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Microwave-assisted synthesis of mesoporous metal-organic framework NH2—MIL-101(Al)

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Abstract

The possibility of formation of the mixed matrix membranes NH2—MIL-101(Al) under the conditions of microwave activation of the reaction mixture at atmospheric pressure is studied. Microwave irradiation affects the morphology and crystallite size and significantly shortens the synthesis time (from tens of hours to 10—30 min). The obtained samples of NH2—MIL-101(Al) with a crystallite size of 100 nm were used as nanofillers for polymer matrix based on the PIM-1 polymer with intrinsic microporosity for the preparation of hybrid membrane materials. Gas permeability for a series of gases was measured on the synthesized membranes.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    V. I. Isaeva, A. L. Tarasov & L. M. Kustov

  2. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 119991, Moscow, Russian Federation

    L. E. Starannikova, Yu. P. Yampol’skii & A. Yu. Alent’ev

  3. Chemical Department, M. V. Lomonosov Moscow State University, 1/3 Leninskie Gory, 119992, Moscow, Russian Federation

    L. M. Kustov

Authors
  1. V. I. Isaeva
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  2. A. L. Tarasov
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  3. L. E. Starannikova
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  4. Yu. P. Yampol’skii
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  5. A. Yu. Alent’ev
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  6. L. M. Kustov
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Correspondence to V. I. Isaeva.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2791—2795, December, 2015.

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Isaeva, V.I., Tarasov, A.L., Starannikova, L.E. et al. Microwave-assisted synthesis of mesoporous metal-organic framework NH2—MIL-101(Al). Russ Chem Bull 64, 2791–2795 (2015). https://doi.org/10.1007/s11172-015-1227-5

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  • DOI: https://doi.org/10.1007/s11172-015-1227-5

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