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Nature of carbonaceous deposits on the alumina supported transition metal oxide catalysts in the wet air oxidation of phenol

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Abstract

Al2O3 supported transition metal (Mn, Fe, Co, Ni, and Cu) oxide catalysts were prepared and tested for the wet oxidation of phenol. The supported copper oxide catalysts showed the highest catalytic activity due to their highest surface reducibility. There was carbonaceous deposits on the used catalysts for the wet oxidation of phenol and the supported manganese oxide catalysts showed the highest amount of carbonaceous deposits. These carbonaceous deposits must have their own micropores which resulted in the decrease of the pore volume and the increase of the surface area. The NMR and FTIR spectroscopy showed that the carbonaceous deposits were mostly of aromatic nature and contained some oxygen-bearing groups such as carboxylic acids and alcohols.

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References

  • V. S. Mishira V. V. Mahajani J. B. Joshi (1995) Ind. Eng. Chem. Res 34 2 Occurrence Handle1:CAS:528:DyaK2MXjtFGks78%3D

    CAS  Google Scholar 

  • Y. I. Matatov-Meytal M. Sheintuch (1998) Ind. Eng. Chem. Res 37 309 Occurrence Handle1:CAS:528:DyaK1cXjsVGjsQ%3D%3D

    CAS  Google Scholar 

  • J. Levec A. Pintar (1995) Catal Today 24 51 Occurrence Handle1:CAS:528:DyaK2MXlvFKhs70%3D

    CAS  Google Scholar 

  • F. Luck (1996) Catal. Today 27 195 Occurrence Handle1:CAS:528:DyaK28XhtF2hsbg%3D

    CAS  Google Scholar 

  • M. Besson A. Kallel P. Gallezot R. Zanella C. Louis (2003) Catal. Comm. 4 471 Occurrence Handle1:CAS:528:DC%2BD3sXmvV2ms78%3D

    CAS  Google Scholar 

  • S. Hosokawa H. Kanai K. Utani Y. Taniguchi Y. Saito S. Imamura (2003) Appl. Catal. B. 45 181 Occurrence Handle1:CAS:528:DC%2BD3sXntVCisbg%3D

    CAS  Google Scholar 

  • F. Arena R. Giovenco T. Torre A. Venuto A. Parmaliana (2003) Appl. Catal. B. 45 51 Occurrence Handle1:CAS:528:DC%2BD3sXms1Cktbk%3D

    CAS  Google Scholar 

  • P.M. Alvarez D. McLurgh P. Plucinski (2002) Ind. Eng. Chem. Res 41 2147 Occurrence Handle1:CAS:528:DC%2BD38XisFKrtb4%3D

    CAS  Google Scholar 

  • A. Pintar J. Levec (1992) J. Catal 135 345 Occurrence Handle1:CAS:528:DyaK38XktVOgt7k%3D

    CAS  Google Scholar 

  • S. Hamoudi F. Larachi A. Adnot A. Sayari (1999) J. Catal 185 333 Occurrence Handle1:CAS:528:DyaK1MXksVOjt7c%3D

    CAS  Google Scholar 

  • S. Hamoudi F. Larachi A. Sayari (1998) J. Catal 177 247

    Google Scholar 

  • S. Hamoudi F. Larachi G. Cerrella M. Cassanello (1998) Ind. Eng. Chem. Res 37 3561 Occurrence Handle1:CAS:528:DyaK1cXkvF2mur8%3D

    CAS  Google Scholar 

  • S.T. Hussain A. Sayari F. Larachi (2001) Appl. Catal. B 34 1 Occurrence Handle1:CAS:528:DC%2BD3MXos1KisrY%3D

    CAS  Google Scholar 

  • S.T. Hussain A. Sayari F. Larachi (2001) J. Catal 201 153 Occurrence Handle1:CAS:528:DC%2BD3MXksVWqtbo%3D

    CAS  Google Scholar 

  • S. Hamoudi K. Belkacemi F. Larachi (1999) Chem. Eng. Sci 54 3569 Occurrence Handle1:CAS:528:DyaK1MXksVSlu7c%3D

    CAS  Google Scholar 

  • F. Larach K. Belkacemi S. Hamoudi A. Sayari (2001) Catal. Today 64 163

    Google Scholar 

  • C. Kim (2002) J. Hazard. Mater B91 285

    Google Scholar 

  • C. Hettige K. R. R. Mahanama D. P. Dissanayake (2001) Chemosphere 43 1079 Occurrence Handle1:CAS:528:DC%2BD3MXislGgsL8%3D Occurrence Handle11368223

    CAS  PubMed  Google Scholar 

  • S.K. Kim S.K. Ihm (2002) Ind. Eng. Chem. Res 41 1967 Occurrence Handle1:CAS:528:DC%2BD38XitVOjt7Y%3D

    CAS  Google Scholar 

  • Q. Zhang K.T. Chuang (1998) Ind. Eng. Chem. Res 37 3343 Occurrence Handle1:CAS:528:DyaK1cXkvVGktr8%3D

    CAS  Google Scholar 

  • A. Sadana F.R. Katzer (1974) Ind. Eng. Chem. Fund 13 127 Occurrence Handle1:CAS:528:DyaE2cXktVKjtL8%3D

    CAS  Google Scholar 

  • S. Imamura A. Doi S. Ishida (1985) Ind. Eng. Chem. Prod. Res. Dev. 24 75 Occurrence Handle1:CAS:528:DyaL2MXotlygtg%3D%3D

    CAS  Google Scholar 

  • C. Leitenburg D. Goi A. Primavera A. Trovarelli G. Dolcetti (1996) Appl. Catal. B. 11 L29

    Google Scholar 

  • M. Absi-Halabi A. Stanislaus D.L. Trimm (1991) Appl. Catal 72 193 Occurrence Handle1:CAS:528:DyaK3MXktFWqtLs%3D

    CAS  Google Scholar 

  • Y. Tanaka H. Shimada N. Matsubayashi A. Nishijima M. Nomura (1998) Catal. Taday 45 319 Occurrence Handle1:CAS:528:DyaK1cXntVGjurY%3D

    CAS  Google Scholar 

  • J.B. Lambert H.F. Shurvell D.L. Lightner R.G. Kooks (1987) Indroduction to Organic Spectroscopy Macmillan Publishing Company New York

    Google Scholar 

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  1. National Research Laboratory for Environmental Catalysis, Department of Chemical Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon, 305-701, Korea

    Sang-Kyung Kim & Son-Ki Ihm

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  1. Sang-Kyung Kim
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  2. Son-Ki Ihm
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Correspondence to Son-Ki Ihm.

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Kim, SK., Ihm, SK. Nature of carbonaceous deposits on the alumina supported transition metal oxide catalysts in the wet air oxidation of phenol. Top Catal 33, 171–179 (2005). https://doi.org/10.1007/s11244-005-2523-3

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