Abstract
Reducing carbon dioxide (CO2) into fuels accompanied by renewable resources has been under research since it helps to decrease CO2 levels in the atmosphere. The most suited source is solar energy which is generous and sustainable. In this aspect, photocatalysis (PC) and photo electrocatalysis (PEC) are favorable methods to utilize solar energy for CO2 reduction to carbonaceous fuels. A PEC system is more efficient than a PC system because of the ability to separate photogenerated holes and electrons for higher efficiency. The photo-electrochemical CO2 reduction reaction (PEC-CO2RR) can be considered as an artificial photosynthetic system that stores solar energy and stabilizes CO2 levels in the atmosphere. Here CuO–MgO nanocomposite (NC) is used for the effective PEC reduction of CO2 into viable carbonaceous fuels. A simple and scalable sol–gel process was used for synthesizing the CuO–MgO NC. The synthesized NC’s structural, morphological and elemental analysis was performed using XRD, Raman spectroscopy, SEM and EDX. Optical properties were evaluated using UV spectroscopy. The electrochemical and PEC analysis was carried out to study the catalytic behavior of CuO–MgO towards CO2 reduction by the cyclic voltammetry method. The CuO–MgO NC exhibited significantly improved PEC-CO2RR performance compared to electrochemical reduction alone. Moreover, the CuO–MgO NC displayed high structural stability and durability, which benchmark its potential towards PEC reduction to CO2 into carbonaceous fuels.
Graphical Abstract
Similar content being viewed by others
References
Reddy MSB, Ponnamma D, Sadasivuni KK et al (2021) Carbon dioxide adsorption based on porous materials. RSC Adv 11:12658–12681. https://doi.org/10.1039/d0ra10902a
Shi S, Yin J (2021) Global research on carbon footprint: a scientometric review. Environ Impact Assess Rev 89:106571. https://doi.org/10.1016/j.eiar.2021.106571
Liu Z, Ciais P, Deng Z et al (2020) Near-real-time monitoring of global CO2 emissions reveals the effects of the COVID-19 pandemic. Nat Commun 11:5172. https://doi.org/10.1038/s41467-020-18922-7
Kannan K, Sliem MH, Abdullah AM et al (2020) Fabrication of ZnO–Fe-MXene based nanocomposites for efficient CO2 reduction. Catalysts 10:549. https://doi.org/10.3390/catal10050549
Zhao Y, Liu Z (2019) Transformation of CO2 into Valuable Chemicals. In: Han B, Wu T (eds) Green Chemistry and Chemical Engineering. Springer, New York, pp 285–322
Centi G, Iaquaniello G, Perathoner S (2019) Chemical engineering role in the use of renewable energy and alternative carbon sources in chemical production. BMC Chem Eng 1:5. https://doi.org/10.1186/s42480-019-0006-8
He J, Janáky C (2020) Recent advances in solar-driven carbon dioxide conversion: expectations versus reality. ACS Energy Lett 5:1996–2014. https://doi.org/10.1021/acsenergylett.0c00645
Xu C, Hong J, Sui P et al (2020) standalone solar carbon-based fuel production based on semiconductors. Cell Rep Phys Sci 1:100101. https://doi.org/10.1016/j.xcrp.2020.100101
Kumaravel V, Bartlett J, Pillai SC (2020) Photoelectrochemical conversion of carbon dioxide (CO2) into fuels and value-added products. ACS Energy Lett 5:486–519. https://doi.org/10.1021/acsenergylett.9b02585
Pan Z, Han E, Zheng J et al (2020) Highly efficient photoelectrocatalytic reduction of CO2 to Methanol by a p–n heterojunction CeO2/CuO/Cu catalyst. Nanomicro Lett 12:18. https://doi.org/10.1007/s40820-019-0354-1
Adimule V, Nandi SS, Yallur BC et al (2021) Enhanced photoluminescence properties of Gd (x–1) Sr x O: CdO nanocores and their study of optical, structural, and morphological characteristics. Mater Today Chem 20:100438. https://doi.org/10.1016/j.mtchem.2021.100438
Adimule V, Nandi SS, Yallur BC et al (2021) Optical, structural and photoluminescence properties of Gd x SrO: CdO nanostructures synthesized by co precipitation method. J Fluoresc 31:487–499. https://doi.org/10.1007/s10895-021-02683-7
Adimule V, Revaigh MG, Adarsha HJ (2020) Synthesis and fabrication of Y-doped ZnO nanoparticles and their application as a gas sensor for the detection of ammonia. J Mater Eng Perform 29:4586–4596. https://doi.org/10.1007/s11665-020-04979-4
Hao L, Sun Z (2020) Metal Oxide-based materials for electrochemical CO2 reduction. Acta Phys Chimi Sin 37:2009033. https://doi.org/10.3866/PKU.WHXB202009033
Kannan K, Radhika D, Nesaraj AS et al (2020) Photocatalytic, antibacterial and electrochemical properties of novel rare earth metal oxides-based nanohybrids. Mater Sci Energy Technol 3:853–861. https://doi.org/10.1016/j.mset.2020.10.008
Abbas S, Uzair B, Sajjad S et al (2021) Dual-functional green facile CuO/MgO nanosheets composite as an efficient antimicrobial agent and photocatalyst. Arab J Sci Eng. https://doi.org/10.1007/s13369-021-05741-1
Alla SK, Verma AD, Kumar V et al (2016) Solvothermal synthesis of CuO–MgO nanocomposite particles and their catalytic applications. RSC Adv 6:61927–61933. https://doi.org/10.1039/C6RA03762C
Paramparambath S, Shafath S, Maurya MR et al (2021) Nonenzymatic electrochemical sensor based on CuO–MgO composite for dopamine detection. IEEE Sens J. https://doi.org/10.1109/jsen.2021.3112009
Maurya MR, Toutam V, Haranath D (2017) Comparative study of photoresponse from vertically grown ZnO nanorod and nanoflake films. ACS Omega 2:5538–5544. https://doi.org/10.1021/acsomega.7b00914
Rashad M, Rüsing M, Berth G et al (2013) CuO and Co3O4 nanoparticles: synthesis, characterizations, and raman spectroscopy. J Nanomater 2013:e714853. https://doi.org/10.1155/2013/714853
Weng M, Zhang Z, Okejiri F et al (2021) Encapsulation of CuO nanoparticles within silicalite-1 as a regenerative catalyst for transfer hydrogenation of furfural. iScience 24:102884. https://doi.org/10.1016/j.isci.2021.102884
Chrzanowski J, Irwin JC (1989) Raman scattering from cupric oxide. Solid State Commun 70:11–14. https://doi.org/10.1016/0038-1098(89)90457-2
Li M, Guo W, Li H et al (2014) Electrochemical biosensor based on one-dimensional MgO nanostructures for the simultaneous determination of ascorbic acid, dopamine, and uric acid. Sens Actuators B 204:629–636. https://doi.org/10.1016/j.snb.2014.08.022
Emayavaramban P, Babu SG, Karvembu R et al (2016) Gold nanoparticles supported on magnesium oxide nanorods for oxidation of alcohols. J Nanosci Nanotechnol 16:2517–2526. https://doi.org/10.1166/jnn.2016.10778
Weibel A, Mesguich D, Chevallier G et al (2018) Fast and easy preparation of few-layered-graphene/magnesia powders for strong, hard and electrically conducting composites. Carbon 136:270–279. https://doi.org/10.1016/j.carbon.2018.04.085
Saad I, Hannachi N, Roisnel T, Hlel F (2019) Optical, UV-vis spectroscopy studies, electrical and dielectric properties of transition metal-based of the novel organic-inorganic hybrid (C 6 H 10 N 2 )(Hg 2 Cl 5 )2 .3H 2 O. J Adv Dielectr. https://doi.org/10.1142/S2010135X19500401
Chen T, Stoebe T (1998) Role of copper in LiF:Mg, Cu, P thermoluminescent phosphors. Radiat Prot Dosim. https://doi.org/10.1093/OXFORDJOURNALS.RPD.A032339
Kas R, Hummadi KK, Kortlever R et al (2016) Three-dimensional porous hollow fibre copper electrodes for efficient and high-rate electrochemical carbon dioxide reduction. Nat Commun 7:10748. https://doi.org/10.1038/ncomms10748
Zhang W, Hu Y, Ma L et al (2018) Progress and perspective of electrocatalytic CO2 reduction for renewable carbonaceous fuels and chemicals. Adv Sci 5:1700275. https://doi.org/10.1002/advs.201700275
Acknowledgements
This work was carried by the NPRP11S-1221-170116 from the Qatar National Research Fund (a member of Qatar Foundation). The statements made herein are exclusively the accountability of the authors.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The corresponding author states that there are no conflict of interest to declare on behalf of all authors.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Sha, M.S., Maurya, M.R., Shafath, S. et al. A Hybrid Photo-Electro Catalytic Conversion of Carbon dioxide Using CuO–MgO Nanocomposite. Top Catal (2022). https://doi.org/10.1007/s11244-022-01579-5
Accepted:
Published:
DOI: https://doi.org/10.1007/s11244-022-01579-5