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Coordinative properties of the pyridine-2-carbaldehyde thiosemicarbazone ligand towards Ni(II)

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Abstract

Three crystal structures of Ni compounds containing bis(pyridine-2-carbaldehyde thiosemicarbazone) ligand (HL), namely (pyridine-2-carbaldehyde thiosemicarbazonato)(pyridine-2-carbaldeyde thiosemicarbazone) nickel(II) nitrate hydrate [Ni(HL)L][NO3]·(H2O) (1), bis(pyridine-2-carbaldehyde thiosemicarbazone) nickel(II) dinitrate [Ni(HL)2][NO3]2·(2a), and bis(pyridine-2-carbaldehyde thiosemicarbazone) nickel(II) dinitrate dihydrate [Ni(HL)2][NO3]2·2(H2O) (2b) are determined by X ray diffraction methods. Comparative structural studies are carried out.

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References

  1. A. Buschini, S. Pinelli, C. Pellacani, F. Giordani, M. Ferrari, F. Bisceglie, M. Giannetto, G. Pelosi, and P. Tarasconi, J. Inorg. Biochem., 103, 666–677 (2009).

    Article  CAS  Google Scholar 

  2. G. Pelosi, The Open Christallography J., 3, 16–28 (2010).

    Article  CAS  Google Scholar 

  3. SMART Software Users Guide, Version 5.1; Bruker Analytical X-ray Systems, Madison, WI (1999).

  4. SAINT Software Users Guide, Version 6.0; Bruker Analytical X-ray Systems, Madison, WI (1999).

  5. G. M. Sheldrick, SADABS; Bruker Analytical X-ray Systems, Madison, WI (1999).

    Google Scholar 

  6. G. M. Sheldrick, SHELXTL v5.1: Program for the Refinement of Crystal Structures 97-2; Univ. Göttingen, Germany (1998).

    Google Scholar 

  7. N. C. Kasuga, K. Sekino, C. Koumo, N. Shimada, M. Ishikawa, and K. Nomiya, J. Inorg. Biochem., 84, 55 (2001); E. Manoj and M. R. P. Kurup, Polyhedron, 27, 275 (2008); I. Garcia, E. Bermejo, A. K. El Sawaf, A. Castineiras, and D. X. West, Polyhedron, 21, 729 (2002); A. Sreekanth, S. Sivakumar, and M. R. P. Kurup, J. Mol. Struct., 655, 47 (2003); V. Amendola, M. Boiocchi, L. Fabbrizzi, and L. Mosca, Chem. Eur. J., 14, 9683 (2008); E. Bermejo, A. Castineiras, I. Garcia-Santos, L. M. Fostiak, J. K. Swearingen, and D. X. West, Z. Anorg. Allg. Chem., 631, 728 (2005).

    Article  CAS  Google Scholar 

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Correspondence to C. Graiff.

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Original Russian Text © 2014 C. Graiff, S. Canossa, G. Predieri.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 3, pp. 522–526, May–June, 2014.

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Graiff, C., Canossa, S. & Predieri, G. Coordinative properties of the pyridine-2-carbaldehyde thiosemicarbazone ligand towards Ni(II). J Struct Chem 55, 493–497 (2014). https://doi.org/10.1134/S0022476614030159

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  • DOI: https://doi.org/10.1134/S0022476614030159

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