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Synthesis and chemical properties of sodium 3,4,5-tris(diethylamino)-1,2-diphosphacyclopentadienide

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Abstract

1,2,3-Tris(diethylamino)cyclopropenylium iodide (1) reacted with sodium polyphosphides to give sodium 3,4,5-tris(diethylamino)-1,2-diphosphacyclopentadienide (2) in high yields. Chemical behavior of compound 2 in the reactions with organic and organoelement electrophiles was studied and compared with that of sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    V. A. Milyukov, L. R. Shakirova, I. A. Bezkishko, D. B. Krivolapov & O. G. Sinyashin

Authors
  1. V. A. Milyukov
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  2. L. R. Shakirova
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  3. I. A. Bezkishko
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  4. D. B. Krivolapov
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  5. O. G. Sinyashin
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Corresponding author

Correspondence to V. A. Milyukov.

Additional information

Based on the Materials of International Congress on Organic Chemistry dedicated to the 150th anniversary of A. M. Butlerov Theory of Structure of Organic Compounds (September 19–23, 2011, Kazan, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1467–1471, July, 2012.

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Milyukov, V.A., Shakirova, L.R., Bezkishko, I.A. et al. Synthesis and chemical properties of sodium 3,4,5-tris(diethylamino)-1,2-diphosphacyclopentadienide. Russ Chem Bull 61, 1483–1488 (2012). https://doi.org/10.1007/s11172-012-0192-5

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  • DOI: https://doi.org/10.1007/s11172-012-0192-5

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