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Nickel(II) complexes of ONS and ONN chelating thiosemicarbazones with triphenylphosphine co-ligands

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Abstract

Reactions of 5-bromo-2-hydroxy-benzaldehyde-S-R-4-R1-thiosemicarbazones, [R, R1 = H,H (L1); CH3, H (L2); H, C6H5 (L3); CH3, C6H5 (L4)] with [Ni(PPh3)2Cl2] in 1:1 molar ratio yielded complexes of general formula [Ni(L)(PPh3)]. While the complexes of L1 and L3 involve the ONS donor set of the thiosemicarbazone, the L2 complexes utilize the ONN set. The reaction of L4 and the nickel salt gave the L3 complex by loss of the CH3 group from the sulphur. The complexes were characterized by physico-chemical and spectroscopic methods. The structures of the L1 and L2 complexes have been determined by single crystal X-ray diffraction and a new coordination mode (ONN) of salicylaldehyde thiosemicarbazones has been identified.

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Acknowledgements

This work was supported by the Research Fund of Istanbul University. Project No. T-957/06102006.

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Authors and Affiliations

  1. Department of Chemistry, Istanbul University, 34320, Istanbul, Avcılar, Turkey

    Şükriye Güveli, Tülay Bal-Demirci & Bahri Ülküseven

  2. Dept Phys, Arts & Sci Fac, Ondokuz Mayis University, 55139, Samsun, Turkey

    Namık Özdemir

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  1. Şükriye Güveli
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  2. Tülay Bal-Demirci
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  3. Namık Özdemir
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  4. Bahri Ülküseven
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Correspondence to Bahri Ülküseven.

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Güveli, Ş., Bal-Demirci, T., Özdemir, N. et al. Nickel(II) complexes of ONS and ONN chelating thiosemicarbazones with triphenylphosphine co-ligands. Transition Met Chem 34, 383–388 (2009). https://doi.org/10.1007/s11243-009-9206-z

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