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Synthesis of 4,4'-Bis[3-(Fluorodinitromethyl)-1H-1,2,4-triazol-5-Yl]azofurazan

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Chemistry of Heterocyclic Compounds Aims and scope

A three-step method was developed for converting both ethoxycarbonylmethyl groups of 4,4'-bis[3-(ethoxycarbonylmethyl)-1Н-1,2,4-triazol-5-yl]azofurazan into fluorodinitromethyl groups, enabling the preparation of the target 4,4'-bis[3-(fluorodinitromethyl)-1Н-1,2,4-triazol-5-yl]azofurazan in 74% overall yield.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave, Moscow, 119991, Russia

    Nataly S. Aleksandrova & Aleksei B. Sheremetev

  2. N. N. Semenov Federal Research Center of Chemical Physics, Russian Academy of Sciences, 4/1 Kosygina St, Moscow, 119334, Russia

    Konstantin A. Monogarov

Authors
  1. Nataly S. Aleksandrova
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  2. Konstantin A. Monogarov
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  3. Aleksei B. Sheremetev
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Correspondence to Konstantin A. Monogarov or Aleksei B. Sheremetev.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(5), 619–622

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Aleksandrova, N.S., Monogarov, K.A. & Sheremetev, A.B. Synthesis of 4,4'-Bis[3-(Fluorodinitromethyl)-1H-1,2,4-triazol-5-Yl]azofurazan. Chem Heterocycl Comp 56, 619–622 (2020). https://doi.org/10.1007/s10593-020-02709-1

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  • DOI: https://doi.org/10.1007/s10593-020-02709-1

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