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Relationship between structure and nonlinear optical properties of new bisazo chromophores. Theoretical and experimental study

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Abstract

Two new bisazo chromophores—derivatives of bis-2,2-(4-hydroxyphenyl)propane (bisphenol A), heterocyclic amines (2-aminobenzothiazole, and 2-amino-6-nitrobenzothiazole) and aniline—were synthesized. Nonlinear optical properties of these chromophores were studied by solvatochromic method (obtained compounds have βCT value ∼10−29 esu). Dependence among the structure of molecules, their dipole moments, and first hyperpolarizabilities was considered on the basis of semi-empirical calculations. A correlation between the measured and calculated β values was studied. The NLO chromophores were used as special monomers to synthesize copolyarylates. The basic characterization of obtained polymers was carried out.

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Authors and Affiliations

  1. Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, Warsaw, 00-664, Poland

    Irmina Zadrożna & Ewa Kaczorowska

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  1. Irmina Zadrożna
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  2. Ewa Kaczorowska
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Correspondence to Irmina Zadrożna.

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Zadrożna, I., Kaczorowska, E. Relationship between structure and nonlinear optical properties of new bisazo chromophores. Theoretical and experimental study. Struct Chem 19, 131–135 (2008). https://doi.org/10.1007/s11224-007-9262-y

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  • DOI: https://doi.org/10.1007/s11224-007-9262-y

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