Abstract
The groundwater resources of mining areas have been in a challenging condition in terms of metal pollution and human health. Therefore, this study investigated the concentration of cobalt (Co), molybdenum (Mo), selenium (Se), tin (Sn), and antimony (Sb) in groundwater samples (wells, qanats, and springs) in a heavily contaminated mining district, South Khorasan, Eastern Iran. Human health risk of the studied metals to target groups was assessed, and water quality of the studied groundwater was investigated in the study area. A total of 367 sampling sites (279 wells, 74 qanats, and 14 springs) in South Khorasan Province were selected to collect the groundwater samples from June to July 2020. Sampling was performed thrice for each sampling point, and hydrochemical parameters were evaluated using a portable multiparameter. Inductively coupled plasma mass spectrometry (ICP-MS) was used to detect the metal concentrations. Results showed an order of Se > Mo > Sn > Co > Sb, and hazard index (HI) demonstrated a warning condition for south of South Khorasan (drinking application), southwest of South Khorasan (Irrigation application), and east and center of South Khorasan (drinking-irrigation application). Hydrochemical parameters showed a classification of “Na + K type” and “Mixed Ca–Mg–Cl type” with an overall group of “Na-Cl-HCO3” for sampled waters. Ficklin-Caboi diagram depicted a classification of “near-neutral low metal,” and Schoeller diagram classified studied groundwater as “good” for drinking and irrigation consumptions and “Na-Cl” type based on ion balance diagram. Based on the correlation analysis, positive relationships were recorded among EC, TDS, Cl−, Na+, sulfate, Ca2+, salt, total hardness, Mg2+, ammonia, and K+ measured in the water samples. In essence, arid regions of the world greatly rely upon groundwater resources for drinking and irrigation consumptions, and mining districts with a heavy load of active mines can be a serious threat to the groundwater quality and human health.
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References
Abraham MR, Susan TB (2017) Water contamination with heavy metals and trace elements from Kilembe copper mine and tailing sites in Western Uganda; implications for domestic water quality. Chemosphere 169:281–287. https://doi.org/10.1016/j.chemosphere.2016.11.077
Alshaebi FY, Yaacob WZW, Samsudin AR, Alsabahi E (2009) Risk assessment at abandoned tin mine in Sungai Lembing, Pahang, Malaysia. Electron J Geotech Eng 14 E:1–9
Amiri V, Bhattacharya P, Nakhaei M (2021) The hydrogeochemical evaluation of groundwater resources and their suitability for agricultural and industrial uses in an arid area of Iran. Groundw Sustain Dev 12:100527. https://doi.org/10.1016/j.gsd.2020.100527
APHA (2005) Standard Methods of Water and Wastewater, 21st edn. American Public Health Association, Washington DC, pp 2–61
APHA (2012) Standard Methods for the Examination of Water and Waste Water, 22nd edn. American Public Health Association, American Water Works Association, Water Environment Federation
Arefian FF, Hossein S, Moeini I (2020) Urban heritage along the silk roads. Springer. 2365–7588 (1). https://doi.org/10.1007/978-3-030-22762-3
Arya S, Subramani T, Karunanidhi D (2020) Delineation of groundwater potential zones and recommendation of artificial recharge structures for augmentation of groundwater resources in Vattamalaikarai Basin. South India Environ Earth Sci. https://doi.org/10.1007/s12665-020-8832-9
Asadi H, Soffianian A, Hemami MR et al (2022) A hybrid GIS-OWA and DANP method for the identification and evaluation of ecotourism attractions: the case study of Abbas Abad Wildlife Refuge, Iran. GeoJournal. https://doi.org/10.1007/s10708-021-10564-6
Atekwana EA, Atekwana EA, Rowe RS et al (2004) The relationship of total dissolved solids measurements to bulk electrical conductivity in an aquifer contaminated with hydrocarbon. J Appl Geophys 56:281–294. https://doi.org/10.1016/j.jappgeo.2004.08.003
Awadh SM, Al-Mimar H, Yaseen ZM (2021) Groundwater availability and water demand sustainability over the upper mega aquifers of Arabian Peninsula and west region of Iraq. Environ Dev Sustain. https://doi.org/10.1007/s10668-019-00578-z
Bakhshi A, Cecchini L, Ghanian M et al (2019) Sustainable irrigation management and farmers’ knowledge in South Khorasan. Iran Int J Sustain Soc 11:318–335. https://doi.org/10.1504/IJSSOC.2019.104567
Banan A, Forouharmehr A, Reza M, Esmaeilbeigi M, Bahmani M, Yazdani M, Kolok AS, Rogan EG (2022) Salinity gradients exacerbate the genotoxicity and bioaccumulation of silver nanoparticles in fingerling Persian sturgeon (Acipenser persicus). Reg Stud Mar Sci 52:102264. https://doi.org/10.1016/j.rsma.2022.102264
Behzadi Tayemeh M, Esmailbeigi M, Shirdel I, Joo HS, Johari SA, Banan A, Nourani H, Mashhadi H, Jami MJ, Tabarrok M (2020) Perturbation of fatty acid composition, pigments, and growth indices of Chlorella vulgaris in response to silver ions and nanoparticles: a new holistic understanding of hidden ecotoxicological aspect of pollutants. Chemosphere 238:124576. https://doi.org/10.1016/j.chemosphere.2019.124576
Bindal S, Singh CK (2019) Predicting groundwater arsenic contamination : Regions at risk in highest populated state of India. Water Res 159:65–76. https://doi.org/10.1016/j.watres.2019.04.054
Bodrud-Doza ISMD, Rume T, Quraishi SB et al (2020) Groundwater for Sustainable Development Groundwater quality and human health risk assessment for safe and sustainable water supply of Dhaka City dwellers in Bangladesh. Groundw Sustain Dev 10:100374. https://doi.org/10.1016/j.gsd.2020.100374
Bogard MJ, St-Gelais NF, Vachon D, del Giorgio PA (2020) Patterns of Spring/Summer Open-Water Metabolism Across Boreal Lakes. Ecosystems 23:1581–1597. https://doi.org/10.1007/s10021-020-00487-7
Bozorgi M, Moein M, Nejadkoorki F, Toosi NB (2020) Assessing the effect of water scarcity on crop selection and spatial pattern of croplands in central Iran. Comput Electron Agric 178:105743. https://doi.org/10.1016/j.compag.2020.105743
Caboi R, Cidu R, Fanfani L, Lattanzi P, Zuddas P (1999) Environmental mineralogy and geochemistry of the abandoned Pb–Zn Montevecchio-Ingurtosu mining district, Sardinia, Italy. Chron Rech Miniere 534:21–28
Cannas D, Loi E, Serra M et al (2020) Relevance of essential trace elements in nutrition and drinking water for human health and autoimmune disease risk. Nutrients 12:1–22. https://doi.org/10.3390/nu12072074
Çiner F, Sunkari ED, Şenbaş BA (2021) Geochemical and multivariate statistical evaluation of trace elements in groundwater of Niğde Municipality, South-Central Turkey: implications for arsenic contamination and human health risks assessment. Arch Environ Contam Toxicol 80:164–182. https://doi.org/10.1007/s00244-020-00759-2
Colombani N, Gervasio MP, Castaldelli G, Mastrocicco M (2020) Soil conditioners effects on hydraulic properties, leaching processes and denitrification on a silty-clay soil. Sci Total Environ 733:139342. https://doi.org/10.1016/j.scitotenv.2020.139342
Cui T, Sreekanth J, Pickett T, Rassam D, Gilfedder M, Barrett D (2021) Impact of model parameterization on predictive uncertainty of regional groundwater models in the context of environmental impact assessment. Environ Impact Assess Rev 90:106620. https://doi.org/10.1016/j.eiar.2021.106620
Dawoudian J, Bahamin S, Tantoh HB (2021) Environmental impact assessment of cement industries using mathematical matrix method: case of Ghayen cement, South Khorasan. Iran Environ Sci Pollut Res 28:22348–22358. https://doi.org/10.1007/s11356-020-12012-3
dos Luís AA, Cabral P (2021) Small dams/reservoirs site location analysis in a semi-arid region of Mozambique. Int Soil Water Conserv Res 9:381–393. https://doi.org/10.1016/j.iswcr.2021.02.002
Egbueri JC (2020) Heavy metals pollution source identification and probabilistic health risk assessment of shallow groundwater in Onitsha, Nigeria. Anal Lett 53:1620–1638. https://doi.org/10.1080/00032719.2020.1712606
Eman K, Meško G (2020) Access to safe and affordable drinking water as a fundamental human right: the case of the Republic of Slovenia. Emerald Handb Crime, Justice Sustain Dev 1:465–484. https://doi.org/10.1108/978-1-78769-355-520201025
Environmental Protection Agency (EPA) (2004) Risk assessment guidance for superfund volume I human health evaluation manual (Part A). EPA/540/1-89/002
Esmaeilbeigi M, Kalbassi MR, Seyedi J, Tayemeh MB, Moghaddam JA (2021) Intra and extracellular effects of benzo [α] pyrene on liver, gill and blood of Caspian White fish (Rutilus frissi kutum): Cyto-genotoxicity and histopathology approach. Mar Pollut Bull 163:111942. https://doi.org/10.1016/j.marpolbul.2020.111942
Esmaeilbeigi M, Behzadi Tayemeh M, Johari SA, Ghorbani F, Sourinejad I, Yu IJ (2022) In silico modeling of the antagonistic effect of mercuric chloride and silver nanoparticles on the mortality rate of zebrafish (Danio rerio) based on response surface methodology. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-022-19693-y
Fallahati A, Soleimani H, Alimohammadi M et al (2020) Impacts of drought phenomenon on the chemical quality of groundwater resources in the central part of Iran—application of GIS technique. Environ Monit Assess. https://doi.org/10.1007/s10661-019-8037-4
FAO (1985) Water Quality for Agriculture. Food and Agriculture Organization, Rome
Ficklin WH, Plumlee GS, Smith KS, McHugh JB (1992) Geochemical classification of mine drainage and natural drainage in mineralized areas. In: Kharaka YK, Maet AS (eds) Water-rock interaction 7:81–384
Ghorbani A, Mousazadeh H, Taheri F et al (2021) An attempt to develop ecotourism in an unknown area: the case of Nehbandan County, South Khorasan Province, Iran. Environ Dev Sustain 23:11792–11817. https://doi.org/10.1007/s10668-020-01142-w
Hein C, Van Schaik H, Six D, Mager T, Kolen J, Ertsen M, Nijhuis S, Verschuure-Stuip G (2020) Introduction: Connecting Water and Heritage for the Future. Adaptive Strategies for Water Heritage. Springer, Cham. https://doi.org/10.1007/978-3-030-00268-8_1
Ilieva D, Surleva AR, Murariu M (2018) Evaluation of ICP-OES Method for heavy metal and metalloids determination in sterile dump material. https://doi.org/10.4028/www.scientific.net/SSP.273.159
Iran National Standard Organization (1997) Standards for drinking water in Iran
Jha MK, Shekhar A, Jenifer MA (2020) Assessing groundwater quality for drinking water supply using hybrid fuzzy-GIS-based water quality index. Water Res 179:115867
Kadam A, Wagh V, Jacobs J et al (2021) Integrated approach for the evaluation of groundwater quality through hydro geochemistry and human health risk from Shivganga river basin, Pune, Maharashtra, India. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-021-15554-2
Kazemi A, Riyahi Bakhtiari A, Kheirabadi N, Barani H, Haidari B (2012) Distribution patterns of metals contamination in sediments based on type regional development on the intertidal coastal zones of the Persian Gulf. Iran Bull Env Contam Toxicol 88:100–103. https://doi.org/10.1007/s00128-011-0412-y
Kazemi A, Esmaeilbeigi M, Ansari A, Asl AG, Mohammadzadeh B (2022a) Alterations and health risk assessment of the environmental concentration of heavy metals in the edible tissue of marine fish (Thunnus tonggol) consumed by different cooking methods. Reg Stud Mar Sci 53:102361. https://doi.org/10.1016/j.rsma.2022.102361
Kazemi A, Esmaeilbeigi M, Sahebi Z, Ansari A (2022b) Health risk assessment of total chromium in the qanat as historical drinking water supplying system. Sci Total Environ 807:150795. https://doi.org/10.1016/j.scitotenv.2021.150795
Khalid S, Shahid M, Natasha, et al (2020) Heavy metal contamination and exposure risk assessment via drinking groundwater in Vehari, Pakistan. Environ Sci Pollut Res 27:39852–39864. https://doi.org/10.1007/s11356-020-10106-6
Khalili Z, Asadi N (2021) Groundwater quality assessment using Aq.QA and GIS technique in Azna city, Lorestan province, Iran. Sustain Water Resour Manag 7:1–12. https://doi.org/10.1007/s40899-021-00495-y
Khan SA, Muhammad S, Nazir S, Shah FA (2020) Heavy metals bounded to particulate matter in the residential and industrial sites of Islamabad, Pakistan: Implications for non-cancer and cancer risks: Evaluation of heavy metals bounded to particulate matter for non-cancer and cancer risks. Environ Technol Innov 19:100822. https://doi.org/10.1016/j.eti.2020.100822
Krogulec E, Małecki JJ, Porowska D, Wojdalska A (2020) Assessment of causes and effects of groundwater level change in an urban area (Warsaw, Poland). Water 12(11):3107. https://doi.org/10.3390/w12113107
Kuiper N, Rowell C, Shomar B (2015) High levels of molybdenum in Qatar’s groundwater and potential impacts. J Geochemical Explor 150:16–24. https://doi.org/10.1016/j.gexplo.2014.12.009
Kumar V, Sharma A, Kumar R et al (2020) Assessment of heavy-metal pollution in three different Indian water bodies by combination of multivariate analysis and water pollution indices. Hum Ecol Risk Assess 26:1–16. https://doi.org/10.1080/10807039.2018.1497946
Laniyan TA, Adewumi AJ (2021) Ecological and human health risk associated with potentially toxic metals in water from Ijero mining area, Southwest Nigeria. Int J Environ Anal Chem 00:1–25. https://doi.org/10.1080/03067319.2021.1931159
Liu Y, Ma R (2020) Human health risk assessment of heavy metals in groundwater in the luan river catchment within the North China Plain. Geofluids. https://doi.org/10.1155/2020/8391793
Long X, Liu F, Zhou X et al (2021) Estimation of spatial distribution and health risk by arsenic and heavy metals in shallow groundwater around Dongting Lake plain using GIS mapping. Chemosphere 269:128698. https://doi.org/10.1016/j.chemosphere.2020.128698
Malmal K, Shiri N (2021) Investigating the Importance of Water in Iran Using Game Theory. J Eng Ind Res 2:28–35
Mastrocicco M, Gervasio MP, Busico G, Colombani N (2021) Natural and anthropogenic factors driving groundwater resources salinization for agriculture use in the Campania plains (Southern Italy). Sci Total Environ 758:144033. https://doi.org/10.1016/j.scitotenv.2020.144033
Michel S, Ghoddousi A (2020) Ovis vignei. The IUCN Red List of Threatened Species 2020: e.T54940655A54940728. https://doi.org/10.2305/IUCN.UK.2020 2.RLTS.T54940655A54940728.en
Mohamed A (2019) Hydro-geophysical study of the groundwater storage variations over the Libyan area and its connection to the Dakhla basin in Egypt. J African Earth Sci 157:103508. https://doi.org/10.1016/j.jafrearsci.2019.05.016
Mridha MAH, Rahman SH (2021) Prediction of groundwater trends for irrigation in Northern Bangladesh. Water Supply 21:2596–2614. https://doi.org/10.2166/ws.2021.076
Nivetha A, Sakthivel C, Prabha I (2021) Heavy metal contamination in groundwater and impact on plant and human. 233–246. https://doi.org/10.1007/978-3-030-63422-3_14
Njora B, Yılmaz H (2021) Evaluation of water accessibility, distribution, water use policies and management in Kenya. International Journal of Water Management and Diplomacy 1:5–16. https://dergipark.org.tr/en/pub/ijwmd/issue/63570/958552
Noreen F, Sajjad A, Mahmood K et al (2020) Human biomonitoring of trace elements in scalp hair from healthy population of pakistan. Biol Trace Elem Res 196:37–46. https://doi.org/10.1007/s12011-019-01906-0
O’Driscoll M (2008) Magnesite ignites. Ind Miner 28–45
Obasi PN, Akudinobi BB (2020) Potential health risk and levels of heavy metals in water resources of lead–zinc mining communities of Abakaliki, southeast Nigeria. Appl Water Sci. https://doi.org/10.1007/s13201-020-01233-z
Parang H, Esmaeilbeigi M (2022) Total mercury concentration in the muscle of four mostly consumed fish and associated human health risks for fishermen and non-fishermen families in the Anzali Wetland, Southern Caspian Sea. Reg Stud Mar Sci 52:102270. https://doi.org/10.1016/j.rsma.2022.102270
Peng K, Li X, Wang Z (2015) Hydrochemical characteristics of groundwater movement and evolution in the Xinli deposit of the Sanshandao gold mine using FCM and PCA methods. Environ Earth Sci. https://doi.org/10.1007/s12665-014-3938-6
Phan VH, Dinh VT, Su Z (2020) Trends in long-term drought changes in the Mekong River Delta of Vietnam. Remote Sens 12(18):1–22. https://doi.org/10.3390/RS12182974
Piesse M (2020) Global water supply and demand trends point towards rising water insecurity. Future Directions International 27(7):2020. https://apo.org.au/node/276976
Qiao J, Zhu Y, Jia X et al (2020) Distributions of arsenic and other heavy metals, and health risk assessments for groundwater in the Guanzhong Plain region of China. Environ Res 181:108957. https://doi.org/10.1016/j.envres.2019.108957
Rajasekhar B, Nambi IM, Govindarajan SK (2020) Human health risk assessment for exposure to BTEXN in an urban aquifer using deterministic and probabilistic methods: a case study of Chennai city. India Environ Pollut 265:114814. https://doi.org/10.1016/j.envpol.2020.114814
Rajmohan N, Masoud MHZ, Niyazi BAM (2021) Impact of evaporation on groundwater salinity in the arid coastal aquifer. Western Saudi Arabia Catena 196:104864. https://doi.org/10.1016/j.catena.2020.104864
Ram A, Pandey SKTHK, Kumar A et al (2021) Groundwater quality assessment using water quality index ( WQI ) under GIS framework. Appl Water Sci 11:1–20. https://doi.org/10.1007/s13201-021-01376-7
Ravanipour M, Hadi M, Rastkari N et al (2021) Presence of heavy metals in drinking water resources of Iran: a systematic review and meta-analysis. Environ Sci Pollut Res 28:26223–26251. https://doi.org/10.1007/s11356-021-13293-y
Ravikumar P, Somashekar R, Prakash K (2015) A comparative study on usage of Durov and Piper diagrams to interpret hydrochemical processes in groundwater from SRLIS river basin, Karnataka, India. Earth Sci 80:31073–31077
Saxena VK, Singh VS, Mondal NC, Jain SC (2003) Use of hydrochemical parameters for the identification of fresh groundwater resources, Potharlanka Island, India. Environ Geol 44:516–521. https://doi.org/10.1007/s00254-003-0807-0
Sayadi MH, Kharkan J, Binkowski LJ et al (2020) Cadmium and chromium levels in water and edible herbs in a risk assessment study of rural residents living in Eastern Iran. Environ Sci Pollut Res 27:9901–9909. https://doi.org/10.1007/s11356-020-07600-2
Seyedi J, Kalbassi MR, Esmaeilbeigi M, Tayemeh MB, Amiri Moghadam J (2021a) Toxicity and deleterious impacts of selenium nanoparticles at supranutritional and imbalance levels on male goldfish (Carassius auratus) sperm. J Trace Elem Med Biol 66:126758. https://doi.org/10.1016/j.jtemb.2021.126758
Seyedi J, Tayemeh MB, Esmaeilbeigi M, Joo HS, Langeroudi EK, Banan A, Johari SA, Jami MJ (2021b) Fatty acid alteration in liver, brain, muscle, and oocyte of zebrafish (Danio rerio) exposed to silver nanoparticles and mitigating influence of quercetin-supplemented diet. Environ Res 194:110611. https://doi.org/10.1016/j.envres.2020.110611
Shams M, Tavakkoli Nezhad N, Dehghan A et al (2020) Heavy metals exposure, carcinogenic and non-carcinogenic human health risks assessment of groundwater around mines in Joghatai, Iran. Int J Environ Anal Chem 00:1–16. https://doi.org/10.1080/03067319.2020.1743835
Shirazi A, Shirazy A, Karami J (2018) Remote sensing to identify copper alterations and promising regions, Sarbishe, South Khorasan, Iran. Int J Geol Earth Sci 4:36–52
Shirdel I, Kalbassi MR, Esmaeilbeigi M, Tinoush B (2020) Disruptive effects of nonylphenol on reproductive hormones, antioxidant enzymes, and histology of liver, kidney and gonads in Caspian trout smolts. Comp Biochem Physiol Part C Toxicol Pharmacol 232:108756. https://doi.org/10.1016/j.cbpc.2020.108756
Siebert S (2021) Water use in human civilizations: an interdisciplinary analysis of a perpetual social-ecological challenge. Front Agric Sci Eng. https://doi.org/10.15302/j-fase-2021393
Soleimani H, Azhdarpoor A, Hashemi H et al (2020) Probabilistic and deterministic approaches to estimation of non-carcinogenic human health risk due to heavy metals in groundwater resources of torbat heydariyeh, southeastern of Iran. Int J Environ Anal Chem 1:1–15. https://doi.org/10.1080/03067319.2020.1757086
Søndergaard J, Asmund G, Larsen MM (2015) Trace elements determination in seawater by ICP-MS with on-line pre-concentration on a Chelex-100 column using a “standard” instrument setup. MethodsX 2:323–330. https://doi.org/10.1016/j.mex.2015.06.003
Sutradhar S, Mondal P (2021) Groundwater suitability assessment based on water quality index and hydrochemical characterization of Suri Sadar Sub-division, West Bengal. Ecol Inform 64:101335. https://doi.org/10.1016/j.ecoinf.2021.101335
Talebi MS, Fatemi M (2020) Assessment of the quality and quantity of groundwater in Bahadoran plain using neural network methods, geostatistical and multivariate statistical analysis. J Appl Res Water Wastewater 14(14):144–151
Tiwari AK, De Maio M (2017) Assessment of risk to human health due to intake of chromium in the groundwater of the Aosta Valley region, Italy. Hum Ecol Risk Assess 23:1153–1163. https://doi.org/10.1080/10807039.2017.1308813
Tsai KS, Chang YM, Kao JCM, Lin KL (2016) Groundwater molybdenum from emerging industries in Taiwan. Bull Environ Contam Toxicol 96:102–106. https://doi.org/10.1007/s00128-015-1695-1
Umamageswari TSR, Sarala Thambavani D, Liviu M (2019) Hydrogeochemical processes in the groundwater environment of Batlagundu block, Dindigul district, Tamil Nadu: conventional graphical and multivariate statistical approach. Appl Water Sci 9:1–15. https://doi.org/10.1007/s13201-018-0890-8
United States Environmental Protection Agency (US EPA) (2012) Standard Operating Procedure for an In Vitro Bioaccessibility Assay for Lead in Soil. EPA 9200.2–86.
USEPA (2004) Overview of the ecological risk assessment process in the office of pesticide programs, US Environmental Protection Agency. Office of Prevention, Pesticides and Toxic Substances Office of pesticides Programs. Washington, DC, p 92
Vasilache N, Vasile GG, Diacu E et al (2020) Groundwater quality assessment for drinking and irrigation purpose using GIS, Piper diagram, and water quality index. Rom J Ecol Environ Chem 2:109–117. https://doi.org/10.21698/rjeec.2020.214
Veisi S, Johari SA, Tyler CR, Mansouri B, Esmaeilbeigi M (2021) Antioxidant properties of dietary supplements of free and nanoencapsulated silymarin and their ameliorative effects on silver nanoparticles induced oxidative stress in Nile tilapia (Oreochromis niloticus). Environ Sci Pollut Res 28:26055–26063. https://doi.org/10.1007/s11356-021-12568-8
Wang X, Cui L, Li J et al (2021a) Ecological and health risk assessments and water quality criteria of heavy metals in the Haihe River. Environ Pollut. https://doi.org/10.1016/j.envpol.2021.117971
Wang H, Yang Q, Ma H, Liang J (2021b) Chemical compositions evolution of groundwater and its pollution characterization due to agricultural activities in Yinchuan Plain, northwest China. Environ Res 200:111449. https://doi.org/10.1016/j.envres.2021.111449
WHO (2011) Nitrate and Nitrite in Drinking Water (WHO/SDE/WSH/07.01/16/Rev/1). Background document for development ofWHO guidelines for drinking water quality, Geneva, Switzerland
Wu C, Fang C, Wu X, Zhu G (2020) Health-risk assessment of arsenic and groundwater quality classification using random forest in the Yanchi Region of Northwest China. Expo Heal 12:761–774. https://doi.org/10.1007/s12403-019-00335-7
Yakamercan E, Ari A, Aygün A (2021) Land application of municipal sewage sludge: human health risk assessment of heavy metals. J Clean Prod 319:128568. https://doi.org/10.1016/j.jclepro.2021.128568
Zakir HM, Sharmin S, Akter A, Rahman MS (2020) Assessment of health risk of heavy metals and water quality indices for irrigation and drinking suitability of waters: a case study of Jamalpur Sadar area, Bangladesh. Environ Adv 2:100005. https://doi.org/10.1016/j.envadv.2020.100005
Zhang C, Duan Q, Yeh PJ, Pan Y, Gong H (2021) Sub-regional groundwater storage recovery in North China Plain after the South-to-North water diversion project. J Hydrol 597:126156. https://doi.org/10.1016/j.jhydrol.2021.126156
Zhang N, Suleiman JS, He M, Hu B (2008) Chromium(III)-imprinted silica gel for speciation analysis of chromium in environmental water samples with ICP-MS detection. Talanta 75:536–543. https://doi.org/10.1016/j.talanta.2007.11.059
Zhang Y, Li F, Ouyang Z (2012) Distribution and health risk assessment of heavy metals of groundwaters in the irrigation district of the lower reaches of Yellow River. Environ Sci 34(1):121–130
Zidi C, Jamrah A, Al-Issai L (2020) Hydrochemical assessment of groundwater, case study Al-Zaroub aquifer, Buraimi Governorate, Sultanate of Oman. Groundw Sustain Dev 11:100450. https://doi.org/10.1016/j.gsd.2020.100450
Zubaidi SL, Ortega-Martorell S, Al-Bugharbee H et al (2020) Urban water demand prediction for a city that suffers from climate change and population growth: Gauteng province case study. Water (switzerland) 12:1–17. https://doi.org/10.3390/W12071885
Zuo TT, Jin HY, Zhang L et al (2020) Innovative health risk assessment of heavy metals in Chinese herbal medicines based on extensive data. Pharmacol Res 159:104987. https://doi.org/10.1016/j.phrs.2020.104987
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Arvin Zist Pooya Lab is acknowledged for its technical support in the acquisition of the water sample preparation and analysis. The authors also gratefully appreciate Ben Kefford for his revision and helpful guidance in improving this paper.
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Ali Kazemi: Investigation, supervision, data curation, field sampling. Milad Esmaeilbeigi: Writing (original draft), data analysis, methodology, graphical analysis. Zahra Sahebi: Conceptualization, funding acquisition, project administration. Sharif Joorabian Shooshtari: Review and editing, GIS data management, running GIS data.
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Kazemi, A., Esmaeilbeigi, M., Sahebi, Z. et al. Hydrochemical evaluation of groundwater quality and human health risk assessment of trace elements in the largest mining district of South Khorasan, Eastern Iran. Environ Sci Pollut Res 29, 81804–81829 (2022). https://doi.org/10.1007/s11356-022-21494-2
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DOI: https://doi.org/10.1007/s11356-022-21494-2