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Copper(II) and lead(II) complexes based on 2,3,5,6-tetrakis(2-pyridyl)pyrazine as a polydentate ligand

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Abstract

The Cu(II) complexes [Cu(Tppz)(Dipic)] · 8H2O (I) and [Pb2(Tppz)Cl4] n (II), where Tppz, H2Dipic are 2,3,5,6-tetrakis(2-pyridyl)pyrazine, dipicolinic acid, respectively, have been synthesized and characterized by elemental analyses, IR, cyclic voltammetry, and electronic spectral studies. Solid state structures of both complexes have been determined by single crystal X-ray crystallography. An ORTEP drawing of two complexes shows that the coordination geometry around the metal center is a distorted octahedron. There are extensive conventional intermolecular O-H…O, N-H…O, and weaker C-H…O and C-H…Cl non-classical hydrogen bonds, which cause the stability of the crystal structure. Crystal data for I: monoclinic, space group: C2/c, a = 35.421(3), b = 8.422(6), c = 22.824(8) Å, β = 101.69(2)°, V = 6668(5) Å3, Z = 8. Crystal data for II: triclinic, space group P \(\bar 1\), a = 7.9534(4), b = 8.8682(5), c = 9.4245(5) Å, β = 95.086(2)°, V = 655.93(6) Å3, Z = 2.

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Authors and Affiliations

  1. Department of Chemistry, Ferdowsi University of Mashhad, Mashhad, 91779, Iran

    A. S. Saljooghi, A. Salimi, F. Delavarmendi & M. Zahmati

  2. Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Messina, 98166, Italy

    H. A. Rudbari & F. Nicolò

Authors
  1. A. S. Saljooghi
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  2. H. A. Rudbari
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  3. F. Nicolò
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  4. A. Salimi
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  5. F. Delavarmendi
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  6. M. Zahmati
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Correspondence to A. S. Saljooghi.

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Saljooghi, A.S., Rudbari, H.A., Nicolò, F. et al. Copper(II) and lead(II) complexes based on 2,3,5,6-tetrakis(2-pyridyl)pyrazine as a polydentate ligand. Russ J Coord Chem 40, 424–431 (2014). https://doi.org/10.1134/S1070328414060062

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  • DOI: https://doi.org/10.1134/S1070328414060062

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