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Crystal structure and triboluminescence of europium(III) tetrakis-thenoyl trifluoroacetonate with outer-sphere organic cation

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Abstract

A novel complex of Eu(III) tetrakis-thenoyltrifluoroacetonate with the outer-sphere cation 2-(E)-1-(2-thenoyl)ethylidene)-1-hydrazonium carboxyimidoamide (Q) of the composition Q[Eu(TTA)4]·H2O (TTA, thenoyltrifluoroacetonate-ion; Q, outer-sphere cation) characterized with intense luminescence and triboluminescence has been synthesized. The structure of the centrosymmetric hydrazonium crystal is composed of complex anions of the composition [Eu(TTA)4]−, which are stacked in layers parallel to the plane (100), whereas interlayers of organic cations are located between the layers. A structural model for the formation of triboluminescent properties has been suggested.

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The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

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Funding

The work was supported by the State Assignment, project No.FWFN (0205) -2022-0003.

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    Boris V. Bukvetskii, Natalya V. Petrochenkova & Anatolii G. Mirochnik

  2. Nevelskoy Maritime State University, 690059, Vladivostok, Russia

    Natalya V. Petrochenkova

Authors
  1. Boris V. Bukvetskii
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  2. Natalya V. Petrochenkova
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  3. Anatolii G. Mirochnik
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Contributions

All authors contributed to the study conception and design. Boris Bukvetskii: investigation formal analysis, visualization, writing — original draft. Natalya Petrochenkova: investigation formal analysis, visualization, writing — original draft. Anatolii Mirochnik: conceptualization project administration, investigation, funding acquisition, writing — review & editing. All authors read and approved the final manuscript.

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Correspondence to Anatolii G. Mirochnik.

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Bukvetskii, B.V., Petrochenkova, N.V. & Mirochnik, A.G. Crystal structure and triboluminescence of europium(III) tetrakis-thenoyl trifluoroacetonate with outer-sphere organic cation. Struct Chem 34, 1707–1713 (2023). https://doi.org/10.1007/s11224-022-02096-7

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