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Structure and Vibrational Spectra of 1:1 Chloranilic Acid (CLA)—Tetramethylpyrazine (TMP) Complex

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Abstract

In searching for new molecular materials the crystals of 1:1 complexes of tetramethylpyrazine (TMP) with chloranilic acid (CLA) were grown. In the crystalline lattice of TMP.CLA infinite chains of hydrogen bonded components are formed. Very strong (d(O⋯N)=2.692(2) Å) hydrogen bonds without proton transfer are present. The components of the complex form stacks of parallel arrangement with the distance typical of van der Waals interaction. One can conclude that in packing, interactions via hydrogen bonds play a decisive role. In the IR spectrum one observes a broad, continuous absorption with well resolved trio typical of strong hydrogen bonds. A detailed analysis of IR and Raman spectra in the low frequency region related to deformation vibrations of CH3 groups shows that strong interaction via hydrogen bonding only slightly affects the dynamics of these groups.

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Authors and Affiliations

  1. Faculty of Chemistry, University of Wrocław, Joliot-Curie 14, 50-383, Wrocław, Poland

    W. Sawka-Dobrowolska, G. Bator & L. Sobczyk

  2. Institute of Chemistry and Environmental Protection, Technical University, Piastów Al.12, 71-065, Szczecin, Poland

    E. Grech & J. Nowicka-Scheibe

  3. Joint Institute for Nuclear Research, 141980, Dubna, Russia

    A. Pawlukojć

  4. Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195, Warsaw, Poland

    A. Pawlukojć

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  1. W. Sawka-Dobrowolska
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  2. G. Bator
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  3. L. Sobczyk
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  4. E. Grech
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  5. J. Nowicka-Scheibe
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  6. A. Pawlukojć
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Correspondence to L. Sobczyk.

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Sawka-Dobrowolska, W., Bator, G., Sobczyk, L. et al. Structure and Vibrational Spectra of 1:1 Chloranilic Acid (CLA)—Tetramethylpyrazine (TMP) Complex. Struct Chem 16, 281–286 (2005). https://doi.org/10.1007/s11224-005-4459-4

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  • DOI: https://doi.org/10.1007/s11224-005-4459-4

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