Abstract
Health and environmental impact of pesticide contamination of groundwater has been reported repeatedly in many studies. The removal of diazinon from agricultural wastewater is still of great interest due to using widely in many developing countries. In the presented study, the magnetic tragacanth-montmorillonite nanocomposite was utilized as an adsorbent to remove diazinon from an aqueous solution. The adsorbent properties were characterized using FE-SEM, EDX, FTIR, XRD, BET, and VSM techniques. The influence of adsorbent dosage, pH, contact time, and initial concentration of diazinon was studied in a batch system. Different adsorption kinetics and isotherm models were used to describe the kinetic and equilibrium data. The results indicated that the adsorption kinetic was fitted better with a Elovich kinetic model, and the adsorption isotherm was well described by the Langmuir-Freundlich model, and the maximum adsorption capacity was 416 mg g−1. According to Weber and Morris’s model and Boyd plot, the results demonstrated that the adsorption kinetic was controlled simultaneously by film diffusion and intraparticle diffusion. Besides, a thermodynamic study showed that the removal of diazinon is an endothermic process. Considering the results, magnetic tragacanth-montmorillonite nanoadsorbent has a high capability to remove diazinon from aqueous solution.
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Adewuyi YG, Khan MA (2020) Simultaneous NO and SO 2 removal by aqueous persulfate activated by combined heat and Fe 2+: experimental and kinetic mass transfer model studies. Environ Sci Pollut Res 27(2):1186–1201
Alinejad-Mir A, Amooey AA, Ghasemi S (2018) Adsorption of direct yellow 12 from aqueous solutions by an iron oxide-gelatin nanoadsorbent; kinetic, isotherm and mechanism analysis. J Clean Prod 170:570–580
Amani M, Latifi A, Tahvildari K, Karimian R (2018) Removal of diazinon pesticide from aqueous solutions using MCM-41 type materials: isotherms, kinetics and thermodynamics. Int J Environ Sci Technol 15(6):1301–1312
Amooey AA, Ghasemi S, Mirsoleimani-azizi SM, Gholaminezhad Z, Chaichi MJ (2014) Removal of diazinon from aqueous solution by electrocoagulation process using aluminum electrodes. Korean J Chem Eng 31(6):1016–1020
Arabloo M, Ghazanfari MH, Rashtchian D (2016) Wettability modification, interfacial tension and adsorption characteristics of a new surfactant: implications for enhanced oil recovery. Fuel 185:199–210
Armaghan M, Amini M (2012) Adsorption of diazinon and fenitrothion on nanocrystalline alumina from non-polar solvent. Colloid J 74(4):427–433
Armaghan M, Amini MM (2017) Adsorption of diazinon and fenitrothion on nanocrystalline magnesium oxides. Arab J Chem 10(1):91–99
Cottet L, Almeida C, Naidek N, Viante M, Lopes M, Debacher N (2014) Adsorption characteristics of montmorillonite clay modified with iron oxide with respect to methylene blue in aqueous media. Appl Clay Sci 95:25–31
Dehghani MH, Kamalian S, Shayeghi M, Yousefi M, Heidarinejad Z, Agarwal S, Gupta VK (2018) High-performance removal of diazinon pesticide from water using multi-walled carbon nanotubes. Microchem J
Elovich SY, Larinov O (1962) Theory of adsorption from solutions of non electrolytes on solid (I) equation adsorption from solutions and the analysis of its simplest form,(II) verification of the equation of adsorption isotherm from solutions. Izv Akad Nauk SSSR Otd Khim Nauk 2(2):209–216
Esfandian H, Samadi-Maybodi A, Parvini M, Khoshandam B (2016) Development of a novel method for the removal of diazinon pesticide from aqueous solution and modeling by artificial neural networks (ANN). J Ind Eng Chem 35:295–308
Firozjaee TT, Mehrdadi N, Baghdadi M, Bidhendi G (2017) The removal of diazinon from aqueous solution by chitosan/carbon nanotube adsorbent. Desalin Water Treat 79:291–300
Ge Y, Qin L, Li Z (2016) Lignin microspheres: an effective and recyclable natural polymer-based adsorbent for lead ion removal. Mater Des 95:141–147
Hassan AF, Elhadidy H, Abdel-Mohsen A (2017) Adsorption and photocatalytic detoxification of diazinon using iron and nanotitania modified activated carbons. J Taiwan Inst Chem Eng 75:299–306
Hemmati K, Masoumi A, Ghaemy M (2016) Tragacanth gum-based nanogel as a superparamagnetic molecularly imprinted polymer for quercetin recognition and controlled release. Carbohydr Polym 136:630–640
Kabwadza-Corner P, Matsue N, Johan E, Henmi T (2014) Mechanism of diazinon adsorption on iron modified montmorillonite. Am J Anal Chem 5(02):70–76
Kalantary RR, Dadban Shahamat Y, Farzadkia M, Esrafili A, Asgharnia H (2015) Photocatalytic degradation and mineralization of diazinon in aqueous solution using nano-TiO2 (Degussa, P25): kinetic and statistical analysis. Desalin Water Treat 55(2):555–563
Khoei AJ, Joogh NJG, Darvishi P, Rezaei K (2019) Application of physical and biological methods to remove heavy metal, arsenic and pesticides, malathion and diazinon from water. Turk J Fish Aquat Sci 19(1):21–28
Lagergren SK (1898) About the theory of so-called adsorption of soluble substances. Sven Vetenskapsakad Handingarl 24:1–39
Larraza I, López-Gónzalez M, Corrales T, Marcelo G (2012) Hybrid materials: magnetite–polyethylenimine–montmorillonite, as magnetic adsorbents for Cr (VI) water treatment. J Colloid Interface Sci 385(1):24–33
Mahdavinia GR, Hasanpour S, Behrouzi L, Sheykhloie H (2016) Study on adsorption of Cu (II) on magnetic starch-g-polyamidoxime/montmorillonite/Fe3O4 nanocomposites as novel chelating ligands. Starch-Stärke 68(3–4):188–199
Masoumi A, Ghaemy M (2014) Removal of metal ions from water using nanohydrogel tragacanth gum-g-polyamidoxime: isotherm and kinetic study. Carbohydr Polym 108:206–215
Moussavi G, Hosseini H, Alahabadi A (2013) The investigation of diazinon pesticide removal from contaminated water by adsorption onto NH 4 Cl-induced activated carbon. Chem Eng J 214:172–179
Naeimi Bagheini A, Saeidi M, Boroomand N (2018) Removal of diazinon pesticide using amino-silane modified magnetite nanoparticles from contaminated water. Int J Nanosci Nanotechnol 14(1):19–32
Nikzad S, Amooey AA, Alinejad-Mir A (2019) Adsorption of diazinon from aqueous solutions by magnetic guar gum-montmorillonite. Chem Data Collect 20:100187
Patra AS, Ghorai S, Ghosh S, Mandal B, Pal S (2016) Selective removal of toxic anionic dyes using a novel nanocomposite derived from cationically modified guar gum and silica nanoparticles. J Hazard Mater 301:127–136
Pirsaheb M, Dargahi A, Hazrati S, Fazlzadehdavil M (2014) Removal of diazinon and 2, 4-dichlorophenoxyacetic acid (2, 4-D) from aqueous solutions by granular-activated carbon. Desalin Water Treat 52(22–24):4350–4355
Quesada-Peñate I, Julcour-Lebigue C, Jáuregui-Haza U-J, Wilhelm A-M, Delmas H (2009) Comparative adsorption of levodopa from aqueous solution on different activated carbons. Chem Eng J 152(1):183–188
Sadeghi S, Alavi Rad F, Zeraatkar Moghaddam A (2014) A highly selective sorbent for removal of Cr(VI) from aqueous solutions based on Fe3O4/poly(methyl methacrylate) grafted Tragacanth gum nanocomposite: optimization by experimental design. Mater Sci Eng C 45:136–145
Saeidi M, Naeimi A, Komeili M (2016) Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water. Vacuum 16:17
Sahraei R, Pour ZS, Ghaemy M (2017) Novel magnetic bio-sorbent hydrogel beads based on modified gum tragacanth/graphene oxide: removal of heavy metals and dyes from water. J Clean Prod 142:2973–2984
Samadi M, Khodadai M, Rahmani A (2011) The comparison of advanced oxidation process and chemical coagulation for the removal of residual pesticides from water. Res J Environ Sci 5(11):817–826
Verma AK, Dash RR, Bhunia P (2012) A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. J Environ Manag 93(1):154–168
Wang J, Guo X (2020) Adsorption kinetic models: physical meanings, applications, and solving methods. J Hazard Mater 122156
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Nikzad, S., Amooey, A.A. & Alinejad-Mir, A. High effective removal of diazinon from aqueous solutions using the magnetic tragacanth-montmorillonite nanocomposite: isotherm, kinetic, and mechanism study. Environ Sci Pollut Res 28, 20426–20439 (2021). https://doi.org/10.1007/s11356-020-12238-1
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DOI: https://doi.org/10.1007/s11356-020-12238-1