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Reaction of hexachlorobutadiene with sodium methoxide

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Abstract

Hexachlorobutadiene reacts with MeONa in refluxing methanol to give (Z)-4,4-dimethoxy2-oxobut-3-enoic acid and 2,4,4-trichloro-1,1,1,3-tetramethoxybut-2-ene, which were converted to methyl (Z)-4,4-dimethoxy-2-oxobut-3-enoate and methyl (Z)-2,4,4-trichloro-3methoxybut-2-enoate upon treatment with CH2N2 and acid hydrolysis, respectively.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    V. A. Egorov, F. A. Gimalova, L. S. Khasanova & M. S. Miftakhov

Authors
  1. V. A. Egorov
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  2. F. A. Gimalova
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  3. L. S. Khasanova
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  4. M. S. Miftakhov
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Corresponding author

Correspondence to M. S. Miftakhov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0355—0358, February, 2015.

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Egorov, V.A., Gimalova, F.A., Khasanova, L.S. et al. Reaction of hexachlorobutadiene with sodium methoxide. Russ Chem Bull 64, 355–358 (2015). https://doi.org/10.1007/s11172-015-0868-8

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  • DOI: https://doi.org/10.1007/s11172-015-0868-8

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