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Mononuclear and heterobimetallic palladium(II) and platinum(II) complexes containing the mixed ligands N-(2-pyridyl or 2-pyrimidyl) acetamide and tertiary diphosphine

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Abstract

Palladium(II) and platinum(II) complexes containing mixed ligands N-(2-pyridyl)acetamide (AH) or N-(2-pyrimidyl)acetamide (BH) and the diphosphines Ph2P(CH2) n PPh2, (n = 1, 2 or 3) have been prepared. The prepared complexes [Pd(A)2(diphos)] or [Pd(B)2(diphos)] have been used effectively to prepare bimetallic complexes of the type [(diphos)Pd(μ-L)2M′Cl2] where M′ = Co, Cu, Mn, Ni, Pd, Pt or SnCl2; L = A or B. The prepared complexes were characterized by elemental analysis magnetic susceptibility, i.r. and UV–Vis spectral data. 31P–{1H}-n.m.r. data have been applied to characterize the produced linkage isomers.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, University of Tikrit, Tikrit, Iraq

    Subhi A. Al-Jibori

  2. Department of Chemistry, College of Science, University of Salahaddin, Erbil, Iraq

    Ali I. Abdullah

  3. Department of Chemistry, College of Basic Science, Applied Science University, Shafa Badran, Amman, 11931, Jordan

    Talal A. K. Al-Allaf

Authors
  1. Subhi A. Al-Jibori
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  2. Ali I. Abdullah
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  3. Talal A. K. Al-Allaf
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Correspondence to Subhi A. Al-Jibori.

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Al-Jibori, S.A., Abdullah, A.I. & Al-Allaf, T.A.K. Mononuclear and heterobimetallic palladium(II) and platinum(II) complexes containing the mixed ligands N-(2-pyridyl or 2-pyrimidyl) acetamide and tertiary diphosphine. Transition Met Chem 32, 398–406 (2007). https://doi.org/10.1007/s11243-006-0193-z

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  • DOI: https://doi.org/10.1007/s11243-006-0193-z

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