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Structural characterization of a complex derived from lead(II) perchlorate and acridono-18-crown-6 ether

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Abstract

This paper describes the X-ray crystal structure of a complex of acridono-18-crown-6 ether 3 and lead(II) perchlorate. The structure shows a π–π bonded heterodimer in the crystal. One part of the dimer moves to 9-hydroxyacridine tautomeric form upon lead(II) complexation, in which the lead(II) ion is eight-coordinated and fits well into the cavity of the macrocycle. The other part of the dimer stays in the 9(10H)-acridone tautomeric form, which favors water complexation. The average bond distance of the two tricyclic units (3.5 Å) indicates a strong π–π interaction. The X-ray studies also revealed a cation–π interaction between lead(II) and the electron-rich acridone moiety.

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Acknowledgments

Financial supports of the Hungarian Scientific Research Fund (OTKA K112289, K109486 and NK84008), the CRP/HUN14-01 ICGEB Research Grant and the New Széchenyi Development Plan (TÁMOP-4.2.1/B-09/1/KMR-2010-0002) are gratefully acknowledged.

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Authors and Affiliations

  1. Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, PO Box 91, Budapest, 1521, Hungary

    Tamás Németh, Ádám Golcs, Tünde Tóth & Péter Huszthy

  2. Institute of Enzymology, RCNS, Hungarian Academy of Sciences, Budapest, Hungary

    Ibolya Leveles & Beáta G. Vértessy

  3. Department of Applied Biotechnology and Food Sciences, Budapest University of Technology and Economics, Budapest, Hungary

    Ibolya Leveles & Beáta G. Vértessy

Authors
  1. Tamás Németh
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  2. Ádám Golcs
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  3. Ibolya Leveles
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  4. Tünde Tóth
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  5. Beáta G. Vértessy
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  6. Péter Huszthy
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Correspondence to Péter Huszthy.

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Dedicated to Professor Magdolna Hargittai on the occasion of her 70th birthday.

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Németh, T., Golcs, Á., Leveles, I. et al. Structural characterization of a complex derived from lead(II) perchlorate and acridono-18-crown-6 ether. Struct Chem 26, 1467–1471 (2015). https://doi.org/10.1007/s11224-015-0657-x

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  • DOI: https://doi.org/10.1007/s11224-015-0657-x

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