Abstract
Reaction of diamino derivative of azoxyfurazan with 2,2-dimethyl-5-nitro-5-nitroso-1,3-dioxane in the presence of dibromoisocyanuric acid afforded bis(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl-ONN-azoxy)azoxyfurazan. The reaction of the latter with AcCl/MeOH and further transformations of the product gave the first representative of substituted (mono- and polynitroalkyl-ONN-azoxy)azoxyfurazans, e.g. bis(nitromethyl-ONN-azoxy)azoxyfurazan, bis(dinitromethyl-ONN-azoxy)azoxyfurazan, bis(trinitromethyl-ONN-azoxy)azoxyfurazan, and some of their derivatives.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1767–1770, September, 2012.
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Luk’yanov, O.A., Pokhvisneva, G.V. & Ternikova, T.V. Bis(nitro- and polynitromethyl-ONN-azoxy)azoxyfurazans and some of their derivatives. Russ Chem Bull 61, 1783–1786 (2012). https://doi.org/10.1007/s11172-012-0245-9
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DOI: https://doi.org/10.1007/s11172-012-0245-9