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Two novel interpenetrated zinc(II) and cadmium(II) coordination polymers based on 4-imidazole-benzoate: Syntheses, crystal structures and properties

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Abstract

Two novel interpenetrated coordination polymers, [Zn(IBA)2] n (1) and {[Cd(IBA)2(H2O)]·4H2O} n (2), have been synthesized by using 4-imidazole-benzoic acid (HIBA) as ligand under hydrothermal conditions. Complex 1 crystallizes in a chiral space group and has a two-fold interpenetrated 2D network structure with (4,4) topology, while complex 2 is a 3D porous dia network with four nets interpenetrating each other. The SHG activity of 1 and the photoluminescent property of 2 have been investigated.

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Authors and Affiliations

  1. State Key Laboratory of Coordination Chemistry, Institute of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China

    ZhengShuai Bai, ShuiSheng Chen, ZhengHua Zhang, ManSheng Chen, GuangXiang Liu & WeiYin Sun

Authors
  1. ZhengShuai Bai
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  2. ShuiSheng Chen
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  3. ZhengHua Zhang
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  4. ManSheng Chen
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  5. GuangXiang Liu
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  6. WeiYin Sun
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Correspondence to WeiYin Sun.

Additional information

Supported by the National Natural Science Foundation of China (Grant Nos. 20731004 & 20721002) and the National Basic Research Program of China (Grant No. 2007CB925103)

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Bai, Z., Chen, S., Zhang, Z. et al. Two novel interpenetrated zinc(II) and cadmium(II) coordination polymers based on 4-imidazole-benzoate: Syntheses, crystal structures and properties. Sci. China Ser. B-Chem. 52, 459–464 (2009). https://doi.org/10.1007/s11426-009-0044-9

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  • DOI: https://doi.org/10.1007/s11426-009-0044-9

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