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Bis(dibenzo[c.e][1,2]oxaphosphorino)dichloroplatinum Complexes

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Abstract

Reaction of a series of P-amino and P-cycloalkoxy dibenzo[c.e][1,2]oxaphosphorines (1), (3) and (5) with cis-bis(benzonitrile)dichloroplatinum(II) afforded the title bis(dibenzooxaphosphorino) complexes (2), (4) and (6), respectively. In the case of chiral P-substituents, the complexes (4) and (6) were obtained in homo and heterochiral forms. Stereospecific 1J(195Pt–P) couplings found in the 31P-n.m.r. spectra of the products (2), (4) and (6) suggested the cis orientation of the identical substituents.

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References

  1. E.N. Jacobsen A. Pfaltz H. Yamamoto (1999) Comprehensive Asymmetric Catalysis Springer New York

    Google Scholar 

  2. H. Brunner W. Zettlmeier (1993) Handbook of Enantioselective Catalysis with Transition Metal Compounds NumberInSeriesVol. II Weinheim VCH

    Google Scholar 

  3. F. Mathey, in: F. Mathey (ed.), Phosphorus–Carbon Heterocyclic Chemistry: The Rise of a New Domain, Pergamon, The Netherlands, 2001. Ch. 7, p.753

  4. Gy. Keglevich T. Chuluunbaatar B. Dajka K. Ludányi Gy. Parlagh T. Kégl L. Kollár L. Tőke (2002) J. Organomet. Chem. 643–644 32

    Google Scholar 

  5. Gy. Keglevich M. Sipos D. Szieberth Gy. Petőcz L. Kollár (2004) J. Organomet. Chem. 689 3158 Occurrence Handle10.1016/j.jorganchem.2004.06.062 Occurrence Handle1:CAS:528:DC%2BD2cXnsVGnsLg%3D

    Article  CAS  Google Scholar 

  6. Gy. Keglevich H. Szelke A. Kerényi T. Imre K. Ludányi J. Dukai F. Nagy P. Arányi (2004) Heteroatom Chem. 15 459 Occurrence Handle1:CAS:528:DC%2BD2cXnvFyit74%3D

    CAS  Google Scholar 

  7. H. Szelke, Gy. Keglevich, A. Kerényi, V. Kudar, M. Hanusz, K. Simon, T. Imre, K. Ludányi, J. Dukai, F. Nagy and P. Arányi, Tetrahedron Asym., in press (2005).

  8. Zs. Csók Gy. Keglevich Gy. Petőcz L. Kollár (1999) J. Organomet. Chem. 586 79 Occurrence Handle10.1016/S0022-328X(99)00156-4

    Article  Google Scholar 

  9. Zs. Csók Gy. Keglevich Gy. Petőcz L. Kollár (1999) Inorg. Chem. 38 831

    Google Scholar 

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Authors and Affiliations

  1. Department of Organic Chemical Technology, Budapest University of Technology and Economics, 1521, Budapest, Hungary

    György Keglevich & Andrea Kerényi

  2. Research Group of the Hungarian Academy of Sciences, Department of Organic Chemical Technology, Budapest University of Technology and Economics, 1521, Budapest, Hungary

    Helga Szelke

  3. Hungarian Academy of Sciences, Chemical Research Center, 1525, Budapest, Hungary

    Timea Imre

Authors
  1. György Keglevich
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  2. Andrea Kerényi
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  3. Helga Szelke
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  4. Timea Imre
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Correspondence to György Keglevich.

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Keglevich, G., Kerényi, A., Szelke, H. et al. Bis(dibenzo[c.e][1,2]oxaphosphorino)dichloroplatinum Complexes. Transition Met Chem 31, 306–309 (2006). https://doi.org/10.1007/s11243-005-6422-z

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  • DOI: https://doi.org/10.1007/s11243-005-6422-z

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