Abstract
Urban planning and development is a decisive factor that increases the automobile numbers which leads to increased energy demand across the globe. In order to meet the escalating requirements of energy, it is necessary to find viable alternatives. Waste plastic oil (WPO) is one such alternative which has dual benefits as it reduces the environmental pollution caused by plastic waste and it could possibly meet the energy requirement along with fossil fuels. The study attempted to reduce emissions from a DI diesel engine fueled with WPO using 30% by volume of n-pentanol with fossil diesel (WPO70P30). EGR (10, 20, and 30%) and injection timing modifications were made with the intention to find optimum engine operating conditions. The experimental results indicated that addition of renewable component like n-pentanol had improved the combustion characteristics by igniting WPO more homogeneously producing a higher premixed combustion phase. Smoke density for WPO70P30 was found to be twice lower than that of neat WPO at standard injection timing of 23°CA bTDC at any given EGR rate, NOx emissions were slightly on the higher side about 12% for WPO70P30 blend against WPO at same operating conditions. WPO70P30 showed lowest smoke and carbon monoxide emissions than diesel and WPO while delivering BTE’s higher than WPO and closer to diesel at all EGR and injection timings. However NOx and HC emissions increased with n-pentanol addition. The use of EGR reduced NOx emissions but was found to aggravate other emissions. It was concluded WPO70P30 can be favorably used in a DI diesel engine at the engines advanced injection timing for better performance than diesel with a slight penalty in NOx emissions.
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Abbreviations
- bTDC:
-
Before top dead center
- CAS:
-
Chemical Abstract Service
- CCI:
-
Calculated Cetane Index
- CO:
-
Carbon monoxide
- DI:
-
Direct Injection
- EGR:
-
Exhaust gas recirculation
- EGT:
-
Exhaust gas temperature
- HC:
-
Hydrocarbons
- HRR:
-
Heat release rate
- LHV:
-
Low heating value
- NOx :
-
Nitrogen oxides
- ν:
-
Kinematic viscosity
- ρ:
-
Density
- SD:
-
Standard deviation
- ULSD:
-
Ultra-low sulfur diesel
- WPO:
-
Waste plastic oil
- WPO70P30:
-
70% by vol. of waste plastic oil + 30% by vol. of n-pentanol blend
References
Anuar Sharuddin SD, Abnisa F, Wan Daud WMA, Aroua MK (2016) A review on pyrolysis of plastic wastes. Energy Convers Manag 115:308–326
Babu D, Anand R (2017) Effect of biodiesel-diesel- n -pentanol and biodiesel-diesel- n -hexanol blends on diesel engine emission and combustion characteristics. Energy 133:761–776
Börjesson M, Ahlgren EO, Lundmark R, Athanassiadis D (2014) Biofuel futures in road transport—a modeling analysis for Sweden. Transp Res Part D: Transp Environ 32:239–252
Cann AF, Liao JC (2009) Pentanol isomer synthesis in engineered microorganisms. Appl Microbiol Biotechnol 85(4):893–899. https://doi.org/10.1007/s00253-009-2262-7
Chen L, Ding S, Liu H, Lu Y, Li Y, Roskilly AP (2017) Comparative study of combustion and emissions of kerosene (RP-3), kerosene-pentanol blends and diesel in a compression ignition engine. Appl Energy 203:91–100
Damodharan D, Sathiyagnanam AP, Rana D, Rajesh Kumar B, Saravanan S (2017) Extraction and characterization of waste plastic oil (WPO) with the effect of n-butanol addition on the performance and emissions of a DI diesel engine fueled with WPO/diesel blends. Energy Convers Manag 131:117–126
Dekishima Y, Lan EI, Shen CR, Cho KM, Liao JC (2011) Extending carbon chain length of 1-butanol pathway for 1-hexanol synthesis from glucose by engineered Escherichia coli. J Am Chem Soc 133(30):11399–11401
De Poures MV, Sathiyagnanam AP, Rana D, Rajesh Kumar B, Saravanan S (2017) 1-Hexanol as a sustainable biofuel in DI diesel engines and its effect on combustion and emissions under the influence of injection timing and exhaust gas recirculation (EGR). Appl Therm Eng 113:1505–1513
Devaraj J, Robinson Y, Ganapathi P (2015) Experimental investigation of performance, emission and combustion characteristics of waste plastic pyrolysis oil blended with diethyl ether used as fuel for diesel engine. Energy 85:304–309
Dhanasekaran R, Krishnamoorthy V, Rana D, Saravanan S, Nagendran A, Rajesh Kumar B (2017) A sustainable and eco-friendly fueling approach for direct-injection diesel engines using restaurant yellow grease and n-pentanol in blends with diesel fuel. Fuel 193:419–431
Geyer R, Jambeck JR, Law KL (2017) Production, use, and fate of all plastics ever made. Sci Adv 3:e1700782
Iannuzzi SE, Barro C, Boulouchos K, Burger J (2017) POMDME-diesel blends: evaluation of performance and exhaust emissions in a single cylinder heavy-duty diesel engine. Fuel 203:57–67. https://doi.org/10.1016/j.fuel.2017.04.089
Kaimal VK, Vijayabalan P (2015) A detailed study of combustion characteristics of a DI diesel engine using waste plastic oil and its blends. Energy Convers Manag 105:951–956
Kumar PS, Sankaranarayanan G (2016) Investigation on environmental factors of waste plastics into oil and its emulsion to control the emission in DI diesel engine. Ecotoxicol Environ Saf 134:440–444
Kumar S, Prakash R, Murugan S, Singh RK (2013) Performance and emission analysis of blends of waste plastic oil obtained by catalytic pyrolysis of waste HDPE with diesel in a CI engine. Energy Convers Manag 74:323–331
Li L, Wang J, Wang Z, Xiao J (2015) Combustion and emission characteristics of diesel engine fueled with diesel/biodiesel/pentanol fuel blends. Fuel 156:211–218
Lingaiah N, Uddin MA, Muto A, Imai T, Sakata Y (2001) Removal of organic chlorine compounds by catalytic dehydrochlorination for the refinement of municipal waste plastic derived oil. Fuel 80(13):1901–1905. https://doi.org/10.1016/s0016-2361(01)00046-1
Liu Y, Murata K, Inaba M, Takahara I, Okabe K (2013) Mixed alcohols synthesis from syngas over Cs- and Ni-modified Cu/CeO2 catalysts. Fuel 104:62–69. https://doi.org/10.1016/j.fuel.2010.08.014
Lü H, Ji Z, Huang (2006) Heat release analysis on combustion and parametric study on emissions of HCCI engines fueled with 2-propanol/n -heptane blend fuels. Energy Fuel 20:1870–1878
Ma Y, Huang R, Huang S, Zhang Y, Xu S, Wang Z (2017a) Experimental investigation on the effect of n-pentanol blending on spray, ignition and combustion characteristics of waste cooking oil biodiesel. Energy Convers Manag 148:440–455
Ma Y, Huang S, Huang R, Zhang Y, Xu S (2017b) Ignition and combustion characteristics of n-pentanol–diesel blends in a constant volume chamber. Appl Energy 185:519–530
Mani M, Nagarajan G (2009) Influence of injection timing on performance, emission and combustion characteristics of a DI diesel engine running on waste plastic oil. Energy 34:1617–1623
Mani M, Nagarajan G, Sampath S (2011) Characterisation and effect of using waste plastic oil and diesel fuel blends in compression ignition engine. Energy 36:212–219
Moffat RJ (1985) Using uncertainty analysis in the planning of an experiment. ASME Trans J Fluids Eng 107:173–178 (ISSN 0098-2202)
Nwafor OMI (2004) Effect of advanced injection timing on emission characteristics of a diesel engine running on biofuel. International Journal of Ambient Energy 25:115–122
Park S, Chung SH, Lu T, Sarathy SM (2015) Combustion characteristics of C5 alcohols and a skeletal mechanism for homogeneous charge compression ignition combustion simulation. Energy Fuel 29:7584–7594
Rajesh kumar B, Saravanan S (2015) Effect of exhaust gas recirculation (EGR) on performance and emissions of a constant speed DI diesel engine fueled with pentanol/diesel blends. Fuel 160:217–226
Rajesh Kumar B, Saravanan S (2016a) Use of higher alcohol biofuels in diesel engines: a review. Renew Sust Energ Rev 60:84–115
Rajesh Kumar B, Saravanan S (2016b) Effects of iso-butanol/diesel and n-pentanol/diesel blends on performance and emissions of a DI diesel engine under premixed LTC (low temperature combustion) mode. Fuel 170:49–59
Mike Rycroft (2017), Waste plastic to fuel oil: an under-exploited opportunity for energy generation, http://www.ee.co.za/article/waste-plastic-fuel-oil-exploited-opportunity-energy-generation.html, Last Accessed 10 Dec 2017
Saleh HE (2009) Experimental study on diesel engine nitrogen oxide reduction running with jojoba methyl ester by exhaust gas recirculation. Fuel 88(8):1357–1364. https://doi.org/10.1016/j.fuel.2009.01.023
Sun J, Cai Q, Wan Y, Wan S, Wang L, Lin J, Mei D, Wang Y (2016) Promotional effects of cesium promoter on higher alcohol synthesis from syngas over cesium-promoted Cu/ZnO/Al 2 O 3 catalysts. ACS Catal 6(9):5771–5785. https://doi.org/10.1021/acscatal.6b00935
Wang X, Cheung CS, Di Y, Huang Z (2012) Diesel engine gaseous and particle emissions fueled with diesel–oxygenate blends. Fuel 94:317–323. https://doi.org/10.1016/j.fuel.2011.09.016
Wei L, Cheung CS, Huang Z (2014) Effect of n-pentanol addition on the combustion, performance and emission characteristics of a direct-injection diesel engine. Energy 70:172–180
Zhang K, Sawaya MR, Eisenberg DS, Liao JC (2008) Expanding metabolism for biosynthesis of nonnatural alcohols. Proc Natl Acad Sci 105(52):20653–20658. https://doi.org/10.1073/pnas.0807157106
Zhu L, Xiao Y, Cheung CS, Guan C, Huang Z (2016) Combustion, gaseous and particulate emission of a diesel engine fueled with n-pentanol (C5 alcohol) blended with waste cooking oil biodiesel. Appl Therm Eng 102:73–79
Acknowledgements
The authors would like to thank the Indian Institute of Technology, Madras for characterization of WPO and the Polymeric Materials Research Laboratory at Alagappa College, Tamil Nadu for the estimation of fuel properties.
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Damodharan, D., Sathiyagnanam, A.P., Rajesh Kumar, B. et al. Cleaner emissions from a DI diesel engine fueled with waste plastic oil derived from municipal solid waste under the influence of n-pentanol addition, cold EGR, and injection timing. Environ Sci Pollut Res 25, 13611–13625 (2018). https://doi.org/10.1007/s11356-018-1558-5
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DOI: https://doi.org/10.1007/s11356-018-1558-5