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Synthesis, characterization and catalytic oxidation of cyclohexene with molecular oxygen over host (zeolite-Y)/guest (nickel(II) complexes of R2[12]1,3-dieneN2O2 and R2[13]1,4-dieneN2O2; R = H, Me, Ph) nanocatalyst (HGN)

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Abstract

12- and 13-Membered diaza dioxa Schiff-base nickel(II) complexes were successfully prepared in a nanoscale microreactor by the template condensation of (1,8-diamino-3,6-dioxaoctane)nickel(II) complex with bifunctional diketones within the nanodimensional pores of zeolite Y. The host–guest nanocatalyst (HGN); ([Ni((R2[12]1,3-dieneN2O2)]2+-NaY, [Ni(R2[13]1,4-dieneN2O2)]2+-NaY; R = H, Me and Ph) is catalytically very efficient as compared to other neat complexes for oxidation of cyclohexene with molecular oxygen as oxidant in the absence of solvent at 70 °C, affording 2-cyclohexene-1-ol and 2-cyclohexene-1-one.

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Authors and Affiliations

  1. Institute of Nano Science and Nano Technology, University of Kashan, Kashan, 87317–51167, Iran

    Masoud Salavati-Niasari

  2. Department of Chemistry, University of Kashan, Kashan, 87317–51167, Iran

    Shirin Shafaie-Arani

  3. Center of Excellence in Electrochemistry, Department of Chemisrtry, Tehran University, Tehran, Iran

    Mohammad Reza Ganjali & Parviz Norouzi

Authors
  1. Masoud Salavati-Niasari
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  2. Shirin Shafaie-Arani
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  3. Mohammad Reza Ganjali
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  4. Parviz Norouzi
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Correspondence to Masoud Salavati-Niasari.

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Salavati-Niasari, M., Shafaie-Arani, S., Ganjali, M.R. et al. Synthesis, characterization and catalytic oxidation of cyclohexene with molecular oxygen over host (zeolite-Y)/guest (nickel(II) complexes of R2[12]1,3-dieneN2O2 and R2[13]1,4-dieneN2O2; R = H, Me, Ph) nanocatalyst (HGN). Transition Met Chem 31, 964–969 (2006). https://doi.org/10.1007/s11243-006-0097-y

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  • DOI: https://doi.org/10.1007/s11243-006-0097-y

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