Abstract
Photocatalytic degradation of dicofol was investigated on TiO2 nano particles (TiO2-NPs) under UV light irradiation. It was shown that dicofol could be completely degraded into inorganic chloride ion under the condition of 0.25 mg/mL TiO2-NPs, 2 h irradiation of 400 W high pressure mercury lamp with a wavelength of 365 nm and air at a rate of 100 mL/min. The effects of the experimental conditions, including the amount of TiO2-NPs, irradiation time and the intensity of light, were studied. The apparent photodegradation rate constant was 0.167/min under the optimal condition. The photocatalytic degradation mechanism of dicofol was also discussed.
Similar content being viewed by others
References
Zhu L T. Pesticides (in Chinese). Beijing: Chemistry Industry Press, 2004. 225–226
Liang G, Tang C Z. Estrogenic effects and acting mechanisms of dicofol. Sichuan Environment (in Chinese), 2004, 23(5): 54–58
Hoekstra P F, Burnison B K, Garrison A W, et al. Estrogenic activity of dicofol with the human estrogen receptor: isomer-and enantiomer-specific implications. Chemosphere, 2006, 64(1): 174–177
Chen Z M. Explanation for taboo of dicofol in tea management. Pesticide Science and Administration (in Chinese), 1996, 3: 32–33
Sood C, Jaggi S, Kumar V, et al. How manufacturing processes affect the level of pesticide residues in tea. J Sci Food Agr, 2004, 84: 2123–2127
Reynolds P, Von B J, Gunier R, et al. Agricultural pesticide use and childhood cancer in California. Epidemiology, 2005, 16(1): 93–100
Liu Y M, Chen W, Li D H, et al. Reproduction toxicity and estrogenic effects of dicofol to daphnia magna. Acta Hydrobiol Sin (in Chinese), 2004, 28(3): 330–332
Wang G H. Selection of high efficient degrading strains and study on its degrading capability. Environmental Protection (in Chinese), 2004, 8: 12–14
Hall A K, Harrowfield J M, Hart R J, et al. Mechanochemical reaction of DDT with calcium oxide. Environ Sci Technol, 1996, 30(12): 3401–3407
Moctezuma E, Leyva E, Monreal N, et al. Photocatalytic degradation of the herbicide “paraquat”. Chemosphere, 1999, 39(3): 511–517
Hügül M, Boz I, Apak R. Photocatalytic decomposition of 4-chloro-phenol over oxide catalysts. J Hazard Mater B, 1999, 64: 313–322
Prevot A B, Pramauro E. Analytical monitoring of photocatalytic treatments, Degradation of 2,3,6-trichlorobenzoic acid in aqueous TiO2 dispersions. Talanta, 1999, 48: 847–857
Hu Y, Xu J J, Yuan C W, et al. A single TiO2-coated side-glowing optical fiber for photocatalytic wastewater treatment. Chin Sci Bull, 2005, 50(18): 1979–1984
Li X F, Wang X Y, Wen X H, et al. Density functional theory study on the anti-wear and extreme pressure properties for disulfide compounds as lubricant additive. Chinese J Struct Chem (in Chinese), 2004, 23(9): 1044–1050
Nomiyama K, Tanizaki T, Ishibashi H, et al. Production mechanism of hydroxylated PCBs by oxidative degradation of selected PCBs using TiO2 in water and estrogenic activity of their intermediates. Environ Sci Technol, 2005, 39: 8762–8769
Carrier M, Perol N, Herrmann J M, et al, Kinetics and reactional pathway of imazapyr photocatalytic degradation influence of pH and metallic ions. Appl Catal B-Environ, 2006, 65: 11–20
Gao L, Zheng S, Zhang Q H. Photocatalytic Material and Application of Nano-Titanium Oxide (in Chinese). Beijing: Chemistry Industry Press, 2002. 40–41
Konstantinou I K, Sakellarides T M, Sakkas V A, et al. Photocatalytic degradation of selected s-Triazine herbicides and organophosphrous insecticides over aquous TiO2 suspensions. Environ Sci Technol, 2001, 35: 398–405.
Liufu S C, Xiao H N, Li Y P, et al. Effects of nanoparticle titanium dioxide and ultraviolet absorbers on anti-photooxidation of acrylic coatings. J Funct Mater (in Chinese), 2004, 4(35): 495–497
Chen S F, Zhao M Y, Tao Y W, et al. Study on the photocatalytic degradation of organo-phosphrus pesticides. Chin J Environ Sci (in Chinese), 1995, 16(5): 61–63
Sabate J, Bayona J M, Solanas A M. Photolysis of PAHs in aqueous phase by UV irradiation. Chemosphere, 2001, 44: 119–124
Choi W Y, Hoffmann M R. Photoreductive mechanism of CCl4 degradation on TiO2 particles and effects of electron donors. Environ Sci Technol, 1995, 29: 1646–1654
Author information
Authors and Affiliations
Corresponding author
Additional information
Supported by the Program for New Century Excellent Talents in University of China (NCET) and the Science-Technology Project of Fujian Province (Grant Nos. 2005-I-030 and 2006Y0026)
About this article
Cite this article
Yu, B., Zeng, J., Gong, L. et al. Photocatalytic degradation investigation of dicofol. Chin. Sci. Bull. 53, 27–32 (2008). https://doi.org/10.1007/s11434-007-0482-8
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s11434-007-0482-8