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Novel guanidinium zwitterion and derived ionic liquids: physicochemical properties and DFT theoretical studies

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Abstract

A new zwitterion containing 1,1,3,3-tetramethylguanidine was synthesized using a simple method, and the physicochemical properties as well as the crystal structure of the compound were also studied. Two new acidic ionic liquids (ILs) were synthesized using the zwitterion as the precursor and the physicochemical properties including density, viscosity, thermal property, and acidic scale of the ILs were investigated. A density functional theory investigation of the geometrical structures and electronic properties of the guanidinium triflate ionic liquid was also presented for better understanding the new ILs.

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Acknowledgments

This study was supported by National Natural Science Funds for Distinguished Young Scholar (20625308), National Basic Research Program of China (973 Program) 2011CB201404 and West Light Foundation of The Chinese Academy of Sciences.

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Authors and Affiliations

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, Gansu, China

    Jiamei Liu, Fang Wang, Zhen Li, Jianwei Zhou, Jing Chen & Chungu Xia

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  1. Jiamei Liu
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  2. Fang Wang
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  3. Zhen Li
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  4. Jianwei Zhou
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  5. Jing Chen
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Correspondence to Zhen Li.

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Liu, J., Wang, F., Li, Z. et al. Novel guanidinium zwitterion and derived ionic liquids: physicochemical properties and DFT theoretical studies. Struct Chem 22, 1119–1130 (2011). https://doi.org/10.1007/s11224-011-9807-y

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