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Mediated electrochemical synthesis of Pd0 nanoparticles in solution

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Abstract

Efficient electrosynthesis of palladium(0) nanoparticles is carried out in solution by mediated electrochemical reduction of a complex dianion [PdCl4]2– in the DMSO/0.1 M Bu4NCl medium. The mediator function was performed by methylviologen and tetraviologen calix[4]resorcines MVCA-C 8+ n with methyl (n = 1), n-pentyl (n = 5), and n-decyl (n = 10) substituents in resorcinol rings at the potentials of redox pairs MV2+/MV•+, MVCA-C 8+ n /MVCA-C 4•+ n . The resulting metal nanoparticles gradually aggregate to yield coarser particles. The smallest size (255 nm) have metal particles obtained in the presence of MVCA-C 8+5 for the rest mediators, metal particles of the micron size are formed. Sonication results in disintegration of aggregates to nanoparticles.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Russia

    V. V. Yanilkin, N. V. Nastapova, G. R. Nasretdinova, R. K. Mukhitova, A. Yu. Ziganshina, I. R. Nizameev & M. K. Kadirov

Authors
  1. V. V. Yanilkin
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  2. N. V. Nastapova
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  3. G. R. Nasretdinova
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  4. R. K. Mukhitova
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  5. A. Yu. Ziganshina
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  6. I. R. Nizameev
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  7. M. K. Kadirov
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Corresponding author

Correspondence to V. V. Yanilkin.

Additional information

Original Russian Text © V.V. Yanilkin, N.V. Nastapova, G.R. Nasretdinova, R.K. Mukhitova, A.Yu. Ziganshina, I.R. Nizameev, M.K. Kadirov, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 10, pp. 1077–1089.

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Yanilkin, V.V., Nastapova, N.V., Nasretdinova, G.R. et al. Mediated electrochemical synthesis of Pd0 nanoparticles in solution. Russ J Electrochem 51, 951–962 (2015). https://doi.org/10.1134/S1023193515100146

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  • DOI: https://doi.org/10.1134/S1023193515100146

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