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Emissions behavior and distribution of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) from cement kilns in China

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Abstract

The production of cement in China is accompanied by various emissions, such as fine particulate matter, heavy metals, nitrogen oxides, sulfur oxides, carbon dioxide…. Moreover, cement kiln presents a potential health risk to its surroundings, linking to emissions of persistent organic pollutants (POPs), such as polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), in brief dioxins. Flue gas samples were collected from five typical cement kilns during twelve runs and were used to evaluate the levels and distribution of PCDD/Fs in the emissions from cement kilns. The PCDD/Fs concentrations (136 congeners) and I-TEQ values ranged from 2.3 to >40 ng/m3 and 9.3 ∼ 90.8 × 10−3 ng I-TEQ/m3, respectively, which were lower than the emission standard in China (0.1 ng I-TEQ/m3). In weight units, the dominant congeners were OCDD, 1,2,3,4,6,7,8-HpCDF, and OCDF; 2,3,4,7,8-PeCDF is the largest contributor (36–66 %) to the total I-TEQ value of twelve runs. HxCDF and TCDF were the first two most abundant homologue groups (12–85 and 4–52 %), and the homologue concentration decreased with rising chlorine number for PCDDs. In addition, there was no marked difference in homologue profiles when solid wastes (refuse-derived fuel and municipal solid waste) and hazardous wastes (DDT and POPs) were combusted as supplemental fuels. The use of various supplemental fuels had no obvious effect on the fingerprint of PCDD/F homologues. Moreover, there was no significant difference in levels of PCDD/Fs emission due to the diversity of production capacity, which were consistent with reported previously. Air pollution control device had effect on the homologue profiles, and cement system with electrostatic precipitators (ESP) had more fractions of octachloro congeners to the total.

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References

  • Abad E, MartÍnez K, Caixach J, Rivera J (2004) Polychlorinated dibenzo-p-dioxin/polychlorinated dibenzofuran releases into the atmosphere from the use of secondary fuels in cement kilns during clinker formation. Environ Sci Technol 38:4734–4738

    Article  CAS  Google Scholar 

  • Altarawneh M, Dlugogorski BZ, Kennedy EM, Mackie JC (2009) Mechanisms for formation, chlorination, dechlorination and destruction of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Prog Energy Combust Sci 35:245–274

    Article  CAS  Google Scholar 

  • Ames M, Zemba S, Green L, Botelho MJ, Gossman D, Linkov I, Palma OJ (2012) Polychlorinated dibenzo (p) dioxin and furan (PCDD/F) congener profiles in cement kiln emissions and impacts. Sci Total Environ 419:37–43

    Article  CAS  Google Scholar 

  • Australia E (1999) Incineration and dioxins: review of formation processes. Environmental and safety services for environment Australia. Canberra, Australia

    Google Scholar 

  • Australia E (2002) Sources of PCDD/PCDF and furans in Australia—air emissions—revised edition. Canberra, Australia

    Google Scholar 

  • Balbo M, Francois A, Ladebat H, Mosnier F (1998) Cement kiln incineration – a viable waste management solution. International Directory of Solid Waste Management. The ISWA Yearbook, pp. 123–127

  • Buekens A (2012) Incineration technologies. Springer, New York

    Google Scholar 

  • Capmas A (2003) The French cement industry experience in the use of waste fuels. Fifth Colloquium of Managers and Technicians of Cement Plants, Sevilla

  • Carrasco F, Bredin N, Heitz M (2002) Gaseous contaminant emissions as affected by burning scrap tires in cement manufacturing. J Environ Qual 31:1484–1490

    Article  CAS  Google Scholar 

  • Conesa JA, Gálvez A, Mateos F, Martín GI, Font R (2008) Organic and inorganic pollutants from cement kiln stack feeding alternative fuels. J Hazard Mater 158:585–592

    Article  CAS  Google Scholar 

  • Eduljee GH (1998) PCDD/PCDF formation and control in cement kilns. Fourth International Conference on High Temperature. Filtration, Austria

    Google Scholar 

  • Emission Standard of Air Pollutants for Cement Industry (2004) The national standard of the People’s Republic of China

  • Fiedler H, Lau C, Eduljee G (2000) Statistical analysis of patterns of PCDDs and PCDFs in stack emission samples and identification of a marker congener. Waste Manag Res 18:283–292

    Article  CAS  Google Scholar 

  • Giannopoulos D, Kolaitis D, Togkalidou A, Skevis G, Founti M (2007) Quantification of emissions from the co-incineration of cutting oil emulsions in cement plants–Part II: trace species. Fuel 86:2491–2501

    Article  CAS  Google Scholar 

  • Gordon M (2002) Dioxin characterization, formation and minimization during municipal solid waste (MSW) incineration: review. Chem Eng J 86:343–368

    Article  Google Scholar 

  • Haegermann B (2004) PCDD/F data from Heidelberg Cement. Heidelberg, Germany

  • Hashimoto S, Fujita T, Geng Y, Nagasawa E (2010) Realizing CO2 emission reduction through industrial symbiosis: a cement production case study for Kawasaki. Resour Conserv Recycl 54:704–710. doi:10.1016/j.resconrec.2009.11.013

    Article  Google Scholar 

  • Japan Ministry of Environment (2003) http://www.env.go.jp/en/topic/PCDD/PCDF/inventory.pdf

  • Jensen A (2004) Emission testing Chile. Santiago, Chile

    Google Scholar 

  • Karstensen KH (2008) Formation, release and control of dioxins in cement kilns. Chemosphere 70:543–560

    Article  CAS  Google Scholar 

  • Kim DH, Mulholland JA, Ryu JY (2005) Formation of polychlorinated naphthalenes from chlorophenols. Proc Combust Inst 30:1245–1253

    Article  CAS  Google Scholar 

  • Lang T (2004) PCDD/PCDF/Furan data from Holcim. Holcim Group Support Ltd., Corporate Industrial Ecology. Holderbank, Switzerland

    Google Scholar 

  • NATO/CCMS (1988) Scientific basis for the development of international toxicity equivalency factor (I-TEF) method of risk assessment for the complex mixtures of dioxins and related compounds. North Atlantic Treaty Organization/Committee on Challenges of Modern Society, Wasgington DC, USA

  • Reijnders L (2007) The cement industry as a scavenger in industrial ecology and the management of hazardous substances. J Inst Ecol 11:15–25

    Article  CAS  Google Scholar 

  • Reiterer H (2004) PCDD/PCDF data from Lafarge. Lafarge Centre Technique Europe Central. GMBH, Austria

    Google Scholar 

  • Ruuskanen J, Vartiainen T, Kojo I, Manninen H, Oksanen J, Frankenhaeuser M (1994) Formation of polychlorinated dibenzo-p-dioxins and dibenzofurans in cocombustion of mixed plastics with coal: exploratory principal component analysis. Chemosphere 28:1989–1999

    Article  CAS  Google Scholar 

  • Wurst F, Prey T (2003) Dioxin emissions when using alternative fuels in the cement industry. ZKG Int 56:74–77

    CAS  Google Scholar 

  • Xhrouet C, Pirard C, De Pauw E (2001) De novo synthesis of polychlorinated dibenzo-p-dioxins and dibenzofurans on fly ash from a sintering process. Environ Sci Technol 35:1616–1623

    Article  CAS  Google Scholar 

  • Zabaniotou A, Theofilou C (2008) Green energy at cement kiln in Cyprus—use of sewage sludge as a conventional fuel substitute. Renew Sust Energ Rev 12:531–541

    Article  CAS  Google Scholar 

  • Zemba S, Ames M, Green L, Botelho MJ, Gossman D, Linkov I, Palma OJ (2011) Emissions of metals and polychlorinated dibenzo-(p)-dioxins and furans (PCDD/Fs) from Portland cement manufacturing plants: Inter-kiln variability and dependence on fuel-types. Sci Total Environ 409:4198–4205

    Article  CAS  Google Scholar 

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Acknowledgments

The financial support by the National Program on Key Basic Research Project of china (2011CB201500) is greatly acknowledged.

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Authors and Affiliations

  1. State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, Zhejiang, 310027, China

    Tong Chen, Ying Guo, Xiaodong Li, Shengyong Lu & Jianhua Yan

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  1. Tong Chen
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  2. Ying Guo
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  3. Xiaodong Li
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  4. Shengyong Lu
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  5. Jianhua Yan
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Correspondence to Tong Chen.

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Responsible editor: Constantini Samara

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Chen, T., Guo, Y., Li, X. et al. Emissions behavior and distribution of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) from cement kilns in China. Environ Sci Pollut Res 21, 4245–4253 (2014). https://doi.org/10.1007/s11356-013-2356-8

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