Abstract
A reaction of simple α,ω-dithiolates with (+)-3-carene and (-)-6h-pinene p-nitroso chlorides goes through the substitution for the chlorine atoms at the quaternary carbon atoms with retention of configuration leading to the corresponding bis-6h-sulfanyl oximes. Their reaction with dichloromethane under conditions of phase-transfer catalysis takes place at the oxime hydroxyl and gives sulfur-containing macrocyclic compounds.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1434–1438, July, 2010.
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Gorshkov, N.B., Agafontsev, A.M. & Tkachev, A.V. Synthesis of terpenoid bis-α-sulfanyl oximes and macrocycles on their basis. Russ Chem Bull 59, 1467–1471 (2010). https://doi.org/10.1007/s11172-010-0264-3
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DOI: https://doi.org/10.1007/s11172-010-0264-3