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The influence of hierarchical zeolite composition and pore structure on behavior of cobalt-based Fischer–Tropsch synthesis catalysts

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Cobalt catalyst supported on hierarchical zeolite possessing a three different Si/Al ratio was studied in Fischer–Tropsch synthesis. The catalyst with Si/Al ratio of 60 was found to be superior to other catalysts in terms of better C5–18 selectivity and higher olefin/paraffin ratio due to smaller cobalt particles and larger number of acidic sites. While Co/Meso-ZSM120 catalyst with perfect crystal structure favored products to accessibility and prevented cobalt particles from being oxidized compared to that of amorphous support, resulting in the lowest deactivation rate and the lowest carbon content on the surface.

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Acknowledgments

The work was supported by the National Natural Science Foundation of China (21106177, 21203232, 51204182), the Open funds of Key Laboratory of Biofuel (CASKLB201306) and The Basic Research Funds for Central University (2010QNA17), A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

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Authors and Affiliations

  1. Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, School of Chemical Engineering, China University of Mining and Technology, Xuzhou, 221116, Jiangsu, China

    Weiming Zhao, Yuelun Wang, Jun Huang & Yunpeng Zhao

  2. Key Laboratory of Biofuel, Chinese Academy of Sciences, Qingdao Institute of Bioenergy and Bioprocess Technology, Qingdao, 266101, China

    Zhuo Li, Hui Wang & Jinhu Wu

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  1. Weiming Zhao
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  2. Yuelun Wang
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  3. Zhuo Li
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  4. Hui Wang
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  5. Jinhu Wu
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  6. Jun Huang
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  7. Yunpeng Zhao
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Correspondence to Yuelun Wang.

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Zhao, W., Wang, Y., Li, Z. et al. The influence of hierarchical zeolite composition and pore structure on behavior of cobalt-based Fischer–Tropsch synthesis catalysts. J Porous Mater 22, 1097–1104 (2015). https://doi.org/10.1007/s10934-015-9984-y

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