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Synthesis, crystal structure of new linear trinuclear isovalence Co(II)([Co3(H–L)2(L)2]), and visualizing intermolecular interactions with Hirshfeld surface method

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Abstract

S-allyl-β-N-[(2-hydroxyphenyl)methylene]hyrazinecarbodithioate) (1, H2L), the Schiff base of dithiocarbazate with unsaturated allyl substitution, can act as a new tridentate SNO ligand H2–L and react with cobalt(II) nitrate hexahydrate to form the novel linear trinuclear isovalence Co(II) complex, [Co3(H–L)2(L)2] 2C2H5OH (2). The compounds were characterized by elemental analysis, infrared, and ultraviolet spectroscopy. Compound 2 was also characterized by single-crystal X-ray analysis and crystallizes in the orthorhombic space group, Pbcn, with a = 30.643(1) Å, b = 9.118(4) Å, c = 19.017(7) Å, α = β = γ = 90°, V = 5312.95 Å3, Z = 4, and R 1 = 0.0790, (wR 2) = 0.1223. The six-coordinate central Co(II) atom is bonded to two deprotonated metal-containing ligands. The terminal Co(II) atoms are in a square planar SNON four-coordinate environment and connected to the central Co(II) by N-atoms from the ligand backbone. For quantifying the intermolecular interactions in crystal lattice, the new d norm surface and the breakdown of fingerprint plots have been used for visualizing and exploring the compound 2.

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Authors and Affiliations

  1. Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 91775-1436, Mashhad, Iran

    Mohammad Yazdanbakhsh & Reza Takjoo

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  1. Mohammad Yazdanbakhsh
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  2. Reza Takjoo
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Correspondence to Mohammad Yazdanbakhsh.

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Yazdanbakhsh, M., Takjoo, R. Synthesis, crystal structure of new linear trinuclear isovalence Co(II)([Co3(H–L)2(L)2]), and visualizing intermolecular interactions with Hirshfeld surface method. Struct Chem 19, 895–903 (2008). https://doi.org/10.1007/s11224-008-9356-1

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