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Synthesis, crystal structures and fluorescence properties of four mixed-ligands Zn(II) and Cd(II) coordination compounds

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Abstract

Four new coordination compounds, [Zn(dba)(bpy)] n (1), {[Zn(dba)(phen)]·2H2O} n (2), [Cd(dba)(bpy)(H2O)2] (3) and [Cd2(dba)2(phen)2] n (4) (H2dba = 2,5-dihydroxy-p-benzenediacetic acid, bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline) have been prepared via solvothermal method and characterized by single-crystal X-ray diffraction, infrared spectroscopy, elemental analysis and powder X-ray diffraction. 1 and 2 possess 1D infinite chain structures. Complex 3 exhibits a mononuclear structure. Complex 4 owns binuclear symmetry units, which were bridged via the dba ligands forming a 2D framework. The fluorescence properties of 1–4 have been studied.

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, China

    LiMin Zhao, Peng Ren, ZhenJie Zhang, Ming Fang, Wei Shi & Peng Cheng

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  1. LiMin Zhao
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  2. Peng Ren
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  3. ZhenJie Zhang
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  4. Ming Fang
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  5. Wei Shi
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  6. Peng Cheng
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Correspondence to Peng Cheng.

Additional information

Supported by the National Natural Science Foundation of China (Grant No. 20631030), the Natural Science Foundation of Tianjin (Grant No. 08ZCGHHZ01100), and the Specialized Research Fund for the Doctoral Program of Higher Education (Grant No. 20060055039) of China

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Zhao, L., Ren, P., Zhang, Z. et al. Synthesis, crystal structures and fluorescence properties of four mixed-ligands Zn(II) and Cd(II) coordination compounds. Sci. China Ser. B-Chem. 52, 1479–1484 (2009). https://doi.org/10.1007/s11426-009-0204-y

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  • DOI: https://doi.org/10.1007/s11426-009-0204-y

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