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Crystal structures of three centrosymmetric TbIII complexes. Structural model for triboluminescence

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Abstract

The molecular and crystal structures of the compounds [TbCl2(OH2)6]Cl (1), [Tb(acac-κ2O)Cl(OH2)(phen-κ2N)2][Tb(acac-κ2O)(OH2)4(phen-κ2N)]Cl3·2H2O·EtOH (2), and [TbCl(OH2)3(phen-κ2N)2]Cl2·H2O (3) were determined by X-ray diffraction. Compounds. 1 and 2 exhibit triboluminescence, whereas compound 3 is not triboluminescent. The structural model for triboluminescence in lanthanide complexes is suggested, and the structural criteria facilitating the triboluminescence properties were revealed. The key factors are the layered character of the crystal structure, the penetration of charge-carrying moieties into the destruction zone, and the boundaries of the destruction zones strictly defined by crystallography. The main types of destruction zones were identified.

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Authors and Affiliations

  1. Institute of Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100 letiya Vladivostoka, 690022, Vladivostok, Russian Federation

    B. V. Bukvetskii, A. S. Shishov & A. G. Mirochnik

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  1. B. V. Bukvetskii
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  2. A. S. Shishov
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  3. A. G. Mirochnik
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Correspondence to A. G. Mirochnik.

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This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the state assignment (Program No. FWFN(0205)-2022-0003). We are grateful to the Far Eastern Center for Structural Research and Analysis.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 6, pp. 1307–1321, June, 2023.

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Bukvetskii, B.V., Shishov, A.S. & Mirochnik, A.G. Crystal structures of three centrosymmetric TbIII complexes. Structural model for triboluminescence. Russ Chem Bull 72, 1307–1321 (2023). https://doi.org/10.1007/s11172-023-3906-y

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