, Zhu Z H, Cheng H M, et al. Modeling of hydrogen diffusion in magnesium hydrides. J Mater Res, 2008, 23: 336–340
Yavari A R. Mechanically prepared nanocrystalline materials. Mater Trans JIM, 1995, 36: 228–239
Sakintuna B, Lamari-Darkrim F, Hirscher M. Metal hydride materials for solid hydrogen storage: A review. Int J Hydrogen Energy, 2007, 32: 1121–1140
Annemieke W C, van den Berg, Carlos O A. Materials for hydrogen storage: Current research trends and perspectives. Chem Comm, 2008, 6: 668–681
Reilly J J, Wiswall R H. Reaction hydrogen with alloys magnesium and nickel and formation of Mg2NiH4. Inorg Chem, 1968, 7: 2254
Zaluska A, Zaluski L, Strom-Olsen J O. Synergy of hydrogen sorption in ball-milled hydrides of Mg and Mg2Ni. J Alloys Comp, 1999, 289: 197–206
Janot R, Aymard L, Rougier A, et al. Enhanced hydrogen sorption capacities and kinetics of Mg2Ni alloys by ball-milling with carbon and Pd coating. J Mater Res, 2003, 18: 1749–1752
Chen X J, Xia T D, Liu X L, et al. Mechanism of combustion synthesis of Mg2Ni. J Alloys Comp, 2006, 426: 123–130
Kodera Y, Yamasaki N, Yamamoto T, et al. Hydrogen storage Mg2Ni alloy produced by induction field activated combustion synthesis. J Alloys Comp, 2007, 446: 138–141
Szajek A, Jurczyk M, Okonska I, et al. Electrochemical and electronic properties of nanocrystalline Mg-based hydrogen storage materials. J Alloys Comp, 2007, 436: 345–350
Tanaka K, Kanda Y, Furuhashi M, et al. Improvement of hydrogen storage properties of melt-spun Mg-Ni-RE alloys by nanocrystallization. J Alloys Comp, 1999, 293: 521–525
Spassov T, Rangelova V, Neykov N. Nanocrystallization and hydrogen storage in rapidly solidified Mg-Ni-RE alloys. J Alloys Comp, 2002, 334: 219–223
Gebert A, Khorkounov B, Wolff U, et al. Stability of rapidly quenched and hydrogenated Mg-Ni-Y and Mg-Cu-Y alloys in extreme alkaline medium. J Alloys Comp, 2006, 419: 319–327
Huang L J, Liang G Y, Sun Z B, et al. Nanocrystallization and hydriding properties of amorphous melt-spun Mg65Cu25Nd10 alloy. J Alloys Comp, 2007, 432: 172–176
Lu K. Nanocrystalline metals crystallized from amorphous solids: Nanocrystallization, structure, and properties. Mater Sci Eng R-Reports, 1996, 16: 161–221
Yao X, Lu G Q, Li L, et al. Multi-component catalysts enhanced hydrogen storage in novel magnesium-based nanocomposites. Australian Patent, 2007903489, 2007
Mao J F, Wu Z, Chen T J, et al. Improved hydrogen storage of LiBH4 catalyzed magnesium. J Phys Chem C, 2007, 111: 12495–12498
Chen P, Xiong Z T, Wu G T, et al. Metal-N-H systems for the hydrogen storage. Scr Mater, 2007, 56: 817–822
Imamura H, Tabata S, Shigetomi N, et al. Composites for hydrogen storage by mechanical grinding of graphite carbon and magnesium. J Alloys Comp, 2002, 330: 579–583
Zuttel A, Wenger P, Rentsch S, et al. LiBH4 a new hydrogen storage material. J Power Sources, 2003, 118: 1–7
Alapati S V, Johnson J K, Sholl D S. Identification of destabilized metal hydrides for hydrogen storage using first principles calculations. J Phys Chem B, 2006, 110: 8769–8776
Ikeda T, Mikami Y, Haruki T. Mg-promoted LiH-LiNH2 hydrogen storage system synthesized by using the mechanochemical method. J Phys Chem C, 2007, 111: 8389–8396
Mayo M J, Suresh A, Porter W D. Thermodynamics for nanosystems: Grain and particle size dependent phase diagrams. Rev Adv Mater Sci, 2003, 5: 100–109
Alba-Simionesco C, Coasne B, Dosseh G, et al. Effects of confinement on freezing and melting. J Phys: Cond Matt, 2006, 18: R15–R68
Santiso E E, George A M, Turner C H, et al. Adsorption and catalysis: The effect of confinement on chemical reactions. Appl Surf Sci, 2005, 252: 766–777
Wagemans R W P, van Lenthe J H, de Jongh P E, et al. Hydrogen storage in magnesium clusters: Quantum chemical study. J Am Chem Soc, 2005, 127: 16675–16680
Liang J J, Kung W C P. Confinement of Mg-MgH2 systems into carbon nanotubes changes hydrogen sorption energetics. J Phys Chem B, 3005, 109: 17837–17841
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Yao, X., Lu, G. Magnesium-based materials for hydrogen storage: Recent advances and future perspectives. Chin. Sci. Bull. 53, 2421–2431 (2008). https://doi.org/10.1007/s11434-008-0325-2
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DOI: https://doi.org/10.1007/s11434-008-0325-2