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Effect of the Mesostructuration of the Beta Zeolite Support on the Properties of Cobalt Catalysts for Fischer–Tropsch Synthesis

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Abstract

The effect of mesostructuration of beta zeolite and of metal loading on the properties of cobalt-based catalysts for Fischer–Tropsch synthesis was studied in this work. The most active catalyst was the mesostructured beta zeolite-supported cobalt (10%), which also showed a low selectivity to methane and the lowest olefin/paraffin ratio.

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References

  1. Vanhove D, Zhang Z, Makambo I, Blanchard M (1984) Appl Catal 9:327–342

    Article  CAS  Google Scholar 

  2. Dunn BC, Covington DJ, Cole P, Pungmire RJ, Meuzelaar HLC, Ernst RD, Heider EC, Eyring EM (2004) Energy Fuels 18:1519–1521

    Article  CAS  Google Scholar 

  3. Botes FG (2005) Appl Catal A 284:21–29

    Article  CAS  Google Scholar 

  4. Martínez A, López C (2005) Appl Catal A 294:251–259

    Article  Google Scholar 

  5. Liu Y, Zhang Y, Tsubaki N (2007) Catal Commun 8:773–779

    Article  CAS  Google Scholar 

  6. Mochizuki T, Hara T, Koizumi N, Yamada M (2007) Catal Lett 113:165–169

    Article  CAS  Google Scholar 

  7. Sietsma JRA, den Breejen JP, Jongh PE, van Dillen AJ, Bitter JH, Jong KP (2007) Stud Surf Sci Catal 167:55–60

    Article  CAS  Google Scholar 

  8. Khodakov AY, Chu W, Fongarland P (2007) Chem Rev 107:1692–1744

    Article  CAS  Google Scholar 

  9. Chernavskii PA (2005) Kinet Catal 46:634–640

    Article  CAS  Google Scholar 

  10. Martínez A, López C, Márquez F, Díaz I (2003) J Catal 220:486–499

    Article  Google Scholar 

  11. Iglesia E (1997) Appl Catal A 161:59–78

    Article  CAS  Google Scholar 

  12. Khodakov AY, Griboval-Constant A, Bechara R, Zholobenko V (2002) J Catal 206:230–241

    Article  CAS  Google Scholar 

  13. Rangel MC, Khodakov AY, Aires FJCS, de Souza MO, Eon JG, dos Santos LM, de Souza AO, Constant AG (2010) Stud Surf Sci Catal 175:763–766

    Article  CAS  Google Scholar 

  14. Bessel S (1993) Appl Catal A 96:253–268

    Article  Google Scholar 

  15. Dry ME (1996) Appl Catal A 138:319–344

    Article  CAS  Google Scholar 

  16. Adesina AA (1996) Appl Catal A 138:345–367

    Article  CAS  Google Scholar 

  17. Medina C, García R, Reyes P, Fierro JLG, Escalona N (2010) Appl Catal A 373:71–75

    Article  CAS  Google Scholar 

  18. Procházková D, Bejblová M, Vlk J, Cejka J (2009) Top Catal 52:618–626

    Article  Google Scholar 

  19. Pereira ALC, Santos NA, Ferreira MLO, Albornoz LA, Rangel MC (2007) Stud Surf Sci Catal 167:225–230

    Article  CAS  Google Scholar 

  20. Araújo GC, Lima S, Rangel MC, Pagola V, Peña MA, Fierro JLG (2005) Catal Today 107:906–912

    Article  Google Scholar 

  21. Liu ZW, Li X, Asami K, Fujimoto K (2005) Ind Eng Chem Res 44:7329–7336

    Article  CAS  Google Scholar 

  22. Eliseev OL, Volkov AS, Budtsov VS, Lapidus AL (2007) Dokl Chem 413:79–81

    Article  CAS  Google Scholar 

  23. Ngamcharussrivichai C, Liu X, Li X, Vitidsant T, Fujimoto K (2007) Fuel 86:50–59

    Article  CAS  Google Scholar 

  24. Dry ME (2004) Stud Surf Sci Catal 152:533–593

    Article  CAS  Google Scholar 

  25. Ngamcharussrivichai C, Imyim A, Li X, Fujimoto K (2006) Ind Eng Chem Res 46:6883–6890

    Article  Google Scholar 

  26. Tang Q, Wang P, Zhang Q, Wang Y (2006) Chem Lett 35:366–367

    Article  CAS  Google Scholar 

  27. Grecco STF, Nobre PSS, Gónzalez EAU, Rangel MC (2008) Nanoporous Mater 599–606

  28. Concepción P, López C, Martínez A, Puntes VF (2004) J Catal 228:321–332

    Article  Google Scholar 

  29. Ojeda M, Pérez-Alonso FJ, Terreros P, Rojas S, Herranz T, Granados ML, Fierro JLG (2006) Langmuir 22:3131–3137

    Article  CAS  Google Scholar 

  30. Camblor MA, Corma A, Valencia S (1998) Microporous Mesoporous Mater 25:59–74

    Article  CAS  Google Scholar 

  31. Mrak M, Tusar NN, Logar NZ, Mali G, Kljajic A, Arcon I, Launay F, Gedeon A, Kaucic V (2006) Microporous Mesoporous Mater 95:76–85

    Article  CAS  Google Scholar 

  32. Pejova B, Isahi A, Najdoski M, Grozdanov I (2001) Mater Res Bull 36:161–170

    Article  CAS  Google Scholar 

  33. Pérez-Pariente J, Martens JA, Jacobs PA (1987) Appl Catal 31:35–40

    Article  Google Scholar 

  34. Ehrhardt C, Gjikaj M, Brockner W (2005) Thermochim Acta 432:36–40

    Article  CAS  Google Scholar 

  35. Tang T, Yin C, Wang L, Ji Y, Xiao F (2007) J Catal 249:111–115

    Article  CAS  Google Scholar 

  36. Kong L, Chen H, Tai J, Shen J, Zhang S, Chen J (2009) Mater Lett 63:343–345

    Article  CAS  Google Scholar 

  37. Zhang H, Li Y (2008) Powder Technol 183:73–78

    Article  CAS  Google Scholar 

  38. Naydenov V, Tosheva L, Sterte J (2005) J Porous Mater 12:193–199

    Article  CAS  Google Scholar 

  39. Zhang H, Meng XC, Li YD, Lin YS (2007) Ind Eng Chem Res 46:4186–4192

    Article  CAS  Google Scholar 

  40. Khodakov AY (2009) Braz J Phys 39:171–175

    Article  CAS  Google Scholar 

  41. Xiong H, Zhang Y, Li J, Gu Y (2004) J Central South Univ Technol 11:414–418

    Article  CAS  Google Scholar 

  42. Martínez A, Prieto G (2007) J Catal 245:470–476

    Article  Google Scholar 

  43. Jean-Marie A, Griboval-Constant A, Khodakov A, Diehl FCR (2009) Chimie 12:660–667

    Article  CAS  Google Scholar 

  44. Zhang Y, Yoneyama Y, Fujimoto K, Tsubaki N (2003) Top Catal 26:129–137

    Article  CAS  Google Scholar 

  45. Sapag K, Rojas S, López Granados M, Fierro JLG, Mendioroz S (2001) J Mol Catal A 167:81–89

    Article  CAS  Google Scholar 

  46. Robles-Dutenhefner PA, Rocha KA, Sousa EMB, Gusevskaya EV (2009) J Catal 265:72–79

    Article  CAS  Google Scholar 

  47. Kabanji AH, Joseph B, Wolan JT (2009) Catal Lett 130:72–78

    Article  Google Scholar 

  48. Ferreira AP, Henriques C, Ribeiro MF, Ribeiro FR (2005) Catal Today 107:181–191

    Article  Google Scholar 

  49. Zhang Y, Nagamori S, Hinchiranan S, Vitidsant T, Tsubaki N (2006) Energy Fuels 20:417–421

    Article  CAS  Google Scholar 

  50. Li H, Li J, Ni H, Song D (2006) Catal Lett 110:71–76

    Article  CAS  Google Scholar 

Download references

Acknowledgments

ALCP acknowledges CAPES for her graduate fellowship. The authors acknowledge to CNPq and FINEP for the financial support. JMGC acknowledge Ministerio de Ciencia e Innovación the Spain through the Formación de Profesorado Universitario program (FPU) for the financial support.

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Authors and Affiliations

  1. GECCAT Grupo de Estudos em Cinética e Catálise, Instituto de Química, Universidade Federal da Bahia, Campus Universitário de Ondina, Salvador, Bahia, 40170-290, Brazil

    Amalia Luz Costa Pereira & Maria do Carmo Rangel

  2. EQS Grupo de Energia y Química Sostenibles, Instituto de Catálisis y Petroleoquímica del CSIC, Calle Marie Curie 2, Cantoblanco, 28049, Madrid, Spain

    Juan Maria González-Carballo, Francisco José Pérez-Alonso, Sergio Rojas & José Luis Garcia Fierro

Authors
  1. Amalia Luz Costa Pereira
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  2. Juan Maria González-Carballo
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  3. Francisco José Pérez-Alonso
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  4. Sergio Rojas
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  5. José Luis Garcia Fierro
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  6. Maria do Carmo Rangel
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Corresponding author

Correspondence to Maria do Carmo Rangel.

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Pereira, A.L.C., González-Carballo, J.M., Pérez-Alonso, F.J. et al. Effect of the Mesostructuration of the Beta Zeolite Support on the Properties of Cobalt Catalysts for Fischer–Tropsch Synthesis. Top Catal 54, 179–189 (2011). https://doi.org/10.1007/s11244-011-9637-6

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  • DOI: https://doi.org/10.1007/s11244-011-9637-6

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