Skip to main content
SpringerLink
Log in

Synthesis and Characterization of Tetra-μ-phenolatotetrazinc(II) Complex with 1-Phenyl-3-Methyl-4-(salicylidene hydrazone)-Phenylethylene-Pyrazolone-5

  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

A new phenoxy-bridged tetranuclear zinc(II) complex with 1-phenyl-3-methyl-4-(salicylidene hydrazone)-phenylethylene-pyrazolone-5 (PMPaP-SAH) has been synthesized and characterized by elemental analysis, IR spectrum, molar conductivity, TG-DTA and single crystal X-ray diffraction. The X-ray diffraction analysis shows that the complex is tetranuclear with a rectangular Zn4 core and metal ions are held together by four μ-phenoxo bridges that lead to the formation of the tetra-μ-phenolatotetrazinc(II) complex. Each Zn(II) ion in the complex is penta-coordinated with a slightly distorted trigonal bipyramid coordination sphere.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Thompson, L. K.; Matthews, C. J.; Zhao, L.; Xu, Z. Q.; Miller, D. O.; Wilson, C.; Leech, M. A.; Howard, J. A. K.; Heath, S. L.; Whittaker, A. G.; Winpenny, R. E. P. J. Solid State Chem. 2001, 159, 308.

    Article  Google Scholar 

  2. Sanmartín, J.; Garcín-Deibe, A. M.; Bermejo, M. R.; Vázpuez, M.; Pedrido, R. Mat. Sci. Eng. 2001, 18, 3.

    Article  Google Scholar 

  3. Gamez, P.; Hong, P. D.; Lutz, M.; Driessen, W. L.; Spek, A. L.; Reedijk, J. Polyhedron 2003, 22, 205.

    Article  Google Scholar 

  4. Pasán, J.; Delgado, F. S.; Rodríguez-Martín, Y.; Hernández-Molina, M.; Ruiz-Pérez, C.; Sanchiz, J.; Lloret, F.; Julve, M. Polyhedron 2003, 22, 2143.

    Article  Google Scholar 

  5. Maspero, A.; Brenna, S.; Galli, S.; Penoni, A. J. Organomet. Chem. 2003, 672, 123.

    Article  Google Scholar 

  6. Adams, H.; Fenton, D. E.; Minardi, G.; Mura, E.; Angelo, M. Inorg. Chem. Commun. 2000, 3, 24.

    Article  Google Scholar 

  7. Pons, J.; Sanchez, F. J.; Casabo, J.; Alvarez-Larena, A.; Piniella, J. F.; Ros, J. Inorg. Chem. Commun. 2003, 6, 833.

    Article  Google Scholar 

  8. Kataeva, O. N.; Gubaidullin, A. T.; Litvinov, I. A.; Lodochnikova, O. A.; Islamov, L. R.; Movchan, A. I.; Chmutova, G. A. J. Mol. Stuct. 2002, 610, 175.

    Article  Google Scholar 

  9. Akama, Y.; Tong, A. Microchem. J. 1996, 53, 34.

    Article  Google Scholar 

  10. Akama, Y.; Tong, A.; Matsumoto, N.; Ikeda, T.; Tunaka, S. Vib. Spectrosc. 1996, 13, 113.

    Article  Google Scholar 

  11. Marchetti, F.; Rettinar, C.; Pettinari, R.; Cingolani, A.; Leonesi, D.; Lorenzotti, A. Polyhedron 1999, 18, 3041.

    Article  Google Scholar 

  12. Uzoukwu, B. A.; Adiukwu, P. U.; Al-Juaid, S. S.; Hitchcock, P. B.; Smith, J. D. Inorg. Chim. Acta 1996, 250, 173.

    Article  Google Scholar 

  13. Yang, Z. Y.; Yang, R. D.; Li, F. S.; Yu, K. B. Polyhedron 2000, 19, 2599.

    Article  Google Scholar 

  14. Raman, N.; Kulandaisamy, A.; Shunmugasundaram, A.; Jeyasubramanian, K. Transit. Met. Chem. 2001, 26, 131.

    Article  Google Scholar 

  15. Tang, X. C.; Jia, D. Z.; Yu, K. B.; Zhang, X. G.; Xia, X.; Zhou, Z. Y. J. Photochem. Photobio. A: Chem. 2000, 134, 23.

    Article  Google Scholar 

  16. Liu, L.; Jia, D. Z.; Qiao, Y. M.; Ji, Y. L.; Yu, K. B. J. Chem. Crystallogr. 2002, 32, 255.

    Article  Google Scholar 

  17. Liu, L.; Jia, D. Z.; Ji, Y. L.; Yu, K. B. J. Photochem. Photobio. A: Chem. 2003, 154, 117.

    Article  Google Scholar 

  18. Liu, L.; Jia, D. Z.; Ji, Y. L. Synth. React. Inorg. Met.-Org. Chem. 2002, 32, 739.

    Article  Google Scholar 

  19. Liu, L.; Jia, D. Z.; Qiao, Y. M.; Yu, K. B. Chin. J. Chem. 2002, 20, 286.

    Google Scholar 

  20. Ji, Y. L.; Liu, L.; Jia, D. Z.; Qiao, Y. M.; Yu, K. B. J. Chem. Crystallogr. 2002, 32, 505.

    Article  Google Scholar 

  21. Huang, R. Q.; Wang, H. L.; Zhou, J. Preparation of Organic Intermediates; Chemistry Industrial Press: China, 1997; p. 109.

    Google Scholar 

  22. Zhou, D. J.; Li, J.; Huang, C. H. Polyhedron 1997, 16, 1381.

    Article  Google Scholar 

  23. Jensen, B. S. Acta Chem. Scand. 1959, 13, 1668.

    Google Scholar 

  24. Geary, W. J. Coord. Chem. Rev. 1971, 7, 81.

    Article  Google Scholar 

  25. Sheldrick, G. M.; SHELX-97, Program for the Refinement of Crystal Structures; Germany, 1997.

  26. Beurskens, P. T.; Admiraal, G.; Beurskens, G.; Bosman, W. P.; Gelder, R. de; Israel, R.; Smits, J. M. M. The DIRDIF-99 Program System; Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands, 1999.

  27. Cromer, D. T.; Waber, J. T. International Tables for Crystallography; The Kynoch Press: Birmingham, England, Vol. IV, Table 2.2 A, 1974.

  28. Crystal Structure Analysis Package, Rigaku and Rigaku/MSC (2000–2004). 9009 New Trails Dr The Woodlands TX77381 USA.

  29. Watkin, D. J.; Prout, C. K.; Carruthers, J. R.; Betteridge, P. W. Crystals Issue 10; Chemical Crystallography Laboratory, Oxford, UK, 1996.

  30. Franco, E.; López-Torres, E.; Mendiola, M. A.; Sevilla, M. T. Polyhedron 2000, 19, 441.

    Article  Google Scholar 

  31. Niu, Y. Y.; Chen, P. K.; Zhang, H. Y.; Wu, Q. G.; Li, F. Synth. React. Inorg. Met.-Org. Chem. 1998, 28, 637.

    Google Scholar 

  32. Xiao, W.; Lu, Z. L.; Wang, X. J.; Su, C. Y.; Yu, K. B.; Liu, H. Q.; Kang, B. S. Polyhedron 2000, 19, 1295.

    Article  Google Scholar 

  33. Havanur, G. H.; Mahale, V. B. Indian J. Chem. 1987, 26A, 1063.

    Google Scholar 

  34. El-Sawaf, A. K.; West, D. X. Transit. Met. Chem. 1998, 23, 417.

    Article  Google Scholar 

  35. Thakkar, N. V.; Patil, R. M. Synth. React. Inorg. Met.-Org. Chem. 2000, 30, 1159.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Applied Chemistry, Xinjiang University, Urumqi, Xinjiang, 830046, China

    Guancheng Xu, Lang Liu, Li Zhang, Guangfei Liu & Dianzeng Jia

  2. Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu, 215006, China

    Jianping Lang

Authors
  1. Guancheng Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Li Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Guangfei Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Dianzeng Jia
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jianping Lang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Dianzeng Jia.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xu, G., Liu, L., Zhang, L. et al. Synthesis and Characterization of Tetra-μ-phenolatotetrazinc(II) Complex with 1-Phenyl-3-Methyl-4-(salicylidene hydrazone)-Phenylethylene-Pyrazolone-5. Struct Chem 16, 431–437 (2005). https://doi.org/10.1007/s11224-005-6352-6

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11224-005-6352-6

Keywords

Search

Navigation