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Electrochemical synthesis of nanocomposite of palladium nanoparticles with polymer viologen-containing nanocapsule

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Abstract

An efficient mediated electrosynthesis of the spherical (85 nm) nanocomposite material Pd@p(MVCA8+-co-St) was carried out in an aqueous medium. Ultrasmall palladium nanoparticles (3—8 nm) are stabilized in nanocapsules of water-soluble nanoparticles of the copolymer p(MVCA8+-co-St) consisting of tetraviologen calix[4]resorcinol (MVCA8+) with styrene (St). The role of the mediator is played by viologen units of a polymer nanoparticle at potentials of the MV2+/MV∙+ redox couple. The high catalytic activity of the nanocomposite material in the reduction of nitrophenol with sodium borohydride is shown.

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References

  1. A. D. Pomogailo, A. S. Rozenberg, I. E. Uflyand, Nanochastitsy metallov v polimerakh [Metal Nanoparticles in Polymers], Khimiya, Moscow, 2000, 672 pp. (in Russian).

    Google Scholar 

  2. V. I. Roldugin, Russ. Chem. Rev., 2000, 69, 899.

    Article  Google Scholar 

  3. M. C. Daniel, D. Astruc, Chem. Rev., 2004, 104, 293.

    Article  CAS  Google Scholar 

  4. I. P. Suzdalev, Nanotekhnologiya: fiziko-khimiya nanoklasterov, nanostruktur i nanomaterialov [Nanotechnology: Physicochemistry of Nanostructures and Nanomaterials] (2nd ed.), Librokom, Moscow, 2009, 589 pp. (in Russian).

    Google Scholar 

  5. V. V. Volkov, T. A. Kravchenko, V. I. Roldugin, Russ. Chem. Rev., 2013, 82, 465.

    Article  Google Scholar 

  6. L. A. Dykman, V. A. Bogatyrev, S. Yu. Shchegolev, N. G. Khlebtsov, Zolotye nanochastitsy. Sintez, svoistva, biomeditsinskoe primenenie [Gold Nanoparticles. Synthesis, Properties, Biomedical Application], Nauka, Moscow, 2008, 319 pp. (in Russian).

    Google Scholar 

  7. B. I. Kharisov, O. V. Kharissova, U. Ortiz-Méndez, Handbook of Less-Common Nanostructures, CRC Press, Taylor and Francis Group, Boca Raton, 2012, 828 pp.

    Google Scholar 

  8. O. A. Petrii, Russ. Chem. Rev., 2015, 84, 159.

    Article  CAS  Google Scholar 

  9. P. C. Lee, D. Meisel, J. Phys. Chem., 1982, 86, 3391.

    Article  CAS  Google Scholar 

  10. P. Yang, W. Zhang, Y. Du, X. Wang, J. Mol. Catal. A, 2006, 260, 4.

    Article  CAS  Google Scholar 

  11. E. J. Kim, J. H. Yeum, H. D. Ghim, S. G. Lee, G. H. Lee, H. J. Lee, S. I. Han, J. H. Choi, Polymer, 2011, 35, 161.

    CAS  Google Scholar 

  12. S. V. Vasilyeva, M. A. Vorotyntsev, I. Bezverkhyy, E. Lesniewska, O. Heintz, R. Chassagnon, J. Phys. Chem. C, 2008, 112, 19878.

    Article  CAS  Google Scholar 

  13. V. A. Zinovyeva, M. A. Vorotyntsev, I. Bezverkhyy, D. Chaumont, J.-C. Hierso, Adv. Funct. Mater., 2011, 21, 1064.

    Article  CAS  Google Scholar 

  14. M. A. Vorotyntsev, M. Skompska, A. Rajchowska, J. Borysiuk, M. Donten, J. Electroanal. Chem., 2011, 662, 105.

    Article  CAS  Google Scholar 

  15. T. V. Magdesieva, O. M. Nikitin, O. A. Levitsky, V. A. Zinovyeva, I. Bezverkhyy, E. V. Zolotukhina, M. A. Vorotyntsev, J. Mol. Catal. A: Chemical, 2012, 353—354, 50.

    Article  Google Scholar 

  16. T. V. Magdesieva, O. M. Nikitin, E. V. Zolotukhina, V. A. Zinovyeva, M. A. Vorotyntsev, Mendeleev Commun., 2012, 22, 305.

    Article  CAS  Google Scholar 

  17. T. V. Magdesieva, O. M. Nikitin, E. V. Zolotukhina, M. A. Vorotyntsev, Electrochim. Acta, 2014, 122, 289.

    Article  CAS  Google Scholar 

  18. Nanotechnology Research Directions: IWGN Workshop Report, Vision for Nanotechnology R&D in the Next Decade, Eds M. C. Roco, R. S. Williams, P. Alivisatos, Kluwer Academic Publishers, Dortrecht—Boston—London, 2002.

  19. X. H. Peng, Q. M. Pan, G. L. Rempel, Chem. Soc. Rev., 2008, 37, 1619.

    Article  Google Scholar 

  20. R. M. Croks, M. Zhao, L. Sun, V. Chechik, L. K. Yeung, Acc. Chem. Res., 2009, 34.

    Google Scholar 

  21. E. D. Sultanova, E. G. Krasnova, S. V. Kharlamov, G. R. Nasybullina, V. V. Yanilkin, I. R. Nizameev, M. K. Kadirov, R. K. Mukhitova, L. Y. Zakharova, A. Y. Ziganshina, A. I. Konovalov, Chem PlusChem, 2015, 80, 217.

    CAS  Google Scholar 

  22. E. D. Sultanova, V. V. Salnikov, R. K. Mukhitova, Yu. F. Zuev, Yu. N. Osin, L. Ya. Zakharova, A. Y. Ziganshina, A. I. Konovalov, Chem. Commun., 2015, 51, 13317.

    Article  CAS  Google Scholar 

  23. V. V. Yanilkin, G. R. Nasybullina, A. Y. Ziganshina, I. R. Nizamiev, M. K. Kadirov, D. E. Korshin, A. I. Konovalov, Mendeleev Commun., 2014, 24, 108.

    Article  CAS  Google Scholar 

  24. V. V. Yanilkin, G. R. Nasybullina, E. D. Sultanova, A. Yu. Ziganshina, A. I. Konovalov, Russ. Chem. Bull. (Int. Ed.), 2014, 63, 1409 [Izv. Akad. Nauk, Ser. Khim., 2014, 1409].

    Article  CAS  Google Scholar 

  25. G. R. Nasretdinova, R. R. Fazleeva, R. K. Mukhitova, I. R. Nizameev, M. K. Kadirov, A. Y. Ziganshina, V. V. Yanilkin, Electrochem. Commun., 2015, 50, 69.

    Article  CAS  Google Scholar 

  26. M. K. Kadirov, I. R. Nizameev, L. Ya. Zakharova, J. Phys. Chem. C., 2012, 116, 11326.

    Article  CAS  Google Scholar 

  27. M. K. Kadirov, A. I. Litvinov, I. R. Nizameev, L. Y. Zakharova, J. Phys. Chem. C., 2014, 118, 19785.

    Article  CAS  Google Scholar 

  28. N. V. Korovin, Korrozionnye i elektrokhimicheskie svoistva palladiya [Corrosion and Electrochemical Properties of Palladium], Metallurgiya, Moscow, 1976, 240 pp. (in Russian).

    Google Scholar 

  29. W. J. Plieth, J. Phys. Chem., 1982, 86, 3166.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    V. V. Yanilkin, N. V. Nastapova, E. D. Sultanova, G. R. Nasretdinova, R. K. Mukhitova, A. Yu. Ziganshina, I. R. Nizameev & M. K. Kadirov

Authors
  1. V. V. Yanilkin
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  2. N. V. Nastapova
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  3. E. D. Sultanova
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  4. G. R. Nasretdinova
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  5. R. K. Mukhitova
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  6. A. Yu. Ziganshina
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  7. I. R. Nizameev
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  8. M. K. Kadirov
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Correspondence to V. V. Yanilkin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0125—0132, January, 2016.

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Yanilkin, V.V., Nastapova, N.V., Sultanova, E.D. et al. Electrochemical synthesis of nanocomposite of palladium nanoparticles with polymer viologen-containing nanocapsule. Russ Chem Bull 65, 125–132 (2016). https://doi.org/10.1007/s11172-016-1274-6

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  • DOI: https://doi.org/10.1007/s11172-016-1274-6

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