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Effect of the production conditions on the size and magnetic characteristics of iron sulfide Fe3S4 nanoparticles

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Theoretical and Experimental Chemistry Aims and scope

It was shown that the reaction of the trinuclear complex [FeFe2O(CH3CO2)6(H2O)3]·2H2O with thiourea in tetraethylene glycol leads to the formation of nanoparticles of thiospinel Fe3S4, the size of which depends on the reaction conditions. It was established that the formed thiospinel particles exhibit superparamagnetic characteristics. It was shown that the size of the nanoparticles has an effect on their magnetic characteristics.

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The work was carried out with financial support from a targeted comprehensive program of fundamental investigations of the National Academy of Sciences of Ukraine “Fundamental problems of nanostructured systems, nanomaterials, and nanotechnologies” (project No. 42/10-H).

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    I. V. Vasilenko & V. V. Pavlishchuk

  2. UMR, Université de Rennes, CNRS 6226, Sciences Chimiques de Rennes, Bat 10B, Campus de Beaulieu, Av du Gal Leclerc, 35042, Rennes, France

    O. Cador & L. Ouahab

Authors
  1. I. V. Vasilenko
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  2. O. Cador
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  3. L. Ouahab
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  4. V. V. Pavlishchuk
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Correspondence to V. V. Pavlishchuk.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 46, No. 5, pp. 312–316, September-October, 2010.

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Vasilenko, I.V., Cador, O., Ouahab, L. et al. Effect of the production conditions on the size and magnetic characteristics of iron sulfide Fe3S4 nanoparticles. Theor Exp Chem 46, 322–327 (2010). https://doi.org/10.1007/s11237-010-9160-z

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  • DOI: https://doi.org/10.1007/s11237-010-9160-z

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