Skip to main content
SpringerLink
Log in

Synthesis, structure, and photophysical property of series of Ln(III) coordination polymers with different carboxylato ligands (Ln = Sm, Eu)

  • Original Research
  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

Four Ln(III) coordination polymers, {[Ln2(1,3-bdc)3(H2O)4]·DMF·H2O} n (Ln = Sm 1, Eu 2) and [Ln2(mal)3(H2O)6] n (Ln = Sm 3, Eu 4) (1,3-H2bdc = isophthalate acid, H2mal = malonate acid), were hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectra, UV–Vis–NIR absorption spectra, and fluorescence spectra. The structural analyses reveal that polymer 1 is a 3D coordination polymer. Its asymmetry unit contains two crystallographically independent Sm(III) ions, both are eight-coordinated. The 1,3-bdc2− anions show three different coordination modes. The structure of polymer 2 is isomorphous with that of 1. Polymer 3 is also a 3D coordination polymer, its asymmetry unit contains one Sm(III) ion, which is nine-coordinate. The mal2− anions have two different coordination modes. The structure of polymer 4 is isomorphous with that of 3. The luminescent study shows that polymers 1, 2, and 4 exhibit characteristic emission bands in the visible region, corresponding to the transitions of the Ln(III) ions. By comparison and analysis of luminescence, it is found that the incidence of the same ligand on the corresponding spectra of different Ln(III) ions is different, and the influence of different ligands on luminescence of the same Ln(III) ion is also very different.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Wang XJ, Cen ZM, Ni QL, Jiang XF, Lian HC, Gui LC, Zuo HH, Wang ZY (2010) Cryst Growth Des 10:2960–2968

    Article  CAS  Google Scholar 

  2. Kitagawa S, Kitaura R, Noro S-I (2004) Angew Chem Int Ed 43:2334–2375

    Article  CAS  Google Scholar 

  3. Pan L, Adams KM, Hernandez HE, Wang XT, Zheng C, Hattori Y, Kaneko K (2003) J Am Chem Soc 125:3062–3067

    Article  CAS  Google Scholar 

  4. Radecka-Paryzek W, Kubicki M, Luks E (2010) Struct Chem 21:299–304

    Article  CAS  Google Scholar 

  5. Wang P, Ma JP, Dong YB, Huang RQ (2007) J Am Chem Soc 129:10620–10621

    Article  CAS  Google Scholar 

  6. Cañadillas-Delgado L, Fabelo O, Pasán J, Delgado FS, Lloret F, Julve M, Ruiz-Pérez C (2010) Dalton Trans 39:7286–7293

    Article  Google Scholar 

  7. Dutra JDL, Gimenez IF, Costa NB Jr, Freire RO (2011) J Photochem Photobiol A 217:389–394

    Article  CAS  Google Scholar 

  8. Sun YG, Rong ST, Yu W, Wu YL, Ding F, Gao EJ, Zhang WZ, Verpoort F (2009) Z Anorg Allg Chem 635:2585–2591

    CAS  Google Scholar 

  9. Wang HH, He P, Yan HG, Gong ML (2011) Sens Actuators B 156:6–11

    Article  Google Scholar 

  10. Neves M, Gano L, Pereira N, Costa MC, Costa MR, Chandia M, Rosodo M, Fausto R (2002) Nucl Med Biol 29:329–338

    Article  CAS  Google Scholar 

  11. Binnemans K (2009) Chem Rev 109:4283–4374

    Article  CAS  Google Scholar 

  12. Xi P, Gu XH, Chen CF, He YX, Huang XA (2007) Spectrochim Acta A 66:667–671

    Article  Google Scholar 

  13. Viswanathan S, de Bettencourt-Dias A (2006) Inorg Chem 45:10138–10146

    Article  CAS  Google Scholar 

  14. Klink SI, Hebbink GA, Grave L, Oude Alink PGB, van Veggel FCJM (2002) J Phys Chem A 106:3681–3689

    Article  CAS  Google Scholar 

  15. Hu M, Wang QL, Xu GF, Deng GR, Yang GM, Yu M, Zhang YH (2007) Inorg Chim Acta 360:1684–1690

    Article  CAS  Google Scholar 

  16. Wu MF, Wang MS, Guo SP, Zheng FK, Chen HF, Jiang XM, Liu GN, Guo GC, Huang JS (2011) Cryst Growth Des 11:372–381

    Article  CAS  Google Scholar 

  17. Dolbecq A, Dumas E, Mayer CR, Mialane P (2010) Chem Rev 110:6009–6048

    Article  CAS  Google Scholar 

  18. Zhang LZ, Gu W, Li B, Liu X, Liao DZ (2007) Inorg Chem 46:622–624

    Article  CAS  Google Scholar 

  19. Wu AQ, Zheng FK, Liu X, Guo GC, Cai LZ, Dong ZC, Takano Y, Huang JS (2006) Inorg Chem Commun 9:347–350

    Article  CAS  Google Scholar 

  20. Amghouz Z, Roces L, García-Granda S, García JR, Souhail B, Mafra L, Shi F-N, Rocha J (2009) J Solid State Chem 182:3365–3373

    Article  CAS  Google Scholar 

  21. Bernini MC, Garro JC, Brusau EV, Narda GE, Varetti EL (2008) J Mol Struct 888:113–123

    Article  CAS  Google Scholar 

  22. Manna SC, Zangrando E, Bencini A, Benelli C, Chaudhuri NR (2006) Inorg Chem 45:9114–9122

    Article  CAS  Google Scholar 

  23. Hernández-Molina M, Ruiz-Pérez C, López T, Lloret F, Julve M (2003) Inorg Chem 42:5456–5458

    Article  Google Scholar 

  24. Cañadillas-Delgado L, Pasán J, Fabelo O, Hernández-Molina M, Lloret F, Julve M, Ruiz-Pérez C (2006) Inorg Chem 45:10585–10594

    Article  Google Scholar 

  25. Gawryszewska P, Ciunik Z (2009) J Photochem Photobiol A 202:1–9

    Article  CAS  Google Scholar 

  26. Lu WG, Jiang L, Lu TB (2010) Cryst Growth Des 10:4310–4318

    Article  CAS  Google Scholar 

  27. Sheldrick GM (1997) SHELXS97 and SHELXL97. University of Göttingen, Göttingen

    Google Scholar 

  28. Deacon GB, Phillips RJ (1980) Coord Chem Rev 33:227–250

    Article  CAS  Google Scholar 

  29. Hernández-Molina M, Lorenzo-Luis P, Ruiz-Pérez C, López T, Martín IR, Anderson KM, Orpen AG, Bocanegra EH, Lloret F, Julve M (2002) J Chem Soc Dalton Trans 2:3462–3470

    Article  Google Scholar 

  30. Zhang CZ, Mao HY, Wang YL, Zhang HY, Tao JC (2007) J Phys Chem Solids 68:236–242

    Article  CAS  Google Scholar 

  31. Huang YG, Wu BL, Yuan DQ, Xu YQ, Jiang FL, Hong MC (2007) Inorg Chem 46:1171–1176

    Article  CAS  Google Scholar 

  32. Wang GL, Tian YM, Cao DX, Yu YS, Sun WB (2011) Z Anorg Allg Chem 637:583–588

    Article  CAS  Google Scholar 

  33. An BL, Gong ML, Li MX, Zhang JM (2004) J Mol Struct 687:1–6

    Article  CAS  Google Scholar 

  34. Gao JZ, Yang W, Kang JW (1995) Spectroscopic properties of the lanthanide complexes in aqueous solution. University of Electronic Science and Technology of China Press, Chengdu, pp 89–95

    Google Scholar 

  35. Zhuravlev KP, Tsaryuk VI, Pekareva IS, Sokolnicki J, Klemenkova ZS (2011) J Photochem Photobiol A 219:139–147

    Article  CAS  Google Scholar 

  36. Subhan MA, Hasegawa Y, Suzuki T, Kaizaki S, Shozo Y (2009) Inorg Chim Acta 362:136–142

    Article  CAS  Google Scholar 

  37. Liu TF, Zhang WJ, Sun WH, Cao R (2011) Inorg Chem 50:5242–5248

    Article  CAS  Google Scholar 

  38. Daiguebonne C, Kerbellec N, Guillou O, Bünzli JC, Gumy F, Catala L, Mallah T, Audebr N, Gérault Y, Bernot K, Calvez G (2008) Inorg Chem 47:3700–3708

    Article  CAS  Google Scholar 

  39. Klink SI, Grave L, Reinhoudt DN, van Veggel FCJM, Werts MHV, Geurts FAJ, Hofstraat JW (2000) J Phys Chem A 104:5457–5468

    Article  CAS  Google Scholar 

  40. Biju S, Reddy MLP, Cowley AH, Vasudevan KV (2009) Cryst Growth Des 9:3562–3569

    Article  CAS  Google Scholar 

  41. Martín IR, Lahoz F, Lavín V, Hernández-Molina M (2000) Opt Mater 25:223–229

    Article  Google Scholar 

Download references

Acknowledgment

This study was supported by the National Natural Science Foundation of China (No. 20571037) and the innovational team project of Liaoning Province Educational Office (No. 2007T092).

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Jing Jin, Xiuyan Wang, Yanying Li, Yuxian Chi & Shuyun Niu

Authors
  1. Jing Jin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xiuyan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yanying Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yuxian Chi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Shuyun Niu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shuyun Niu.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (PDF 1129 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jin, J., Wang, X., Li, Y. et al. Synthesis, structure, and photophysical property of series of Ln(III) coordination polymers with different carboxylato ligands (Ln = Sm, Eu). Struct Chem 23, 1523–1531 (2012). https://doi.org/10.1007/s11224-012-9957-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11224-012-9957-6

Keywords

Search

Navigation