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Unexpected 3:2 stoichiometry and structure of 15-crown-5 complex with lithium chlorochromate

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Abstract

X-ray diffraction study of the lithium chlorochromate complex with 15-crown-5 (15C5) revealed the existence of an unexpected complex dication with [(15C5)3Li2(H2O)2]2+ composition, which is also stable in the gas phase according to the quantum-chemical calculations by B3LYP/6-311+G(d,p) method.

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Authors and Affiliations

  1. STC “Institute for Single Crystals”, National Academy of Science of Ukraine, 60 Lenina ave., Kharkiv, 61001, Ukraine

    Oleg V. Shishkin & Roman I. Zubatyuk

  2. V. M. Karazin Kharkiv National University, 60 Svobody sq., Kharkiv, 61077, Ukraine

    Oleg V. Shishkin

  3. A. V. Bogatsky Physico-Chemical Institute, National Academy of Science of Ukraine, 86 Lustdorfskaya doroga, Odessa, Ukraine

    Oleg Yu. Zhovtyak, Andrey V. Kiriyak, Sergei A. Kotlyar & Gerbert L. Kamalov

Authors
  1. Oleg V. Shishkin
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  2. Roman I. Zubatyuk
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  3. Oleg Yu. Zhovtyak
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  4. Andrey V. Kiriyak
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  5. Sergei A. Kotlyar
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  6. Gerbert L. Kamalov
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Correspondence to Oleg V. Shishkin.

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Shishkin, O.V., Zubatyuk, R.I., Zhovtyak, O.Y. et al. Unexpected 3:2 stoichiometry and structure of 15-crown-5 complex with lithium chlorochromate. Struct Chem 20, 139–143 (2009). https://doi.org/10.1007/s11224-008-9388-6

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  • DOI: https://doi.org/10.1007/s11224-008-9388-6

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