Abstract
The oil-rich Damintun Depression is located in the Liaohe Basin, Northeast China, and was formed during the Paleogene. The major oil-producing strata in the depression are mudstone and shale. To explore the burial diagenetic history of the basin and the formation thresholds of hydrocarbons, the characters of the kaolinite subgroup minerals and mixed-layer illite/smectite in the mudstone and the shale are studied by using X-ray diffraction, electron probe, scanning electron microscope, and Fourier infrared spectrum. The kaolinite subgroup consists of kaolinite and halloysite. The kaolinite is flake-like or vermiform-like. The halloysite is in long tubular shape and its length is related to its iron content. A longer tube has lower iron content. The crystallinity of kaolinite is 0.40 °2θ, and its degree of order increases from 0.03 to 1.17 with the burial depth. Kaolinite is in disorder when the buried depth is less than or equal to 2479 m, and it is partially ordered when the buried depth is greater than 2479 m. Kaolinite is supposed to turn into dickite when the depth is greater than 2550 m, but low penetrability and low porosity of the shale and mudstone prevent such a change. The mixed-layer illite/smectite changes from disorder to order continually as the buried depth increases. Its disorder (R 0I/S), as defined by illite layer content (I%), is smaller than 50% at depths less than 2550.25 m. Based on Hoffman & Hower’s model, the paleo-geothermal gradients of 3.37–3.76°C/100 m (3.57°C /100 m on average) can be derived in the Paleocene Damintun Depression, which is significantly higher than the present geothermal gradient (2.9°C/100 m). The threshold depth of the oil formation in the depression is about 2550 m.
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References
Hoffman J, Hower J. Clay mineral assemblages as low grade metamorphic geothermometers: Application to the thrust-faulted disturbed belt of Montana, U.S.A.. In: Schoole, P A, et al. eds. Aspects of Diagenesis. SEPM Spec, 1979, 26: 55–79
Cathelineau M, Nieva D A. Cation site occupancy in chlorites and illites as a function of temperature. Clay Miner, 1988, 23: 471–485
Harvey C C, Browne P R L. Mixed-layer clay geothermometry in the Wairakei geothermal field, New Zealand. Clays Clay Miner, 1991, 39: 614–621
Kirsten L P, Mcdowell S D. Illite/smectite geothermometry of the Proterozoic Oronto Group, midcontinent rift system. Clays Clay Miner, 1993, 41: 134–147
Pollastro R M. Considerations and applications of the illite/smectite geothermometer in hydrocarbon bearing rocks of Micene to Mississippian age. Clays Clay Miner, 1993, 41: 119–133
Zhao M, Chen X M, Ji J F, et al. Evolution of chlorite composition in the Paleogene prototype basin of Jiyang Depression, Shandong, China, and its implication for paleogeothermal gradient. Sci China Ser D-Earth Sci, 2007, 50: 1645–1654
Zhao M, Chen X M, Ji J F, et al. Diagenetic and paleogeothermal evolution of the clay minerals in the Paleogene Changwei prototype basin of Shandong Province, China (in Chinese). Acta Petrol Sin, 2006, 22: 2195–2204
Claire-Isabelle F, Juraj M, Daniel B, et al. New thermochemical evidence on the stability of dickite vs. kaolinite. Amer Miner, 2003, 88: 837–845
Joussein E, Petit S, Churchman J, et al. Halloysite clay minerals —A review. Clay Miner, 2005, 40: 383–426
Murray H H. Kaolin minerals: their genesis and occurrences. In: Bailey S W, ed. Hydrous Phyllosilicates (Exclusive of Micas). Washington, D.C.: Reviews in Mineralogy, 19. Miner Soc Amer, 1988. 67–89
Ruiz Cruz M D, Moreno Real L. Diagenetic kaolinite/dickite (Betic Cordilleras, Spain). Clays Clay Miner, 1993, 41: 570–579
Beaufort D, Cassagnabère A, Petit S, et al. Kaolinite-to-dickite reaction in sandstone reservoirs. Clay Miner, 1998, 33: 297–316
Anovitz L M, Perkins D, Essene E J. Metastability in near-surface rocks in the system Al2O3-SiO2-H2O. Clays Clay Miner, 1991, 39: 225–233
de Ligny D, Navrotsky A. Energetics of kaolin polymorphs. Amer Miner, 1999, 84: 506–516
Fialips C I, Navrotsky A, Petit S. Crystal properties and energetics of synthetic kaolinite. Amer Miner, 2001, 86: 304–311
Ruiz Cruz M D, Reyes E. Kaolinite and dickite formation during shale diagenesis: Isotopic data. Appl Geochem, 1998, 13: 95–104
Jiang J Q, Li J, Shi J N, et al. Geothermal characteristics of Damingtun sag and its significance for petroleum accumulation (in Chinese). Acta Sediment Sin, 2004, 22: 541–546
Chen Z Y, Chen Y C, Guo Y M, et al. Some Recognitions and Practices of Precised Explorations in Damintun Sag (in Chinese). Beijng: Petroleum Industry Press, 2007. 3–19
Shi Y R, Xie Q B, Pen S M, et al. Research in sequence stratigraphy of Sha-4 Formation in Damintun Sag (in Chinese). J Xi’an Shiyou Univ (Nat Sci Ed), 2007, 22: 14–18
Shi J N, Jiang J Q, Lu C G, et al. The characteristics and origin of overpressure in damingtun depression of Liaohe Basin and petroleum exploration significance (in Chinese). Mar Petrol, 2004, 24: 19–24
Xie W Y, Jiang J Q, Shi J N. Evolution of geopressure field in Damintun Sag and its significance on hydrocarbon accumulation (in Chinese). Acta Petrol Sin, 2004, 25: 48–52
Warr L N, Rice A H N. Inter laboratory standardization and calibration of clay mineral crystallinity and crystallite size data. J Metamorp Geol, 1994, 2: 141–152
Biscaye P E. Mineralogy and sedimentation of recent deep-sea clay in the Atlantic Ocean and adjacent seas and oceans. Geol Soc Amer Bull, 1965, 6: 803–831
Bauluz B, Mayayo M J, Yuste A, et al. Genesis of kaolinite from Albian sedimentary deposits of the Iberian Range (NE Spain): Analysis by XRD, SEM and TEM. Clay Miner, 2008, 43: 459–475
Cases J M, Liètard O, Yvon J, et al. Etude des propiétés cristallochimiques, morphologiques, superficielles de kaolinites désordonneés. Bull Miner, 1982, 105: 439–455
Kemp S J, Merriman R J, Bouch J E. Clay mineral reaction progress —The maturity and burial history of the Lias Group of England and Wales. Clay Miner, 2005, 40: 43–61
Zhao X Y. Discussion on the effect of clay minerals in primary migration of petroleum (in Chinese). Acta Sediment Sin, 1990, 8: 67–73
Liu L Y, Liu Y Q, Chen G. Property and diagenitic significance of authigenic clay mineral in upper and middle Jurassic clastic rock of tulufan depression, Xinjiang (in Chinese). Acta Petrol Sin, 1998, 14: 258–268
Waples D W. Time and temperature in petroleum formation: Application of Lopatin’s method to petroleum exploration. Amer Assoc Petrol Geol Bull, 1980, 64: 916–926
Rice D D, Claypool G E. Generation,accumulation,and resource potential of biogenic gas. Amer Assoc Petrol Geol Bull, 1981, 64: 5–25
Tissot B P, Welte D H. Petroleum Formation and Occurrence. Berlin: Springer-Verlag, 1984. 539
Shi J N, Jiang J Q. The research of paleotemperature in Damintun Depression with the apatite fission track method (in Chinese). Petrol Geol Oilfield Dev Daqing, 2003, 22: 18–21
Lee S Y, Gilkes R J. Groundwater geochemistry and composition of hardpans in southwestern Australian regolith. Geoderma, 2005, 126: 59–84
Sieffermann G, Millot G. L’halloysite des sols jeunes sur basaltes récents du centre Cameroun. Bull du Groupe Français des Argiles, 1968, 20: 25–38
Bailey S W. Structures of layer silicates. In: Brindley G W, Brown G, eds. Crystal Structures of Clay Minerals and Their X-ray Identification. London: Mineralogical Society, 1980. 1–123
Churchman G J, Carr R M. The definition and nomenclature of halloysites. Clays Clay Miner, 1975, 23: 382–388
Hart R D, Gilkes R J, Siradz S, et al. The nature of soil kaolins from Indonesia and Western Australia. Clays Clay Miner, 2002, 50: 198–207
Noro H. Hexagonal platy halloysite in an altered tuff bed, Komaki city, Aichi prefecture, Central Japan. Clay Miner, 1986, 21: 401–415
Robertson I D M, Eggleton R A. Weathering of granitic muscovite to kaolinite and halloysite and plagioclase-derived kaolinite to halloysite. Clays Clay Miner, 1991, 39: 113–126
Noro H, Yamada K, Suzuki K. An application of electron probe microanalysis for clay minerals (in Japanese). Kobutsugaku Zasshi, 1981, 15: 42–54
Churchman G J, Davy T J, Aylmore L A G, et al. Characteristics of fine pores in some halloysites. Clay Miner, 1995, 30: 89–98
Adamo P, Violante P, Wilson M J. Tubular and spheroidal halloysite in pyroclastic deposits in the area of the Roccamonfina volcano (southern Italy). Geoderma, 2001, 99: 295–316
Carson C D, Kunze G W. New occurrences of tabular halloysite. Soil Sci Soc Amer Proc, 1970, 34: 538–540
Ross G J, Kodama H, Wang C, et al. Halloysite from a strongly weathered soil at mont Jacques Cartier, Quebec. Soil Sci Soc Amer J, 1983, 47: 327–332
Churchman G J, Theng B K G. Interactions of halloysites with amides: Mineralogical factors affecting complex formation. Clay Miner, 1984, 19: 161–175
Saigusa M, Shoji S, Kato T. Origin and nature of halloysite in ando soils from Towada tephra, Japan. Geoderma, 1978, 20: 115–129
Singh B, Gilkes R J. An electron optical investigation of the alteration of kaolinite to halloysite. Clays Clay Miner, 1992, 40: 212–229
Eggleton R A, Tilley D B. Hisingerite: A ferric kaolin mineral with curved morphology. Clays Clay Miner, 1998, 46: 400–413
Dixon J B. Kaolin and serpentine group minerals. In: Dixon J B, Weed S B, eds. Minerals in Soil Environments. 2nd ed. Soil Sci Soc Amer, Madison, Wisconsin, 1989. 467–526
Fialips C I. Juraj Majzlan, Daniel Beaufort and Alexandra Navrotsky. New thermochemical evidence on the stability of dickite vs. kaolinite. Amer Miner, 2003, 88: 837–845
Beaufort D, Cassagnabère A, Petit S, et al. Kaolinite-to-dickite reaction in sandstone reservoirs. Clay Miner, 1998, 33: 97–316
Lanson B, Beaufort D, Berger G, et al. Authigenic kaolin and illitic minerals during burial diagenesis of sandstones: A review. Clay Miner, 2002, 37: 1–22
Shutov V D, Aleksandrova A V, Losievskaya S A. Genetic interpretation of the polytypism of the kaolinite group in sedimentary rocks. Sedimentology, 1970, 15: 9–82
Brindley G W, Kao C, Harrison J L, et al. Relation between structural disorder and other characteristics of kaolinites and dickites. Clays Clay Miner, 1986, 34: 239–249
Beaufort D, Cassagnabere A, Petit S, et al. Kaolinite to dickite reaction in sandstone reservoirs. Clay Miner, 1998, 33: 297–316
Ehrenberg S N, Aagaard P, Wilson M J, et al. Depth-dependent transformation of kaolinite to dickite in sandstones of the Norwegian Continental shelf. Clay Miner, 1993, 28: 325–352
McAulay G E, Burley S D, Johnes L H. Silicate mineral authigenesis in the Hutton and NW Hutton fields: Implications for sub-surface porosity development. In: Parker J R, ed. Petroleum Geology of Northwest Europe. London: Geol Soc, 1993. 1377–1394
McAulay G E, Burley S D, Fallick A E, et al. Palaeohydrodynamic fluid flow regimes during diagenesis of the Brent Group in the Hutton-NW Hutton reservoirs: constraints from oxygen isotope studies of authigenic kaolin and reverse flexural modelling. Clay Miner, 1994, 29: 609–626
Whitney G. Role of water in the smectite-to-illite reaction. Clays Clay Miner, 1990, 38: 343–350
Cassan J P, Lucas J. La diagenèse des grès argileux d’Hassi-Messaoud (Sahara): Silicification et dickitisation. Bull Service Carte Géologie Alsace Lorraine, 1966, 19: 241–253
Zimmerle W, Rösch H. Petrogenetic significance of dickite in European sedimentary rocks. Zentralblatt für Geologie und Palaontologie, 1991, 1: 1175–1196
McKenzie D P. Some remarks on the development of sedimentary basins. Earth Planet Sci Lett, 1978, 40: 25–32
Zhou Y S, Little R. Numerical simulation of the thermal maturation, oil generation and migration in the Songliao Basin, Northeastern China. Mar Petrol Geol, 1999, 16: 771–792
Xie X N, Jiao J J, Tang Z H, et al. Evolution of abnormally low pressure and its implications for the hydrocarbon system in the southeast uplift zone of Songliao Basin, China. Amer Assoc Petrol Geol Bull, 2003, 87: 99–119
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Zhao, M., Ji, J., Chen, Z. et al. Evolution of kaolinite subgroup minerals and mixed-layer illite/smectite in the Paleogene Damintun Depression in Liaohe Basin of China and its implication for paleotemperature. Sci. China Earth Sci. 54, 73–83 (2011). https://doi.org/10.1007/s11430-010-4080-2
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DOI: https://doi.org/10.1007/s11430-010-4080-2