Abstract
Structural features of polymeric silicon glycerolate hydrogels based on tetrafunctional silicon glycerolates were investigated using model process, namely, hydrolytic transformation of difunctional silicon glycerolates, by IR and 1H NMR spectroscopy, elemental analysis, atomic emission spectrometry. The possibility of forming a polymer network containing Si—O—Si and Si—OCH2CH(OH)CH2O—Si fragments was demonstrated. The molecular weight of the sub-chains in the network was calculated using Flory—Rehner approach based on the mechanical properties of the swollen network of flexible polymeric chains.
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References
FR Pat. 2160293; Chem. Abstrs., 1974, 80, 52379.
M. Y. Cheong, H. A. Hassan, R. Ismail, Z. A. A. Hasan, J. Saudi Chem. Soc., 2015, doi.org/10.1016/j.jscs.2015.09.002.
M. A. Brook, Y. Chen, K. Guo, Z. Zhang, J. D. Brennan, J. Mater. Chem., 2004, 14, 1469.
I. Gill, A. Ballesteros, J. Am. Chem. Soc., 1998, 120, 8587.
T. G. Khonina, A. P. Safronov, M. V. Ivanenko, E. V. Shadrina, O. N. Chupakhin, J. Mater. Chem. B, 2015, 3, 5490.
The Sol-Gel Handbook, V. 1, Synthesis and Processing, Eds D. Levy, M. Zayat, Wiley—VCH, Weinheim, 2015, 1616 pp.
The Sol-Gel Handbook, V. 3, Synthesis, Characterization, and Applications, Ed. D. Levy, M. Zayat, Wiley—VCH, Weinheim, 2015, 1508 pp.
J. D. Wright, N. A. J. M. Sommerdijk, Sol-Gel Materials: Chemistry and Applications, CRC Press, Florida, 2000, 125 pp.aa
H. E. Bergna, W. O. Roberts, Colloidal Silica: Fundamentals and Applications, CRC Press, Florida, 2006, 675 pp.
A. C. Pierre, G. M. Pajonk, Chem. Rev., 2002, 102, 4243.
Handbook of Sol–Gel Science and Technology: Applications of Sol–Gel Technology, Ed. S. Sakka, V. 3, Kluwer Academic Publishers, Norwell, 2005, 791 pp.
A. I. Maksimov, V. A. Moshnikov, Yu. M. Tairov, O. A. Shilova, Osnovi Sol—gel Technologii Nanokompozitov[Basics of Sol-gel Technology of Nanocomposite], Elmor, St-Petersburg, 2012, 255 pp. (in Russian).
N. A. Shabanova, P. D. Sakrisov, Sol—gel technologii. Nanodispersnii kremnesem[Sol-gel Technologies. Nanoscale Kieselgur], BINOM, Laboratorija znanii, Moscow, 2012, 328 pp. (in Russian).
T. Tsuru, J. Sol-Gel Sci. Technol., 2008, 46, 349.
T. G. Khonina, O. N. Chupakhin, L. P. Larionov, T. G. Bojakovskaja, A. L. Suvorov, E. V. Shadrina, Pharm. Chem. J. (Engl. Transl.), 2008, 42, 609[Khimiko-Farmatsevticheskii Zh., 2008, 42, 5].
Pat. RF 2382046; Byul. isobret.[Invention Bull.], 2010, No. 5 (in Russian).
T. G. Khonina, A. P. Safronov, E. V. Shadrina, M. V. Ivanenko, A. I. Suvorova, O. N. Chupakhin, J. Colloid Interface Sci., 2012, 365, 81.
E. Yu. Larchenko, T. G. Khonina, E. V. Shadrina, I. N. Ganebnikh, E. G. Matochkina, M. I. Kodess, Aktualnie problemi organicheskogo sinteza i analiza[Actual Problems of Organic Synthesis and Analysis], NISO Ural Branch RAS, Ekaterinburg, 2010, 250 (in Russian).
T. G. Khonina, E. Yu. Larchenko, E. V. Shadrina, I. N. Ganebnyh, A. A. Boiko, E. G. Matochkina, M. I. Kodess, O. N. Chupakhin, Russ. Chem. Bull., 2010, 59, 2230.
P. J. Flory, J. Rehner, J. Chem. Phys., 1943, 11, 512.
F. Horkay, I. Tasaki, P. J. Basser, Biomacromolecules, 2000, 84.
FQS Poland Sp., zoo: http://www.fqs.pl.
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Based on the Materials of the XX Mendeleev Congress on General and Applied Chemistry (September 26—30, 2016, Ekaterinburg, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1478—1482, August, 2017.
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Larchenko, E.Y., Permikin, V.V., Safronov, A.P. et al. Structural features of polymeric silicon glycerolate hydrogels. Russ Chem Bull 66, 1478–1482 (2017). https://doi.org/10.1007/s11172-017-1911-8
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DOI: https://doi.org/10.1007/s11172-017-1911-8