Abstract
Supramolecular self-assembly, an important strategy in nanotechnology, has been widely studied in the past two decades. In this review, we have introduced the recent progress on construction of two-dimensional (2D) nanostructures by host-guest supramolecular chemistry at solid-liquid interface, and the interactions between the host assembly and the guest molecules are the major concerns. At first, the hydrogen bonds connected hybrid structures are discussed. And then we have paid a close attention on the surface-confined condensation reactions that has flourished recently in direct preparing novel nanostructures with increasing structural complexity. In the end, the cavity confinement of the 2D supramolecular host-guest architectures has been studied. On the basis of the above-mentioned interactions, a group of functional hybrid structures have been prepared. Notably, scanning tunneling microscopy (STM), a unique technique to probe the surface morphology and information at the single molecule level, has been used to probe the formed structures on highly oriented pyrolytic graphite (HOPG) surface.
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Shimomura M, Sawadaishi T. Bottom-up strategy of materials fabrication: A new trend in nanotechnology of soft materials. Curr Opin Colloid Interface Sci, 2001, 6: 11–16
Geissler M, Xia YN. Patterning: Principles and some new develop ments. Adv Mater, 2004, 16: 1249–1269
Philp D, Stoddart JF. Self-assembly in natural and unnatural systems. Angew Chem Int Ed, 1996, 35: 1155–1196
Barth JV, Costantini G, Kern K. Engineering atomic and molecular nanostructures at surfaces. Nature, 2005, 437: 671–679
Blake AJ, Champness NR, Hubberstey P, Li WS, Withersby MA, Schroder M. Inorganic crystal engineering using self-assembly of tailored building-blocks. Coord Chem Rev, 1999, 183: 117–138
Leininger S, Olenyuk B, Stang PJ. Self-assembly of discrete cyclic nanostructures mediated by transition metals. Chem Rev, 2000, 100: 853–908
Lehn JM. Perspectives in supramolecular chemistry—From molecular recognition towards molecular information processing and self-organization. Angew Chem Int Ed, 1990, 29: 1304–1319
Jin X, Yang S, Li Z, Liu KS, Jiang L. Bio-inspired special wetting surfaces via self-assembly. Sci China Chem, 2012, 55: 2327–2333
Decher G. Fuzzy nanoassemblies: Toward layered polymeric multicomposites. Science, 1997, 277: 1232–1237
Zhang SG. Fabrication of novel biomaterials through molecular self-assembly. Nature Biotechnol, 2003, 21: 1171–1178
Xiong YS, Tang ZY. Role of self-assembly in construction of inorganic nanostructural materials. Sci China Chem, 2012, 55: 2272–2282
Rosler A, Vandermeulen GWM, Klok HA. Advanced drug delivery devices via self-assembly of amphiphilic block copolymers. Adv Drug Delivery Rev, 2001, 53: 95–108
Fendler JH. Self-assembled nanostructured materials. Chem Mater, 1996, 8: 1616–1624
Smith RK, Lewis PA, Weiss PS. Patterning self-assembled monolayers. Prog Surf Sci, 2004, 75: 1–68
Hu S, Wang X. From cluster assembly to ultrathin nanocrystals and complex nanostructures. Sci China Chem, 2012, 55: 2257–2271
Yu Z, Lu K, Wei ZX. Self-assembly of conjugated polymers for anisotropic nanostructures. Sci China Chem, 2012, 55: 2283–2291
Cao AM, Hu JS, Wan LJ. Morphology control and shape evolution in 3D hierarchical superstructures. Sci China Chem, 2012, 55: 2249–2256
Bishop KJM, Wilmer CE, Soh S, Grzybowski BA. Nanoscale forces and their uses in self-assembly. Small, 2009, 5: 1600–1630
Prins LJ, Reinhoudt DN, Timmerman P. Noncovalent synthesis using hydrogen bonding. Angew Chem Int Ed, 2001, 40: 2382–2486
Wurthner F, You CC, Saha-Moller CR. Metallosupramolecular squares: From structure to function. Chem Soc Rev, 2004, 33: 133–146
Zhang DW, Zhao X, Hou JL, Li ZT. Aromatic amide foldamers: Structures, properties, and functions. Chem Rev, 2012, 112: 5271–5316
Claessens CG, Stoddart JF. π-π Interactions in self-assembly. J Phys Org Chem, 1997, 10: 254–272
Gale PA, Quesada R, Anion coordination and anion-templated assembly: Highlights from 2002 to 2004. Coord Chem Rev, 2006, 250: 3219–3244
Faul CFJ, Antonietti M. Metal nuclearity modulated four-, six-, and eight-connected entangled frameworks based on mono-, bi-, and trimetallic cores as nodes. Chem Eur J, 2006, 12: 2680–2691
Mali KS, Adisoejoso J, Ghijsens E, de Cat I, de Feyter S. Exploring the complexity of supramolecular interactions for patterning at the liquid-solid interface. Acc Chem Res, 2012, 45: 1309–1320
Ciesielski A, Samorì P. Supramolecular assembly/reassembly processes: Molecular motors and dynamers operating at surfaces. Nanoscale, 2011, 3: 1397–1410
Xu L, Miao XR, Zhao B, Deng WL. Hydrogen-bonding-induced polymorphous phase transitions in 2D organic nanostructures. Chem-Asian J, 2013, 8, 5: 926–933
Xu LR, Yang L, Cao LL, Li T, Chen SS, Zhao DH, Lei SB, Ma J. Effect of bulky substituents on the self-assembly and mixing behavior of arylene ethynylene macrocycles at the solid/liquid interface. Phys Chem Chem Phys, 2013, 15: 11748–11757
Mamdouh W, Uji-i H, Ladislaw JS, Dulcey AE, Percec V, de Schryver FC, de Feyter S. Solvent controlled self-assembly at the liquid/solid interface revealed by STM. J Am Chem Soc, 2006, 128: 317–325
Yang YL, Wang C. Solvent effects on two-dimensional molecular self-assemblies investigated by using scanning tunneling microscopy. Curr Opin Colloid Interface Sci, 2009, 14: 135–147
Shen YT, Zhu NB, Zhang XM, Deng K, Feng W, Yan QF, Lei SB, Zhao DH, Zeng QD, Wang C. A foldamer at the liquid/graphite interface: The effect of interfacial interactions, solvent, concentration and temperature. Chem Eur J, 2011, 17: 7061–7068
Zhang XM, Xu HJ, Shen YT, Wang YB, Shen Z, Zeng QD, Wang C. Solvent dependent supramolecular self-assembly and surface reversal of a modified porphyrin. Phys Chem Chem Phys, 2013, 15: 12510–12515
Balandina T, Tahara K, Sandig N, Blunt MO, Adisoejoso J, Lei S, Zerbetto F, Tobe Y, de Feyter S. Role of substrate in directing the self-assembly of multicomponent supramolecular networks at the liquid-solid interface. ACS Nano, 2012, 6: 8381–8389
Zhang XM, Zeng QD, Wang C. Reversible phase transformation at solid-liquid interface: STM reveals. Chem Asian J, 2013: doi: 10.1002/asia.201300605
Gutzler R, Sirtl T, Dienstmaier JF, Mahata K, Heckl WM, Schmittel M, Lackinger M. Reversible phase transitions in self-assembled monolayers at the liquid-solid interface: Temperature-controlled opening and closing of nanopores. J Am Chem Soc, 2010, 132: 5084–5090
Lei SB, Deng K, Yang YL, Zeng QD, Wang C, Jiang JZ. Assembling of asymmetric tris(phthalocyaninato) lutetium triple-decker complex at the solid/liquid interface: Recognition of isomerization and electric driven molecular switches. Nano Lett, 2008, 8: 1836–1843
Ciesielski A, Lena S, Masiero S, Spada GP, Samorì P. Dynamers at the solid-liquid interface: Controlling the reversible assembly/reassembly process between two highly ordered supramolecular guanine motifs. Angew Chem Int Ed, 2010, 49: 1963–1966
Mali KS, Wu DQ, Feng XL, Müllen K, van der Auweraer M, de Feyter S. Scanning tunneling microscopy-induced reversible phase transformation in the two-dimensional crystal of a positively charged discotic polycyclic aromatic hydrocarbon. J Am Chem Soc, 2011, 133: 5686–5688
Bleger D, Clesielki A, Samori P, Hecht S. Photoswitching vertically oriented azobenzene self-assembled monolayers at the solid-liquid interface. Chem Eur J, 2010, 16: 14256–14260
Xu L, Miao XR, Ying X, Deng WL. Two-dimensional self-assembled molecular structures formed by the competition of van der waals forces and dipole-dipole interactions. J Phys Chem C, 2012, 116: 1061–1069
Li M, Xu HJ, Shen Z, You XZ, Zeng QD, Wang C. Bipyridine mediated assembling characteristics of aromatic acid derivatives. J Phys Chem C, 2010, 114: 1881–1884
Lei SB, Wan LJ, Wang C, Bai CL. Direct observation of the ordering and molecular folding of poly[(m-phenylenevinylene)-co-(2,5-dioctoxy-p-phenylenevinylene)]. Adv Mater, 2004, 16: 828–831
Qiu XH, Wang C, Zeng QD, Xu B, Yin SX, Wang H, Xu SL, Bai CL. Alkane-assisted adsorption and assembly of phthalocyanines and porphyrins. J Am Chem Soc, 2000, 122: 5550–5556
Nath KG, Ivasenko O, Miwa JA, Dang H, Wuest JD, Nanci A, Perepichka DF, Rosei F. Rational modulation of the periodicity in linear hydrogen-bonded assemblies of trimesic acid on surfaces. J Am Chem Soc, 2006, 128: 4212–4213
Lu J, Zeng QD, Wang C, Zheng QY, Wan LJ, Wan CL. Self-assembled two-dimensional hexagonal networks. J Mater Chem, 2002, 12: 2856–2858
Baalousha M, Motelica-Heino M, Galaup S, Le Coustumer P. Supramolecular structure of humic acids by TEM with improved sample preparation and staining. Microsc Res Tech, 2005, 66: 299–306
Hightower JB, Olmos DR, Walmsley JA. Supramolecular structure and polymorphism of alkali metal salts of guanosine 5′-monophosphate: SEM and NMR study. J Phys Chem B, 2009, 113: 12214–12219
Chung WJ, Oh JW, Kwak K, Lee BY, Meyer J, Wang E, Hexemer A, Lee SW. Biomimetic self-templating supramolecular structures. Nature, 2011, 478: 364–368
Ye M, Zhang Y, Li H, Xie M, Hu J, Supramolecular structures of amyloid-related peptides in an ambient water nanofilm. J Phys Chem B, 2012, 114: 15759–15765
Liu L, Zhang L, Niu L, Xu M, Mao XB, Yang YL, Wang C. Observation of reduced cytotoxicity of aggregated amyloidogenic peptides with chaperone-like molecules. ACS Nano, 2011, 5: 6001–6007
Mao XB, Wang CX, Wu XK, Ma XJ, Liu L, Zhang L, Niu L, Guo YY, Li DH, Yang YL, Wang C. Beta structure motifs of islet amyloid polypeptides identified through surface-mediated assemblies. Proc Natl Acad Sci USA, 2011, 108: 19605–19610
Zhan D, Liu L, Xu YN, Ni ZH, Yan JX, Zhao C, Shen ZX. Low temperature edge dynamics of AB-stacked bilayer graphene: Naturally favored closed zigzag edges. Sci Rep, 2011, 1: 12
Binning G, Rohrer H, Gerbe C, Weibel E. Surface studies by scanning tunneling microscopy. Phys Rev Lett, 1982, 49: 57–61
Binnig G, Rohrer H. Scanning tunneling microscopy—From birth to adolescence. Rev Mod Phys, 1987, 59: 615–625
de Feyter S, de Schryver FC. Two-dimensional supramolecular self-assembly probed by scanning tunneling microscopy. Chem Soc Rev, 2003, 32: 139–150
de Feyter S, de Schryver FC. Self-assembly at the liquid/solid interface: STM reveals. J Phys Chem B, 2005, 109: 4290–4302
Mali KS, Adisoejoso J, Ghijsens E, de Cat I, de Feyter S. Exploring the complexity of supramolecular interactions for patterning at the liquid-solid interface. Acc Chem Res, 2012, 45: 1309–1320
Xu LR, Yang L, Lei SB. Self-assembly of conjugated oligomers and polymers at the interface: Structure and properties. Nanoscale, 2012, 4: 4399–4415
Lei SB, Tahara K, Feng XL, Furukawa S, de Schryver FC, Müllen K, Tobe Y, de Feyter S. Molecular clusters in two-dimensional surface-confined nanoporous molecular networks: Structure, rigidity, and dynamics. J Am Chem Soc, 2008, 130: 7119–7129
Furukawa S, de Feyter S. Two-dimensional crystal engineering at the liquid-solid interface. Top Curr Chem, 2009, 287: 87–133
Liang HL, He Y, Ye Y, Xu X, Cheng F, Sun W, Shao X, Wang Y, Li J, Wu K. Two-dimensional molecular porous networks constructed by surface assembling. Coord Chem Rev, 2009, 253: 2959–2979
Besenbacher F, Lauritsen JV, Linderoth TR, Lægsgaard E, Vang RT, Wendt S. Atomic-scale surface science phenomena studied by scanning tunneling microscopy. Sur Sci, 2009, 603: 1315–1327
Yang YL, Wang C. Hierarchical construction of self-assembled low-dimensional molecular architectures observed by using scanning tunneling microscopy. Chem Soc Rev, 2009, 38: 2576–2589
Otsuki J. STM studies on porphyrins. Coord Chem Rev, 2010, 254: 2311–2341
de Feyter S, GesquièRe A, Mottaleb MMA, Grim PCM, de Schryver FC. Scanning tunneling microscopy: A unique tool in the study of chirality, dynamics, and reactivity in physisorbed organic monolayers. Acc Chem Res, 2000, 33: 520–531
Vang RT, Lauritsen JV, Læsgaard E, Besenbacher F. Scanning tunneling microscopy as a tool to study catalytically relevant model systems. Chem Soc Rev, 2008, 37: 2191–2203
Rossel F, Pivetta M, Schneider WD. Luminescence experiments on supported molecules with the scanning tunneling microscope. Sur Sci Rep, 2010, 65: 129–144
Xie RS, Song YH, Wan LL, Yuan HZ, Li PC, Xiao XP, Liu L, Ye SH, Lei SB, Wang L. Two-dimensional polymerization and reaction at the solid/liquid interface: Scanning tunneling microscopy study. Anal Sci, 2011, 27: 129–138
Okawa Y, Mandal SK, Hu C, Tateyama Y, Goedecker S, Tsukamoto S, Hasegawa T, Gimzewski JK, Aono M. Chemical wiring and soldering toward all-molecule electronic circuitry. J Am Chem Soc, 2011, 133: 8227–8233
Mielke J, Leyssner F, Koch M, Meyer S, Luo Y, Selvanathan S, Haag R, Tegeder P, Grill L. Imine derivatives on Au(111): Evidence for “inverted” thermal isomerization. ACS Nano, 2011, 5: 2090–2097
Grill L, Dyer M, Lafferentz L, Persson M, Peters MV, Hecht S. Nano-architectures by covalent assembly of molecular building blocks. Nat Nanotechnol, 2007, 2: 687–691
Zhang XM, Xu SD, Li M, Shen YT, Wei ZQ, Wang S, Zeng QD, Wang C. Photo-induced polymerization and isomerization on the surface observed by scanning tunneling microscopy. J Phys Chem C, 2012, 116: 8950–8955
Zhong DY, Franke JH, Podiyanachari SK, Blömker T, Zhang HM, Kehn G, Erker G, Chi LF. Linear alkane polymerization on a gold surface. Science, 2011, 334: 213–216
Tahara K, Yamaga H, Ghijsens E, Inukai K, Adisoejoso J, Blunt MO, de Feyter S, Tobe Y. Control and induction of surface-confined homochiral porous molecular networks. Nat Chem, 2011, 3: 714–719
de Cat I, Guo ZX, George SJ, Meijer EW, Schenning APHJ, de Feyter S. Induction of chirality in an achiral monolayer at the liquid/solid interface by a supramolecular chiral auxiliary. J Am Chem Soc, 2012, 134: 3171–3177
Cai JM, Ruffieux P, Jaafar R, Bieri M, Braun T, Blankenburg S, Muoth M, Seitsonen AP, Saleh M, Feng XL, Müllen K, Fasel R. Atomically precise bottom-up fabrication of graphene nanoribbons. Nature, 2010, 466: 470–473
Zhang YQ, Kepčija N, Kleinschrodt M, Diller K, Fischer S, Papageorgiou AC, Allegretti F, Björk J, Klyatskaya S, Klappenberger F, Ruben M, Barth JV. Homo-coupling of terminal alkynes on a noble metal surface. Nat Commun, 2012, 3: 1286
Bebensee F, Bombis C, Vadapoo SR, Cramer JR, Besenbacher F, Gothelf KV, Linderoth TR. On-surface azide-alkyne cycloaddition on Cu(111): Does it “click” in ultrahigh vacuum? J Am Chem Soc, 2012, 135: 2136–2139
Zhang XM, Zeng QD, Wang C. Molecular templates and nano-reactors: Two-dimensional hydrogen bonded supramolecular networks on solid/liquid interfaces. RSC Adv, 2013, 3: 11351–11366
Elemans JAAW, Lei SB, de Feyter S. Molecular and Supramolecular Networks on surfaces: From two-dimensional crystal engineering to reactivity. Angew Chem Int Ed, 2009, 48: 7298–7332
Li M, Zeng QD, Wang C. Self-assembled supramolecular networks at interfaces: Molecular immobilization and recognition using nanoporous templates. Sci China Phys Mech Astron, 2011, 54: 1739–1748
Zeng QD, Wang C. Construction of tunable supramolecular networks studied by scanning tunneling microscopy. Sci China Chem, 2010, 53: 310–317
Zhang, XM, Zeng QD, Wang C. On-surface single molecule synthesis chemistry: A promising bottom-up approach towards functional surfaces. Nanoscale, 2013, 5: 8269–8287
Zhang XM, Wang S, Shen YT, Yang YL, Deng K, Zhao KQ, Zeng QD, Wang C. Triphenylene substituted pyrene derivative: Synthesis and single molecule investigation. J Phys Chem C, 2013, 117: 307–312
Qiu XH, Nazin GV, Ho W. Vibrationally resolved fluorescence excited with submolecular precision. Science, 2003, 299: 542–546
Lei SB, Deng K, Yang DL, Zeng QD, Wang C. Charge-transfer effect at the interface of phthalocyanine-electrode contact studied by scanning tunneling spectroscopy. J Phys Chem B, 2006, 110: 1256–1260
Kong XH, Wang M, Lei SB, Yang YL, Wang C. Electronic sensory behavior of titanylphthalocyanine revealed by scanning tunneling spectroscopy and cyclic voltammetry methods. J Mater Chem, 2006, 16: 4265–4269
Fischer O, Kygler M, Maggio-Aprile I, Berthod C, Renner C. Scanning tunneling spectroscopy of high-temperature superconductors. Rev Mod Phys, 2007, 79: 353–419
Griessl SJH, Lackinger M, Jamitzky F, Markert T, Hietschold M, Heckl WM. Room-temperature scanning tunneling microscopy manipulation of single C60 molecules at the liquid-solid interface: Playing nanosoccer. J Phys Chem B, 2004, 108: 11556–11560
Griessl SJH, Lackinger M, Jamitzky F, Markert T, Hietschold M, Heckl WM. Incorporation and manipulation of coronene in an organic template structure. Langmuir, 2004, 20: 9403–9407
Nath KG, Ivasenko O, Miwa JA, Dang H, Wuest JD, Nanci A, Perepichka DF, Rosei F. Rational modulation of the periodicity in linear hydrogen-bonded assemblies of trimesic acid on surfaces. J Am Chem Soc, 2006, 128: 4212–4213
Li M, Yang YL, Zhao KQ, Zeng QD, Wang C. Bipyridine-mediated assembling characteristics of aromatic acid derivatives. J Phys Chem C, 2008, 112: 10141–10144
Li M, Deng K, Lei SB, Yang YL, Wang TS, Shen YT, Wang CR, Zeng QD, Wang C. Site-selective fabrication of two-dimensional fullerene arrays by using a supramolecular template at the liquid-solid interface. Angew Chem Int Ed, 2008, 47: 6717–6721
Zhang XM, Wang S, Shen YT, Guo YY, Zeng QD, Wang C. Two-dimensional networks of an azobenzene derivative: Bi-pyridine mediation and photo regulation. Nanoscale, 2012, 4: 5039–5042
Li YB, Deng K, Wu XK, Lei SB, Zhao KQ, Yang YL, Zeng QD, Wang C. Molecular arrays formed in anisotropically rearranged supramolecular network with molecular substitutional asymmetry. J Mater Chem, 2010, 20: 9100–9103
Li YB, Zhao KQ, Yang YL, Deng K, Zeng QD, Wang C. Functionalization of two-component molecular networks: Recognition of Fe3+. Nanoscale, 2012, 4: 148–151
Li YB, Wan JH, Deng K, Han XN, Lei SB, Yang YL, Zheng QY, Zeng QD, Wang C. Transformation of self-assembled structure by the addition of active reactant. J Phys Chem C, 2011, 115: 6540–6544
Tanoue R, Higuchi R, Enoki N, Miyasato Y, Uemura S, Kimizuka N, Stieg AZ, Gimzewski JK, Kunitake M. Termodynamically controlled self-assembly of covalent nanoarchitectures in aqueous solution. ACS Nano, 2011, 5: 3923–3929
Hu FY, Zhang XM, Wang XC, Wang S, Wang HQ, Duan WB, Zeng QD, Wang C. In situ STM investigation of two-dimensional chiral assemblies through schiff-base condensation at a liquid/solid interface. ACS Appl Mater Interfaces, 2013, 5: 1583–1587
Lei SB, Deng K, Ma Z, Huang W, Wang C. Templated assembling of phthalocyanine arrays along a polymer chain. Chem Commun, 2011, 47: 8829–8831
Shen YT, Deng K, Li M, Zhang XM, Zhou G, Müllen K, Zeng QD, Wang C. Self-assembling in fabrication of ordered porphyrins and phthalocyanines hybrid nano-arrays on HOPG. CrystEngComm, 2013, 15: 5526–5531
Shen YT, Li M, Guo YY, Deng K, Zeng QD, Wang C. The site-selective molecular recognition of ternary architectures by using supramolecular nanoporous networks at a liquid-solid interface. Chem Asian J, 2010, 5: 787–790
Lu J, Lei SB, Zeng QD, Kang SZ, Wang C, Wan LJ, Bai CL. Tem late-induced inclusion structures with copper(II) phthalocyanine and coronene as guests in two-dimensional hydrogen-bonded host networks. J Phys Chem B, 2004, 108: 5161–5165
Shen YT, Deng K, Zhang XM, Lei D, Xia Y, Zeng QD, Wang C. Selective and competitive adsorptions of guest molecules in phase-separated networks. J Phys Chem C, 2011, 115: 19696–19701
Shen YT, Zeng LJ, Lei D, Zhang XM, Deng K, Feng YY, Feng W, Lei SB, Li SF, Gan LH, Zeng QD, Wang C. Competitive adsorption and dynamics of guest molecules in 2D molecular sieves. J Mater Chem, 2011, 21: 8787–8791
Tahara K, Furukawa S, Uji-i H, Uchino T, Ichikawa T, Zhang J, Mamdouh W, Sonoda M, de Schryver FC, de Feyter S, Tobe Y. Molecular geometry directed Kagomé and honeycomb networks: Toward two-dimensional crystal engineering. J Am Chem Soc, 2006, 128: 3502–3503
Lei SB, Surin M, Tahara K, Adisoejoso J, Lazzaroni R, Tobe Y, de Feyter S. Programmable hierarchical three-component 2D assembly at a liquid-solid interface: Recognition, selection, and transformation. Nano Lett, 2008, 8: 2541–2546
Shen YT, Deng K, Zeng QD, Wang C. Size-selective effects on fullerene adsorption by nanoporous molecular networks. Small, 2010, 6: 76–80
Shen YT, Guan L, Zhang XM, Wang S, Gan LH, Zeng QD, Wang C. Site-selective effects on guest-molecular adsorption and fabrication of four-component architecture by higher order networks. Phys Chem Chem Phys, 2013, 15: 12475–12479
Shen YT, Guan L, Zhu XY, Zeng QD, Wang C. Submolecular observation of photosensitive macrocycles andtheir isomerization effects on host-guest network. J Am Chem Soc, 2009, 131: 6174–6180
Shen YT, Deng K, Zhang XM, Feng W, Zeng QD, Wang C, Gong JR. Switchable ternary nanoporous supramolecular network on photo-regulation. Nano Lett, 2011, 11: 3245–3250
Zhang XM, Shen YT, Wang S, Guo YY, Zeng QD, Wang C. One plus two: Supramolecular coordination in a nano-reactor on surface. Sci Rep, 2012, 2: 742
Zeng QD, Wu DX, Wang C, Lu J, Ma BC, Shu CY, Ma HW, Li Y, Bai CL. Bipyridine conformations control the solid-state supramolecular chemistry of zinc(II) phthalocyanine with bipyridines. CrystEngComm, 2005, 7: 243–248
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Zhang, X., Zeng, Q. & Wang, C. Host-guest supramolecular chemistry at solid-liquid interface: An important strategy for preparing two-dimensional functional nanostructures. Sci. China Chem. 57, 13–25 (2014). https://doi.org/10.1007/s11426-013-4975-9
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DOI: https://doi.org/10.1007/s11426-013-4975-9