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Iron (III) sulfide particles produced by a polyol method

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Abstract

Iron(III) sulfide Fe2S3 particles were produced using a polyol method. Although pyrrhotite Fe1−xS appeared together with Fe2S3, the relative yield of Fe2S3 changed when the concentration of reagents in the oleylamine changed. Mössbauer spectra of the particles showed superparamagnetic doublets due to Fe2S3 at 293 K, along with a hyperfine magnetic splitting of H = 24.7 T at 6 K. XRD patterns of the Fe2S3 suggested a structure similar to that of greigite Fe3S4.

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Authors and Affiliations

  1. Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan

    Ryo Shimizu, Ippei Kubono & Yasuhiro Yamada

  2. The University of Electro-Communications, 1-5-1 Chofugaoka, Chofu, Tokyo, 182-8585, Japan

    Yoshio Kobayashi

  3. RIKEN, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan

    Yoshio Kobayashi

Authors
  1. Ryo Shimizu
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  2. Ippei Kubono
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  3. Yoshio Kobayashi
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  4. Yasuhiro Yamada
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Correspondence to Yasuhiro Yamada.

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Proceedings of the 5th Joint International Conference on Hyperfine Interactions and International Symposium on Nuclear Quadrupole Interactions (HFI/NQI 2014) Canberra, Australia, 21-26 September 2014

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Shimizu, R., Kubono, I., Kobayashi, Y. et al. Iron (III) sulfide particles produced by a polyol method. Hyperfine Interact 231, 115–121 (2015). https://doi.org/10.1007/s10751-014-1095-7

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  • DOI: https://doi.org/10.1007/s10751-014-1095-7

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