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Quantifying effects of primary parameters on adsorption–desorption of atrazine in soils

  • SOILS, SEC 3 • REMEDIATION AND MANAGEMENT OF CONTAMINATED OR DEGRADED LANDS • RESEARCH ARTICLE
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Abstract

Purpose

Adsorption and desorption are important processes that influence the transport, transformation, and bioavailability of atrazine in soils. Equilibrium batch experiments were carried out to investigate the adsorption–desorption characteristics of atrazine. The objectives of this study were to (1) determine and quantify the main soil parameters governing atrazine adsorption and desorption phenomena; (2) find the correlativity between the identified soil parameters; and (3) investigate the universal desorption hysteresis traits.

Materials and methods

Fifteen soils with contrasting physico-chemical characteristics were collected from 11 provinces in eastern China. The equilibrium time was 24 h both for adsorption and desorption experiments. Atrazine was detected by Waters 2695/UV HPLC.

Results and discussion

Adsorption isotherms of atrazine could be well described by the Freundlich equation (r ≥ 0.994, p < 0.01). The total organic carbon (TOC) was the first independent variable that described 53.0 % of the total variability of K f, followed by the pH (9.9 %), and the clay (4.0 %) and silt (1.2 %) contents, separately; while the primary soil properties that affect desorption parameters included the TOC, pH, free Fe2O3 (Fed) and the sand content, with the biggest contribution achieved by the TOC (ranged from 48.5–78.1 %). The results showed that when the content ratio of clay to TOC (RCO) was less than 40, the atrazine adsorption was largely influenced by the organic matrix, while when the RCO was greater than 40, they were vital affected by the clay content.

Conclusions

Adsorption–desorption isotherms of atrazine in soils were nonlinear. The content of TOC, clay, and iron oxides, as well as the pH value were the key soil parameters affecting the adsorption–desorption of atrazine in soil, among which the RCO especially exhibited relevance. Additionally, the desorption hysteresis existed for atrazine retention in all 15 tested soils, and the hysteretic effect enhanced with the increasing time for desorption. This would be ascribed to the heterogeneity physical–chemical properties of these soils.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (40901113), the Natural Science Foundation of Guangdong Province (8451064001001121), the Project Supported by Zhejiang Provincial Natural Science Foundation of China (R5110079) and the Fundamental Research Funds for the Central Universities (2011FZA6020).

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Authors and Affiliations

  1. Key Laboratory of Plant Nutrition and Fertilizer in South Region, Ministry of Agriculture/Guangdong Key Laboratory of Nutrient Cycling and Farmland Conservation, Soil and Fertilizer Institute, Soil and Fertilizer Institute, Guangdong Academy of Agricultural Sciences, Guangzhou, 510640, People’s Republic of China

    Yufen Huang, Zhongzhen Liu, Fang Zeng & Ronghui Wang

  2. College of Environmental and Natural Resource Sciences, Zhejiang Provincial Key Laboratory of Subtropical Soil and Plant Nutrition, Zhejiang University, Hangzhou, 310058, People’s Republic of China

    Yan He

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  1. Yufen Huang
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  2. Zhongzhen Liu
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  3. Yan He
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  4. Fang Zeng
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  5. Ronghui Wang
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Correspondence to Zhongzhen Liu or Yan He.

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Huang, Y., Liu, Z., He, Y. et al. Quantifying effects of primary parameters on adsorption–desorption of atrazine in soils. J Soils Sediments 13, 82–93 (2013). https://doi.org/10.1007/s11368-012-0572-3

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  • DOI: https://doi.org/10.1007/s11368-012-0572-3

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