Skip to main content
SpringerLink
Log in

Potassium and cesium thiocyanate complexes with diphenyloxa-21-crown-7: Synthesis and vibration spectra. Selective properties of dipnehyloxa-21-crown-7

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Novel K and Cs complexes with diphenyloxa-21-crown-7 (2,3,5,6-dibenzo-1,4,7,10,13,16,19-heptaoxacyclo-heneicosadiene-2,5; DPO21C7) are synthesized and isolated in a solid state, and their IR spectra (4000−400 cm−1) are studied. Only four ether O atoms of crown ether are involved in coordination. Conformation of a macrocycle in the complexes depends on the cation size. The potentiometric selectivity of diphenyloxa-21-crown-7 toward Cs+ ions was found to be the greatest.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Hiraoka, M., Crown Compounds: Properties and Applications, Tokyo: Kodansha, 1982.

    Google Scholar 

  2. Host-Guest Complex Chemistry, Vogtle, F. and Weber, E., Eds., New York: Springer, 1985.

    Google Scholar 

  3. Ivanova, I.S., Dorokhov, A.V., Kireeva, I.K., et al., Koord. Khim., 2005, vol. 31, no.2, p. 98.

    Google Scholar 

  4. Materova, E.A., Grekovich, A.L., and Didina, S.E., Elektrokhimiya, 1972, vol. 8, no.12, p. 1829.

    Google Scholar 

  5. I.U.P.A.C. Recommendation for Nomenclature of Ion Selective Electrodes, Pure Appl. Chem., 1976. no. 48, p. 127.

  6. Tsivadze, A.Yu., Varnek, A.A., and Khutorskii, V.E., Koordinatsionnye soedineniya metallov s kraun-ligandami (Coordination Compounds of Metals with Crown Ligands), Moscow: Nauka, 1991.

    Google Scholar 

  7. Raevskii, O.A., Tkachev, V.V., Atovmyan, L.O., et al., Koord. Khim., 1988, vol. 14, no.12, p. 1697.

    Google Scholar 

  8. Kireeva, I.K., Generalova, N.B., Trofimov, V.A., and Tsivadze, A.Yu., Zh. Neorg. Khim., 1991, vol. 36, no.6, p. 1464.

    Google Scholar 

  9. Barsoum, N.B., Suzan, K.K., Yehia, A.I., et al., Talanta, 1998, vol. 47, p. 1215.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia

    I. S. Ivanova, A. V. Dorokhov, E. N. Pyatova & E. N. Galkina

  2. All-Russia Research Institute of Chemical Technology, Moscow, Russia

    V. V. Yakshin

  3. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia

    A. Yu. Tsivadze

Authors
  1. I. S. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Dorokhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. N. Pyatova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. N. Galkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Yakshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. Yu. Tsivadze
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 3, 2005, pp. 163–167.

Original Russian Text Copyright © 2005 by Ivanova, Dorokhov, Pyatova, Galkina, Yakshin, Tsivadze.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ivanova, I.S., Dorokhov, A.V., Pyatova, E.N. et al. Potassium and cesium thiocyanate complexes with diphenyloxa-21-crown-7: Synthesis and vibration spectra. Selective properties of dipnehyloxa-21-crown-7. Russ J Coord Chem 31, 151–155 (2005). https://doi.org/10.1007/s11173-005-0066-6

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11173-005-0066-6

Keywords

Search

Navigation