Abstract
A one-dimensional Cd(II) complex [Cd(H3ODPT)2(MBTZ)2.2H2O]n (1) (MBTZ = 1,3-bis(1,2,4-triazol-1- yl-methyl)benzene, H4ODPT = 4,4′-oxydiphthalic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. Single crystal X-ray diffraction analysis reveals that complex 1 is a one-dimensional double chain polymer containing 24-membered rings with MBTZ ligands as the bridges arranged parallel to the b crystal direction, while the singly deprotonated H4ODPT ligands are extended on both sides of such double chains. In addition, the luminescence measurements reveal that complex 1 exhibits strong fluorescent emission in the solid state at room temperature.
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Original Russian Text © 2018 C. Yuan, S. N. Liu, X. J. Xu.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 8, pp. 1992–1997, November-December, 2018.
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Yuan, C., Liu, S.N. & Xu, X.J. Synthesis, Crystal Structure and Fluorescent Property of a Onedimensional Coordination Polymer Constructed By 1,3-Bis(1,2,4-Triazol-1-Ylmethyl)- Benzene And 4,4′-Oxydiphthalic Acid. J Struct Chem 59, 1928–1934 (2018). https://doi.org/10.1134/S0022476618080231
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DOI: https://doi.org/10.1134/S0022476618080231