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Photochemistry of the iron(III) complex with pyruvic acid in aqueous solutions

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Abstract

Photochemistry of the 1: 1 FepIII complex with pyruvic acid (PyrH) in aqueous solutions was studied by stationary photolysis and nanosecond laser flash photolysis with the excitation by the 3rd harmonics of an Nd:YAG laser. The quantum yield of [FeIIIPyr]2+ under the excitation at 355 nm is 1.0±0.1 and 0.46±0.05 in the absence and in the presence of dissolved oxygen, respectively. In experiments on laser flash photolysis, a weak intermediate absorption in the region 580–720 nm was found. The absorption was ascribed to the [FeII…MeC(O)COO•]p2+ radical complex. Laser flash photolysis of [FePyr]p2+ in the presence of methyl viologen dications (MVp2+) resulted in the formation of the MV•+ radical cations. The proposed reaction mechanism includes the inner-sphere electron transfer in the light-excited complex accompanied by the formation of the [FepII…MeC(O)COO•]p2+ radical complex followed by its transformation into the reaction products.

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Authors and Affiliations

  1. Department of Environmental Science, Wuhan University, 430072, Wuhan, Hubei, P. R. China

    X. Zhang, Y. Gong, F. Wu & N. Deng

  2. Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 ul. Institutskay a, 630090, Novosibirsk, Russian Federation

    I. P. Pozdnyakov, E. M. Glebov, V. P. Grivin & V. F. Plyusnin

  3. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    I. P. Pozdnyakov, E. M. Glebov, V. P. Grivin, V. F. Plyusnin & N. M. Bazhinb

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  1. X. Zhang
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  2. Y. Gong
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  3. F. Wu
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  5. I. P. Pozdnyakov
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  6. E. M. Glebov
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  8. V. F. Plyusnin
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Correspondence to E. M. Glebov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1771–1779, September, 2009.

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Zhang, X., Gong, Y., Wu, F. et al. Photochemistry of the iron(III) complex with pyruvic acid in aqueous solutions. Russ Chem Bull 58, 1828–1836 (2009). https://doi.org/10.1007/s11172-009-0249-2

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  • DOI: https://doi.org/10.1007/s11172-009-0249-2

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